Pseudohomogeneous metallic catalyst based on tungstate-decorated amphiphilic carbon quantum dots for selective oxidative scission of alkenes to aldehyde

Abstract Herein, we present an interesting role of tungstate-decorated amphiphilic carbon quantum dots (A-CQDs/W) in the selective oxidative cleavage of alkenes to aldehydes. In this work, for the first time, we disclose an unprecedented tungstate-based oxidative system incorporating A-CQDs as a bri...

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Autores principales: Aram Rezaei, Leila Hadian-Dehkordi, Hadi Samadian, Mehdi Jaymand, Homa Targhan, Ali Ramazani, Hadi Adibi, Xiaolei Deng, Lingxia Zheng, Huajun Zheng
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Publicado: Nature Portfolio 2021
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spelling oai:doaj.org-article:f23f7c4a959d4a538fdae41ef9309b5b2021-12-02T13:34:46ZPseudohomogeneous metallic catalyst based on tungstate-decorated amphiphilic carbon quantum dots for selective oxidative scission of alkenes to aldehyde10.1038/s41598-021-83863-02045-2322https://doaj.org/article/f23f7c4a959d4a538fdae41ef9309b5b2021-02-01T00:00:00Zhttps://doi.org/10.1038/s41598-021-83863-0https://doaj.org/toc/2045-2322Abstract Herein, we present an interesting role of tungstate-decorated amphiphilic carbon quantum dots (A-CQDs/W) in the selective oxidative cleavage of alkenes to aldehydes. In this work, for the first time, we disclose an unprecedented tungstate-based oxidative system incorporating A-CQDs as a bridge to the homogeneous catalyst for selective and efficient cleavage of a wide substrate scope of alkenes into aldehydes. The A-CQDs/W were synthesized via a one-step hydrothermal synthesis approach using 1-aminopropyl-3-methyl-imidazolium chloride and stearic acid for the surface modification, following by anion-exchange to immobilize WO4 –2 to A-CQDs. The A-CQDs/W act as a pseudohomogeneous metallic catalyst (PMC) for selective oxidative scission of alkenes under phase transfer catalysts (PTC) free condition without over oxidation to acids, using water and H2O2 as a green oxidant. Thanks to the sub-nanometric size and novel engineered chemical structure, this PMC and reactants are in the same phase, besides they can be easily isolated from each other by extraction processes. The synthesized PMC exhibited excellent solubility and stability in various solvents. Interestingly, the system’s high conversion efficiency was preserved even after eight catalytic cycles indicating the recyclability of the synthesized PMC. We believe that this study provides a significant and conceptually novel advance in oxidative cleavage chemistry.Aram RezaeiLeila Hadian-DehkordiHadi SamadianMehdi JaymandHoma TarghanAli RamazaniHadi AdibiXiaolei DengLingxia ZhengHuajun ZhengNature PortfolioarticleMedicineRScienceQENScientific Reports, Vol 11, Iss 1, Pp 1-13 (2021)
institution DOAJ
collection DOAJ
language EN
topic Medicine
R
Science
Q
spellingShingle Medicine
R
Science
Q
Aram Rezaei
Leila Hadian-Dehkordi
Hadi Samadian
Mehdi Jaymand
Homa Targhan
Ali Ramazani
Hadi Adibi
Xiaolei Deng
Lingxia Zheng
Huajun Zheng
Pseudohomogeneous metallic catalyst based on tungstate-decorated amphiphilic carbon quantum dots for selective oxidative scission of alkenes to aldehyde
description Abstract Herein, we present an interesting role of tungstate-decorated amphiphilic carbon quantum dots (A-CQDs/W) in the selective oxidative cleavage of alkenes to aldehydes. In this work, for the first time, we disclose an unprecedented tungstate-based oxidative system incorporating A-CQDs as a bridge to the homogeneous catalyst for selective and efficient cleavage of a wide substrate scope of alkenes into aldehydes. The A-CQDs/W were synthesized via a one-step hydrothermal synthesis approach using 1-aminopropyl-3-methyl-imidazolium chloride and stearic acid for the surface modification, following by anion-exchange to immobilize WO4 –2 to A-CQDs. The A-CQDs/W act as a pseudohomogeneous metallic catalyst (PMC) for selective oxidative scission of alkenes under phase transfer catalysts (PTC) free condition without over oxidation to acids, using water and H2O2 as a green oxidant. Thanks to the sub-nanometric size and novel engineered chemical structure, this PMC and reactants are in the same phase, besides they can be easily isolated from each other by extraction processes. The synthesized PMC exhibited excellent solubility and stability in various solvents. Interestingly, the system’s high conversion efficiency was preserved even after eight catalytic cycles indicating the recyclability of the synthesized PMC. We believe that this study provides a significant and conceptually novel advance in oxidative cleavage chemistry.
format article
author Aram Rezaei
Leila Hadian-Dehkordi
Hadi Samadian
Mehdi Jaymand
Homa Targhan
Ali Ramazani
Hadi Adibi
Xiaolei Deng
Lingxia Zheng
Huajun Zheng
author_facet Aram Rezaei
Leila Hadian-Dehkordi
Hadi Samadian
Mehdi Jaymand
Homa Targhan
Ali Ramazani
Hadi Adibi
Xiaolei Deng
Lingxia Zheng
Huajun Zheng
author_sort Aram Rezaei
title Pseudohomogeneous metallic catalyst based on tungstate-decorated amphiphilic carbon quantum dots for selective oxidative scission of alkenes to aldehyde
title_short Pseudohomogeneous metallic catalyst based on tungstate-decorated amphiphilic carbon quantum dots for selective oxidative scission of alkenes to aldehyde
title_full Pseudohomogeneous metallic catalyst based on tungstate-decorated amphiphilic carbon quantum dots for selective oxidative scission of alkenes to aldehyde
title_fullStr Pseudohomogeneous metallic catalyst based on tungstate-decorated amphiphilic carbon quantum dots for selective oxidative scission of alkenes to aldehyde
title_full_unstemmed Pseudohomogeneous metallic catalyst based on tungstate-decorated amphiphilic carbon quantum dots for selective oxidative scission of alkenes to aldehyde
title_sort pseudohomogeneous metallic catalyst based on tungstate-decorated amphiphilic carbon quantum dots for selective oxidative scission of alkenes to aldehyde
publisher Nature Portfolio
publishDate 2021
url https://doaj.org/article/f23f7c4a959d4a538fdae41ef9309b5b
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