Oxygen radical character in group 11 oxygen fluorides

While transition metal complexes bearing terminal oxido ligands are common, those of group 11 elements have yet to be experimentally observed. Here, Riedel and colleagues synthesise molecular oxygen fluorides of copper, silver and gold, and show that the oxo ligands possess radical character.

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Autores principales:	Lin Li, Tony Stüker, Stefanie Kieninger, Dirk Andrae, Tobias Schlöder, Yu Gong, Lester Andrews, Helmut Beckers, Sebastian Riedel
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2018
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/f190948839204e2bb4a032cc26c93302
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spelling	oai:doaj.org-article:f190948839204e2bb4a032cc26c933022021-12-02T17:32:29ZOxygen radical character in group 11 oxygen fluorides10.1038/s41467-018-03630-02041-1723https://doaj.org/article/f190948839204e2bb4a032cc26c933022018-03-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-03630-0https://doaj.org/toc/2041-1723While transition metal complexes bearing terminal oxido ligands are common, those of group 11 elements have yet to be experimentally observed. Here, Riedel and colleagues synthesise molecular oxygen fluorides of copper, silver and gold, and show that the oxo ligands possess radical character.Lin LiTony StükerStefanie KieningerDirk AndraeTobias SchlöderYu GongLester AndrewsHelmut BeckersSebastian RiedelNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-6 (2018)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Lin Li Tony Stüker Stefanie Kieninger Dirk Andrae Tobias Schlöder Yu Gong Lester Andrews Helmut Beckers Sebastian Riedel Oxygen radical character in group 11 oxygen fluorides
description	While transition metal complexes bearing terminal oxido ligands are common, those of group 11 elements have yet to be experimentally observed. Here, Riedel and colleagues synthesise molecular oxygen fluorides of copper, silver and gold, and show that the oxo ligands possess radical character.
format	article
author	Lin Li Tony Stüker Stefanie Kieninger Dirk Andrae Tobias Schlöder Yu Gong Lester Andrews Helmut Beckers Sebastian Riedel
author_facet	Lin Li Tony Stüker Stefanie Kieninger Dirk Andrae Tobias Schlöder Yu Gong Lester Andrews Helmut Beckers Sebastian Riedel
author_sort	Lin Li
title	Oxygen radical character in group 11 oxygen fluorides
title_short	Oxygen radical character in group 11 oxygen fluorides
title_full	Oxygen radical character in group 11 oxygen fluorides
title_fullStr	Oxygen radical character in group 11 oxygen fluorides
title_full_unstemmed	Oxygen radical character in group 11 oxygen fluorides
title_sort	oxygen radical character in group 11 oxygen fluorides
publisher	Nature Portfolio
publishDate	2018
url	https://doaj.org/article/f190948839204e2bb4a032cc26c93302
work_keys_str_mv	AT linli oxygenradicalcharacteringroup11oxygenfluorides AT tonystuker oxygenradicalcharacteringroup11oxygenfluorides AT stefaniekieninger oxygenradicalcharacteringroup11oxygenfluorides AT dirkandrae oxygenradicalcharacteringroup11oxygenfluorides AT tobiasschloder oxygenradicalcharacteringroup11oxygenfluorides AT yugong oxygenradicalcharacteringroup11oxygenfluorides AT lesterandrews oxygenradicalcharacteringroup11oxygenfluorides AT helmutbeckers oxygenradicalcharacteringroup11oxygenfluorides AT sebastianriedel oxygenradicalcharacteringroup11oxygenfluorides
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Oxygen radical character in group 11 oxygen fluorides

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