Activation of allylic esters in an intramolecular vinylogous kinetic resolution reaction with synergistic magnesium catalysts

Kinetic resolution allows to obtain enantioenriched compounds from racemic mixtures. Here, the authors report a synergistic magnesium catalyst promoting kinetic resolution of an intramolecular vinylogous Michael reaction to access [6.6.5]-tricyclic chiral skeletons.

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Autores principales: Dan Li, Yuling Yang, Minmin Zhang, Linqing Wang, Yingfan Xu, Dongxu Yang, Rui Wang
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2020
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Acceso en línea:https://doaj.org/article/f213bfe77c9f4fbf901b3b506a51692b
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spelling oai:doaj.org-article:f213bfe77c9f4fbf901b3b506a51692b2021-12-02T15:45:30ZActivation of allylic esters in an intramolecular vinylogous kinetic resolution reaction with synergistic magnesium catalysts10.1038/s41467-020-16486-02041-1723https://doaj.org/article/f213bfe77c9f4fbf901b3b506a51692b2020-05-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-16486-0https://doaj.org/toc/2041-1723Kinetic resolution allows to obtain enantioenriched compounds from racemic mixtures. Here, the authors report a synergistic magnesium catalyst promoting kinetic resolution of an intramolecular vinylogous Michael reaction to access [6.6.5]-tricyclic chiral skeletons.Dan LiYuling YangMinmin ZhangLinqing WangYingfan XuDongxu YangRui WangNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-10 (2020)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Dan Li
Yuling Yang
Minmin Zhang
Linqing Wang
Yingfan Xu
Dongxu Yang
Rui Wang
Activation of allylic esters in an intramolecular vinylogous kinetic resolution reaction with synergistic magnesium catalysts
description Kinetic resolution allows to obtain enantioenriched compounds from racemic mixtures. Here, the authors report a synergistic magnesium catalyst promoting kinetic resolution of an intramolecular vinylogous Michael reaction to access [6.6.5]-tricyclic chiral skeletons.
format article
author Dan Li
Yuling Yang
Minmin Zhang
Linqing Wang
Yingfan Xu
Dongxu Yang
Rui Wang
author_facet Dan Li
Yuling Yang
Minmin Zhang
Linqing Wang
Yingfan Xu
Dongxu Yang
Rui Wang
author_sort Dan Li
title Activation of allylic esters in an intramolecular vinylogous kinetic resolution reaction with synergistic magnesium catalysts
title_short Activation of allylic esters in an intramolecular vinylogous kinetic resolution reaction with synergistic magnesium catalysts
title_full Activation of allylic esters in an intramolecular vinylogous kinetic resolution reaction with synergistic magnesium catalysts
title_fullStr Activation of allylic esters in an intramolecular vinylogous kinetic resolution reaction with synergistic magnesium catalysts
title_full_unstemmed Activation of allylic esters in an intramolecular vinylogous kinetic resolution reaction with synergistic magnesium catalysts
title_sort activation of allylic esters in an intramolecular vinylogous kinetic resolution reaction with synergistic magnesium catalysts
publisher Nature Portfolio
publishDate 2020
url https://doaj.org/article/f213bfe77c9f4fbf901b3b506a51692b
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AT yulingyang activationofallylicestersinanintramolecularvinylogouskineticresolutionreactionwithsynergisticmagnesiumcatalysts
AT minminzhang activationofallylicestersinanintramolecularvinylogouskineticresolutionreactionwithsynergisticmagnesiumcatalysts
AT linqingwang activationofallylicestersinanintramolecularvinylogouskineticresolutionreactionwithsynergisticmagnesiumcatalysts
AT yingfanxu activationofallylicestersinanintramolecularvinylogouskineticresolutionreactionwithsynergisticmagnesiumcatalysts
AT dongxuyang activationofallylicestersinanintramolecularvinylogouskineticresolutionreactionwithsynergisticmagnesiumcatalysts
AT ruiwang activationofallylicestersinanintramolecularvinylogouskineticresolutionreactionwithsynergisticmagnesiumcatalysts
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