Catalytic enantioselective C(sp 3)–H functionalization involving radical intermediates
Enantioselective functionalization of ubiquitous C(sp3)–H bonds via radical species has witnessed a renaissance in the past years. Here, the authors summarize the main achievements in the field by identifying two main reaction pathways determining the stereochemistry and give an outlook on future ch...
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Nature Portfolio
2021
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oai:doaj.org-article:f28f20eec4be4ea6b4db528d8daffcbb2021-12-02T14:18:54ZCatalytic enantioselective C(sp 3)–H functionalization involving radical intermediates10.1038/s41467-020-20770-42041-1723https://doaj.org/article/f28f20eec4be4ea6b4db528d8daffcbb2021-01-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-20770-4https://doaj.org/toc/2041-1723Enantioselective functionalization of ubiquitous C(sp3)–H bonds via radical species has witnessed a renaissance in the past years. Here, the authors summarize the main achievements in the field by identifying two main reaction pathways determining the stereochemistry and give an outlook on future challenges and opportunities.Chi ZhangZhong-Liang LiQiang-Shuai GuXin-Yuan LiuNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-9 (2021) |
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Science Q Chi Zhang Zhong-Liang Li Qiang-Shuai Gu Xin-Yuan Liu Catalytic enantioselective C(sp 3)–H functionalization involving radical intermediates |
description |
Enantioselective functionalization of ubiquitous C(sp3)–H bonds via radical species has witnessed a renaissance in the past years. Here, the authors summarize the main achievements in the field by identifying two main reaction pathways determining the stereochemistry and give an outlook on future challenges and opportunities. |
format |
article |
author |
Chi Zhang Zhong-Liang Li Qiang-Shuai Gu Xin-Yuan Liu |
author_facet |
Chi Zhang Zhong-Liang Li Qiang-Shuai Gu Xin-Yuan Liu |
author_sort |
Chi Zhang |
title |
Catalytic enantioselective C(sp 3)–H functionalization involving radical intermediates |
title_short |
Catalytic enantioselective C(sp 3)–H functionalization involving radical intermediates |
title_full |
Catalytic enantioselective C(sp 3)–H functionalization involving radical intermediates |
title_fullStr |
Catalytic enantioselective C(sp 3)–H functionalization involving radical intermediates |
title_full_unstemmed |
Catalytic enantioselective C(sp 3)–H functionalization involving radical intermediates |
title_sort |
catalytic enantioselective c(sp 3)–h functionalization involving radical intermediates |
publisher |
Nature Portfolio |
publishDate |
2021 |
url |
https://doaj.org/article/f28f20eec4be4ea6b4db528d8daffcbb |
work_keys_str_mv |
AT chizhang catalyticenantioselectivecsp3hfunctionalizationinvolvingradicalintermediates AT zhongliangli catalyticenantioselectivecsp3hfunctionalizationinvolvingradicalintermediates AT qiangshuaigu catalyticenantioselectivecsp3hfunctionalizationinvolvingradicalintermediates AT xinyuanliu catalyticenantioselectivecsp3hfunctionalizationinvolvingradicalintermediates |
_version_ |
1718391641483509760 |