Use of trifluoroacetaldehyde N-tfsylhydrazone as a trifluorodiazoethane surrogate and its synthetic applications

Since fluoro-compounds are popular in industrial settings, efficient methods for incorporation of fluoride into organic molecules are desirable. Here, the authors developed trifluoroacetaldehyde N-tfsylhydrazone (TFHZ-Tfs) as a CF3CHN2 surrogate that generates CF3CHN2 in situ under basic conditions.

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Autores principales:	Xinyu Zhang, Zhaohong Liu, Xiangyu Yang, Yuanqing Dong, Matteo Virelli, Giuseppe Zanoni, Edward A. Anderson, Xihe Bi
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2019
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/f16d80073b9e4ad596a828624a933cc7
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spelling	oai:doaj.org-article:f16d80073b9e4ad596a828624a933cc72021-12-02T17:01:53ZUse of trifluoroacetaldehyde N-tfsylhydrazone as a trifluorodiazoethane surrogate and its synthetic applications10.1038/s41467-018-08253-z2041-1723https://doaj.org/article/f16d80073b9e4ad596a828624a933cc72019-01-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-08253-zhttps://doaj.org/toc/2041-1723Since fluoro-compounds are popular in industrial settings, efficient methods for incorporation of fluoride into organic molecules are desirable. Here, the authors developed trifluoroacetaldehyde N-tfsylhydrazone (TFHZ-Tfs) as a CF3CHN2 surrogate that generates CF3CHN2 in situ under basic conditions.Xinyu ZhangZhaohong LiuXiangyu YangYuanqing DongMatteo VirelliGiuseppe ZanoniEdward A. AndersonXihe BiNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-9 (2019)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Xinyu Zhang Zhaohong Liu Xiangyu Yang Yuanqing Dong Matteo Virelli Giuseppe Zanoni Edward A. Anderson Xihe Bi Use of trifluoroacetaldehyde N-tfsylhydrazone as a trifluorodiazoethane surrogate and its synthetic applications
description	Since fluoro-compounds are popular in industrial settings, efficient methods for incorporation of fluoride into organic molecules are desirable. Here, the authors developed trifluoroacetaldehyde N-tfsylhydrazone (TFHZ-Tfs) as a CF3CHN2 surrogate that generates CF3CHN2 in situ under basic conditions.
format	article
author	Xinyu Zhang Zhaohong Liu Xiangyu Yang Yuanqing Dong Matteo Virelli Giuseppe Zanoni Edward A. Anderson Xihe Bi
author_facet	Xinyu Zhang Zhaohong Liu Xiangyu Yang Yuanqing Dong Matteo Virelli Giuseppe Zanoni Edward A. Anderson Xihe Bi
author_sort	Xinyu Zhang
title	Use of trifluoroacetaldehyde N-tfsylhydrazone as a trifluorodiazoethane surrogate and its synthetic applications
title_short	Use of trifluoroacetaldehyde N-tfsylhydrazone as a trifluorodiazoethane surrogate and its synthetic applications
title_full	Use of trifluoroacetaldehyde N-tfsylhydrazone as a trifluorodiazoethane surrogate and its synthetic applications
title_fullStr	Use of trifluoroacetaldehyde N-tfsylhydrazone as a trifluorodiazoethane surrogate and its synthetic applications
title_full_unstemmed	Use of trifluoroacetaldehyde N-tfsylhydrazone as a trifluorodiazoethane surrogate and its synthetic applications
title_sort	use of trifluoroacetaldehyde n-tfsylhydrazone as a trifluorodiazoethane surrogate and its synthetic applications
publisher	Nature Portfolio
publishDate	2019
url	https://doaj.org/article/f16d80073b9e4ad596a828624a933cc7
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Use of trifluoroacetaldehyde N-tfsylhydrazone as a trifluorodiazoethane surrogate and its synthetic applications

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