Synthesis and Characterization of Biochar-Based Geopolymer Materials

The aim of this research is to evaluate the possibility to realize alkali-activated materials exploiting biochar, a secondary raw material coming from pyrolysis/gasification processes, for environmental benefits, such as improvement of soil fertility and reduction of CO<sub>2</sub> emiss...

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Auteurs principaux: Federica Piccolo, Fernanda Andreola, Luisa Barbieri, Isabella Lancellotti
Format: article
Langue:EN
Publié: MDPI AG 2021
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Accès en ligne:https://doaj.org/article/f15e1357ef034802a4645d0aa81f0057
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Résumé:The aim of this research is to evaluate the possibility to realize alkali-activated materials exploiting biochar, a secondary raw material coming from pyrolysis/gasification processes, for environmental benefits, such as improvement of soil fertility and reduction of CO<sub>2</sub> emissions into the atmosphere thanks to the carbon sink process where carbon dioxide is subtracted from the cycle of carbon. For the matrix of the geopolymers, a waste material derived from incinerator bottom ash was used and compared to pure metakaolin matrix. The materials obtained are lightweight and porous, with high water absorption capacity and moisture adsorption/desorption. BET analysis shows an increase in specific surface by increasing the biochar content and the biochar acts as a filler in the pores. From porosimetry analysis it is possible to follow the evolution of the curing process of the geopolymer prepared: specimens containing 70 wt% biochar after 28 and 90 days showed an increase in total Hg intrusion volume, pore area and total porosity but a decrease in the dimensions of pores. Due to the technical properties of materials containing biochar, they can be used in the future for a cleaner design of products in the field of sustainable construction for insulating panels or lightweight materials for houses and gardens in terraces and balconies.