INTERACTIONS BETWEEN CETYLTRIMETHYLAMMONIUM OR TETRAMETYLAMMMONIUM BROMIDE AND MCl2 OR MCl5 (M = Hg, Cu, Zn, Co, Ni, Cd and Nb) IN MONONUCLEAR COMPLEXES: SYNTHESIS AND INFRARED STUDY
On allowing cetyltrimethyl ammonium bromide (C19H42NBr) and HgCl2, CuCl2.2H2O, CoCl2.6H2O, ZnCl2, NiCl2.6H2O or NbCl5 in specific ratio in methanol, new mononuclear have been obtained and studied by infrared. The suggested structures are discrete, of infinite chain with octahedral or tetrahedral en...
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Alma Mater Publishing House "Vasile Alecsandri" University of Bacau
2020
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oai:doaj.org-article:f14b5a72338849fca9d9d5536fc0b1d42021-12-02T19:52:42ZINTERACTIONS BETWEEN CETYLTRIMETHYLAMMONIUM OR TETRAMETYLAMMMONIUM BROMIDE AND MCl2 OR MCl5 (M = Hg, Cu, Zn, Co, Ni, Cd and Nb) IN MONONUCLEAR COMPLEXES: SYNTHESIS AND INFRARED STUDY10.29081/jesr.v26i3.2082068-75592344-4932https://doaj.org/article/f14b5a72338849fca9d9d5536fc0b1d42020-07-01T00:00:00Zhttp://www.jesr.ub.ro/1/article/view/208https://doaj.org/toc/2068-7559https://doaj.org/toc/2344-4932 On allowing cetyltrimethyl ammonium bromide (C19H42NBr) and HgCl2, CuCl2.2H2O, CoCl2.6H2O, ZnCl2, NiCl2.6H2O or NbCl5 in specific ratio in methanol, new mononuclear have been obtained and studied by infrared. The suggested structures are discrete, of infinite chain with octahedral or tetrahedral environments around the metallic centres. The MX2 behaves as discrete chains. For most of the structures, when intermolecular hydrogen bonds are considered, supramolecular architectures may be obtained. DAME SEYEASSANE TOURECHEIKH ABDOUL KHADIR DIOPLIBASSE DIOPAlma Mater Publishing House "Vasile Alecsandri" University of Bacauarticleintermolecular hydrogen bonds, discrete structures, infinite chain, supramolecular architectureTechnologyTEngineering (General). Civil engineering (General)TA1-2040ENJournal of Engineering Studies and Research, Vol 26, Iss 3 (2020) |
institution |
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DOAJ |
language |
EN |
topic |
intermolecular hydrogen bonds, discrete structures, infinite chain, supramolecular architecture Technology T Engineering (General). Civil engineering (General) TA1-2040 |
spellingShingle |
intermolecular hydrogen bonds, discrete structures, infinite chain, supramolecular architecture Technology T Engineering (General). Civil engineering (General) TA1-2040 DAME SEYE ASSANE TOURE CHEIKH ABDOUL KHADIR DIOP LIBASSE DIOP INTERACTIONS BETWEEN CETYLTRIMETHYLAMMONIUM OR TETRAMETYLAMMMONIUM BROMIDE AND MCl2 OR MCl5 (M = Hg, Cu, Zn, Co, Ni, Cd and Nb) IN MONONUCLEAR COMPLEXES: SYNTHESIS AND INFRARED STUDY |
description |
On allowing cetyltrimethyl ammonium bromide (C19H42NBr) and HgCl2, CuCl2.2H2O, CoCl2.6H2O, ZnCl2, NiCl2.6H2O or NbCl5 in specific ratio in methanol, new mononuclear have been obtained and studied by infrared. The suggested structures are discrete, of infinite chain with octahedral or tetrahedral environments around the metallic centres. The MX2 behaves as discrete chains. For most of the structures, when intermolecular hydrogen bonds are considered, supramolecular architectures may be obtained.
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format |
article |
author |
DAME SEYE ASSANE TOURE CHEIKH ABDOUL KHADIR DIOP LIBASSE DIOP |
author_facet |
DAME SEYE ASSANE TOURE CHEIKH ABDOUL KHADIR DIOP LIBASSE DIOP |
author_sort |
DAME SEYE |
title |
INTERACTIONS BETWEEN CETYLTRIMETHYLAMMONIUM OR TETRAMETYLAMMMONIUM BROMIDE AND MCl2 OR MCl5 (M = Hg, Cu, Zn, Co, Ni, Cd and Nb) IN MONONUCLEAR COMPLEXES: SYNTHESIS AND INFRARED STUDY |
title_short |
INTERACTIONS BETWEEN CETYLTRIMETHYLAMMONIUM OR TETRAMETYLAMMMONIUM BROMIDE AND MCl2 OR MCl5 (M = Hg, Cu, Zn, Co, Ni, Cd and Nb) IN MONONUCLEAR COMPLEXES: SYNTHESIS AND INFRARED STUDY |
title_full |
INTERACTIONS BETWEEN CETYLTRIMETHYLAMMONIUM OR TETRAMETYLAMMMONIUM BROMIDE AND MCl2 OR MCl5 (M = Hg, Cu, Zn, Co, Ni, Cd and Nb) IN MONONUCLEAR COMPLEXES: SYNTHESIS AND INFRARED STUDY |
title_fullStr |
INTERACTIONS BETWEEN CETYLTRIMETHYLAMMONIUM OR TETRAMETYLAMMMONIUM BROMIDE AND MCl2 OR MCl5 (M = Hg, Cu, Zn, Co, Ni, Cd and Nb) IN MONONUCLEAR COMPLEXES: SYNTHESIS AND INFRARED STUDY |
title_full_unstemmed |
INTERACTIONS BETWEEN CETYLTRIMETHYLAMMONIUM OR TETRAMETYLAMMMONIUM BROMIDE AND MCl2 OR MCl5 (M = Hg, Cu, Zn, Co, Ni, Cd and Nb) IN MONONUCLEAR COMPLEXES: SYNTHESIS AND INFRARED STUDY |
title_sort |
interactions between cetyltrimethylammonium or tetrametylammmonium bromide and mcl2 or mcl5 (m = hg, cu, zn, co, ni, cd and nb) in mononuclear complexes: synthesis and infrared study |
publisher |
Alma Mater Publishing House "Vasile Alecsandri" University of Bacau |
publishDate |
2020 |
url |
https://doaj.org/article/f14b5a72338849fca9d9d5536fc0b1d4 |
work_keys_str_mv |
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