Activation of allylic esters in an intramolecular vinylogous kinetic resolution reaction with synergistic magnesium catalysts

Kinetic resolution allows to obtain enantioenriched compounds from racemic mixtures. Here, the authors report a synergistic magnesium catalyst promoting kinetic resolution of an intramolecular vinylogous Michael reaction to access [6.6.5]-tricyclic chiral skeletons.

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Auteurs principaux:	Dan Li, Yuling Yang, Minmin Zhang, Linqing Wang, Yingfan Xu, Dongxu Yang, Rui Wang
Format:	article
Langue:	EN
Publié:	Nature Portfolio 2020
Sujets:	Science Q
Accès en ligne:	https://doaj.org/article/f213bfe77c9f4fbf901b3b506a51692b
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spelling	oai:doaj.org-article:f213bfe77c9f4fbf901b3b506a51692b2021-12-02T15:45:30ZActivation of allylic esters in an intramolecular vinylogous kinetic resolution reaction with synergistic magnesium catalysts10.1038/s41467-020-16486-02041-1723https://doaj.org/article/f213bfe77c9f4fbf901b3b506a51692b2020-05-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-16486-0https://doaj.org/toc/2041-1723Kinetic resolution allows to obtain enantioenriched compounds from racemic mixtures. Here, the authors report a synergistic magnesium catalyst promoting kinetic resolution of an intramolecular vinylogous Michael reaction to access [6.6.5]-tricyclic chiral skeletons.Dan LiYuling YangMinmin ZhangLinqing WangYingfan XuDongxu YangRui WangNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-10 (2020)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Dan Li Yuling Yang Minmin Zhang Linqing Wang Yingfan Xu Dongxu Yang Rui Wang Activation of allylic esters in an intramolecular vinylogous kinetic resolution reaction with synergistic magnesium catalysts
description	Kinetic resolution allows to obtain enantioenriched compounds from racemic mixtures. Here, the authors report a synergistic magnesium catalyst promoting kinetic resolution of an intramolecular vinylogous Michael reaction to access [6.6.5]-tricyclic chiral skeletons.
format	article
author	Dan Li Yuling Yang Minmin Zhang Linqing Wang Yingfan Xu Dongxu Yang Rui Wang
author_facet	Dan Li Yuling Yang Minmin Zhang Linqing Wang Yingfan Xu Dongxu Yang Rui Wang
author_sort	Dan Li
title	Activation of allylic esters in an intramolecular vinylogous kinetic resolution reaction with synergistic magnesium catalysts
title_short	Activation of allylic esters in an intramolecular vinylogous kinetic resolution reaction with synergistic magnesium catalysts
title_full	Activation of allylic esters in an intramolecular vinylogous kinetic resolution reaction with synergistic magnesium catalysts
title_fullStr	Activation of allylic esters in an intramolecular vinylogous kinetic resolution reaction with synergistic magnesium catalysts
title_full_unstemmed	Activation of allylic esters in an intramolecular vinylogous kinetic resolution reaction with synergistic magnesium catalysts
title_sort	activation of allylic esters in an intramolecular vinylogous kinetic resolution reaction with synergistic magnesium catalysts
publisher	Nature Portfolio
publishDate	2020
url	https://doaj.org/article/f213bfe77c9f4fbf901b3b506a51692b
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Activation of allylic esters in an intramolecular vinylogous kinetic resolution reaction with synergistic magnesium catalysts

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