Electrochemical activation of C–H by electron-deficient W2C nanocrystals for simultaneous alkoxylation and hydrogen evolution

Designing electrode materials for mild and additive-free activation of C–H bonds is of great challenge. The authors report the application of electron-deficient W2C nanocrystal electrodes to boost the dissociation of C-H bonds toward the efficient alkoxylation and hydrogen evolution reactions.

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Autores principales: Xiu Lin, Shi-Nan Zhang, Dong Xu, Jun-Jun Zhang, Yun-Xiao Lin, Guang-Yao Zhai, Hui Su, Zhong-Hua Xue, Xi Liu, Markus Antonietti, Jie-Sheng Chen, Xin-Hao Li
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Lenguaje:EN
Publicado: Nature Portfolio 2021
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Acceso en línea:https://doaj.org/article/f1916d1f7d554325ba3dbd08f89db883
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spelling oai:doaj.org-article:f1916d1f7d554325ba3dbd08f89db8832021-12-02T18:02:47ZElectrochemical activation of C–H by electron-deficient W2C nanocrystals for simultaneous alkoxylation and hydrogen evolution10.1038/s41467-021-24203-82041-1723https://doaj.org/article/f1916d1f7d554325ba3dbd08f89db8832021-06-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-24203-8https://doaj.org/toc/2041-1723Designing electrode materials for mild and additive-free activation of C–H bonds is of great challenge. The authors report the application of electron-deficient W2C nanocrystal electrodes to boost the dissociation of C-H bonds toward the efficient alkoxylation and hydrogen evolution reactions.Xiu LinShi-Nan ZhangDong XuJun-Jun ZhangYun-Xiao LinGuang-Yao ZhaiHui SuZhong-Hua XueXi LiuMarkus AntoniettiJie-Sheng ChenXin-Hao LiNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-9 (2021)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Xiu Lin
Shi-Nan Zhang
Dong Xu
Jun-Jun Zhang
Yun-Xiao Lin
Guang-Yao Zhai
Hui Su
Zhong-Hua Xue
Xi Liu
Markus Antonietti
Jie-Sheng Chen
Xin-Hao Li
Electrochemical activation of C–H by electron-deficient W2C nanocrystals for simultaneous alkoxylation and hydrogen evolution
description Designing electrode materials for mild and additive-free activation of C–H bonds is of great challenge. The authors report the application of electron-deficient W2C nanocrystal electrodes to boost the dissociation of C-H bonds toward the efficient alkoxylation and hydrogen evolution reactions.
format article
author Xiu Lin
Shi-Nan Zhang
Dong Xu
Jun-Jun Zhang
Yun-Xiao Lin
Guang-Yao Zhai
Hui Su
Zhong-Hua Xue
Xi Liu
Markus Antonietti
Jie-Sheng Chen
Xin-Hao Li
author_facet Xiu Lin
Shi-Nan Zhang
Dong Xu
Jun-Jun Zhang
Yun-Xiao Lin
Guang-Yao Zhai
Hui Su
Zhong-Hua Xue
Xi Liu
Markus Antonietti
Jie-Sheng Chen
Xin-Hao Li
author_sort Xiu Lin
title Electrochemical activation of C–H by electron-deficient W2C nanocrystals for simultaneous alkoxylation and hydrogen evolution
title_short Electrochemical activation of C–H by electron-deficient W2C nanocrystals for simultaneous alkoxylation and hydrogen evolution
title_full Electrochemical activation of C–H by electron-deficient W2C nanocrystals for simultaneous alkoxylation and hydrogen evolution
title_fullStr Electrochemical activation of C–H by electron-deficient W2C nanocrystals for simultaneous alkoxylation and hydrogen evolution
title_full_unstemmed Electrochemical activation of C–H by electron-deficient W2C nanocrystals for simultaneous alkoxylation and hydrogen evolution
title_sort electrochemical activation of c–h by electron-deficient w2c nanocrystals for simultaneous alkoxylation and hydrogen evolution
publisher Nature Portfolio
publishDate 2021
url https://doaj.org/article/f1916d1f7d554325ba3dbd08f89db883
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AT shinanzhang electrochemicalactivationofchbyelectrondeficientw2cnanocrystalsforsimultaneousalkoxylationandhydrogenevolution
AT dongxu electrochemicalactivationofchbyelectrondeficientw2cnanocrystalsforsimultaneousalkoxylationandhydrogenevolution
AT junjunzhang electrochemicalactivationofchbyelectrondeficientw2cnanocrystalsforsimultaneousalkoxylationandhydrogenevolution
AT yunxiaolin electrochemicalactivationofchbyelectrondeficientw2cnanocrystalsforsimultaneousalkoxylationandhydrogenevolution
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AT huisu electrochemicalactivationofchbyelectrondeficientw2cnanocrystalsforsimultaneousalkoxylationandhydrogenevolution
AT zhonghuaxue electrochemicalactivationofchbyelectrondeficientw2cnanocrystalsforsimultaneousalkoxylationandhydrogenevolution
AT xiliu electrochemicalactivationofchbyelectrondeficientw2cnanocrystalsforsimultaneousalkoxylationandhydrogenevolution
AT markusantonietti electrochemicalactivationofchbyelectrondeficientw2cnanocrystalsforsimultaneousalkoxylationandhydrogenevolution
AT jieshengchen electrochemicalactivationofchbyelectrondeficientw2cnanocrystalsforsimultaneousalkoxylationandhydrogenevolution
AT xinhaoli electrochemicalactivationofchbyelectrondeficientw2cnanocrystalsforsimultaneousalkoxylationandhydrogenevolution
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