Activation of allylic esters in an intramolecular vinylogous kinetic resolution reaction with synergistic magnesium catalysts
Kinetic resolution allows to obtain enantioenriched compounds from racemic mixtures. Here, the authors report a synergistic magnesium catalyst promoting kinetic resolution of an intramolecular vinylogous Michael reaction to access [6.6.5]-tricyclic chiral skeletons.
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Nature Portfolio
2020
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oai:doaj.org-article:f213bfe77c9f4fbf901b3b506a51692b2021-12-02T15:45:30ZActivation of allylic esters in an intramolecular vinylogous kinetic resolution reaction with synergistic magnesium catalysts10.1038/s41467-020-16486-02041-1723https://doaj.org/article/f213bfe77c9f4fbf901b3b506a51692b2020-05-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-16486-0https://doaj.org/toc/2041-1723Kinetic resolution allows to obtain enantioenriched compounds from racemic mixtures. Here, the authors report a synergistic magnesium catalyst promoting kinetic resolution of an intramolecular vinylogous Michael reaction to access [6.6.5]-tricyclic chiral skeletons.Dan LiYuling YangMinmin ZhangLinqing WangYingfan XuDongxu YangRui WangNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-10 (2020) |
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Science Q Dan Li Yuling Yang Minmin Zhang Linqing Wang Yingfan Xu Dongxu Yang Rui Wang Activation of allylic esters in an intramolecular vinylogous kinetic resolution reaction with synergistic magnesium catalysts |
description |
Kinetic resolution allows to obtain enantioenriched compounds from racemic mixtures. Here, the authors report a synergistic magnesium catalyst promoting kinetic resolution of an intramolecular vinylogous Michael reaction to access [6.6.5]-tricyclic chiral skeletons. |
format |
article |
author |
Dan Li Yuling Yang Minmin Zhang Linqing Wang Yingfan Xu Dongxu Yang Rui Wang |
author_facet |
Dan Li Yuling Yang Minmin Zhang Linqing Wang Yingfan Xu Dongxu Yang Rui Wang |
author_sort |
Dan Li |
title |
Activation of allylic esters in an intramolecular vinylogous kinetic resolution reaction with synergistic magnesium catalysts |
title_short |
Activation of allylic esters in an intramolecular vinylogous kinetic resolution reaction with synergistic magnesium catalysts |
title_full |
Activation of allylic esters in an intramolecular vinylogous kinetic resolution reaction with synergistic magnesium catalysts |
title_fullStr |
Activation of allylic esters in an intramolecular vinylogous kinetic resolution reaction with synergistic magnesium catalysts |
title_full_unstemmed |
Activation of allylic esters in an intramolecular vinylogous kinetic resolution reaction with synergistic magnesium catalysts |
title_sort |
activation of allylic esters in an intramolecular vinylogous kinetic resolution reaction with synergistic magnesium catalysts |
publisher |
Nature Portfolio |
publishDate |
2020 |
url |
https://doaj.org/article/f213bfe77c9f4fbf901b3b506a51692b |
work_keys_str_mv |
AT danli activationofallylicestersinanintramolecularvinylogouskineticresolutionreactionwithsynergisticmagnesiumcatalysts AT yulingyang activationofallylicestersinanintramolecularvinylogouskineticresolutionreactionwithsynergisticmagnesiumcatalysts AT minminzhang activationofallylicestersinanintramolecularvinylogouskineticresolutionreactionwithsynergisticmagnesiumcatalysts AT linqingwang activationofallylicestersinanintramolecularvinylogouskineticresolutionreactionwithsynergisticmagnesiumcatalysts AT yingfanxu activationofallylicestersinanintramolecularvinylogouskineticresolutionreactionwithsynergisticmagnesiumcatalysts AT dongxuyang activationofallylicestersinanintramolecularvinylogouskineticresolutionreactionwithsynergisticmagnesiumcatalysts AT ruiwang activationofallylicestersinanintramolecularvinylogouskineticresolutionreactionwithsynergisticmagnesiumcatalysts |
_version_ |
1718385785175015424 |