The Effect of Excessive Sulfate in the Li-Ion Battery Leachate on the Properties of Resynthesized Li[Ni1/3Co1/3Mn1/3]O2

In order to examine the effect of excessive sulfate in the leachate of spent Li-ion batteries (LIBs), LiNi1/3Co1/3Mn1/3O2 (pristine NCM) and sulfate-containing LiNi1/3Co1/3&l...

Descripción completa

Guardado en:

Detalles Bibliográficos
Autores principales:	Jimin Lee, Sanghyuk Park, Mincheol Beak, Sang Ryul Park, Ah Reum Lee, Suk Hyun Byun, Junho Song, Jeong Soo Sohn, Kyungjung Kwon
Formato:	article
Lenguaje:	EN
Publicado:	MDPI AG 2021
Materias:	Li-ion battery cathode material sulfate impurity leachate Technology T Electrical engineering. Electronics. Nuclear engineering TK1-9971 Engineering (General). Civil engineering (General) TA1-2040 Microscopy QH201-278.5 Descriptive and experimental mechanics QC120-168.85
Acceso en línea:	https://doaj.org/article/f34d760dfd154e119b0e64c2dc06bc3e
Etiquetas:	Agregar Etiqueta Sin Etiquetas, Sea el primero en etiquetar este registro!

id	oai:doaj.org-article:f34d760dfd154e119b0e64c2dc06bc3e
record_format	dspace
spelling	oai:doaj.org-article:f34d760dfd154e119b0e64c2dc06bc3e2021-11-11T18:11:07ZThe Effect of Excessive Sulfate in the Li-Ion Battery Leachate on the Properties of Resynthesized Li[Ni<sub>1/3</sub>Co<sub>1/3</sub>Mn<sub>1/3</sub>]O<sub>2</sub>10.3390/ma142166721996-1944https://doaj.org/article/f34d760dfd154e119b0e64c2dc06bc3e2021-11-01T00:00:00Zhttps://www.mdpi.com/1996-1944/14/21/6672https://doaj.org/toc/1996-1944In order to examine the effect of excessive sulfate in the leachate of spent Li-ion batteries (LIBs), LiNi<sub>1/3</sub>Co<sub>1/3</sub>Mn<sub>1/3</sub>O<sub>2</sub> (pristine NCM) and sulfate-containing LiNi<sub>1/3</sub>Co<sub>1/3</sub>Mn<sub>1/3</sub>O<sub>2</sub> (NCMS) are prepared by a co-precipitation method. The crystal structures, morphology, surface species, and electrochemical performances of both cathode active materials are studied by scanning electron microscopy (SEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and charge-discharge tests. The XRD patterns and XPS results identify the presence of sulfate groups on the surface of NCMS. While pristine NCM exhibits a very dense surface in SEM images, NCMS has a relatively porous surface, which could be attributed to the sulfate impurities that hinder the growth of primary particles. The charge-discharge tests show that discharge capacities of NCMS at C-rates, which range from 0.1 to 5 C, are slightly decreased compared to pristine NCM. In dQ/dV plots, pristine NCM and NCMS have the same redox overvoltage regardless of discharge C-rates. The omnipresent sulfate due to the sulfuric acid leaching of spent LIBs has a minimal effect on resynthesized NCM cathode active materials as long as their precursors are adequately washed.Jimin LeeSanghyuk ParkMincheol BeakSang Ryul ParkAh Reum LeeSuk Hyun ByunJunho SongJeong Soo SohnKyungjung KwonMDPI AGarticleLi-ion batterycathode materialsulfateimpurityleachateTechnologyTElectrical engineering. Electronics. Nuclear engineeringTK1-9971Engineering (General). Civil engineering (General)TA1-2040MicroscopyQH201-278.5Descriptive and experimental mechanicsQC120-168.85ENMaterials, Vol 14, Iss 6672, p 6672 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Li-ion battery cathode material sulfate impurity leachate Technology T Electrical engineering. Electronics. Nuclear engineering TK1-9971 Engineering (General). Civil engineering (General) TA1-2040 Microscopy QH201-278.5 Descriptive and experimental mechanics QC120-168.85
spellingShingle	Li-ion battery cathode material sulfate impurity leachate Technology T Electrical engineering. Electronics. Nuclear engineering TK1-9971 Engineering (General). Civil engineering (General) TA1-2040 Microscopy QH201-278.5 Descriptive and experimental mechanics QC120-168.85 Jimin Lee Sanghyuk Park Mincheol Beak Sang Ryul Park Ah Reum Lee Suk Hyun Byun Junho Song Jeong Soo Sohn Kyungjung Kwon The Effect of Excessive Sulfate in the Li-Ion Battery Leachate on the Properties of Resynthesized Li[Ni<sub>1/3</sub>Co<sub>1/3</sub>Mn<sub>1/3</sub>]O<sub>2</sub>
description	In order to examine the effect of excessive sulfate in the leachate of spent Li-ion batteries (LIBs), LiNi<sub>1/3</sub>Co<sub>1/3</sub>Mn<sub>1/3</sub>O<sub>2</sub> (pristine NCM) and sulfate-containing LiNi<sub>1/3</sub>Co<sub>1/3</sub>Mn<sub>1/3</sub>O<sub>2</sub> (NCMS) are prepared by a co-precipitation method. The crystal structures, morphology, surface species, and electrochemical performances of both cathode active materials are studied by scanning electron microscopy (SEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and charge-discharge tests. The XRD patterns and XPS results identify the presence of sulfate groups on the surface of NCMS. While pristine NCM exhibits a very dense surface in SEM images, NCMS has a relatively porous surface, which could be attributed to the sulfate impurities that hinder the growth of primary particles. The charge-discharge tests show that discharge capacities of NCMS at C-rates, which range from 0.1 to 5 C, are slightly decreased compared to pristine NCM. In dQ/dV plots, pristine NCM and NCMS have the same redox overvoltage regardless of discharge C-rates. The omnipresent sulfate due to the sulfuric acid leaching of spent LIBs has a minimal effect on resynthesized NCM cathode active materials as long as their precursors are adequately washed.
format	article
author	Jimin Lee Sanghyuk Park Mincheol Beak Sang Ryul Park Ah Reum Lee Suk Hyun Byun Junho Song Jeong Soo Sohn Kyungjung Kwon
author_facet	Jimin Lee Sanghyuk Park Mincheol Beak Sang Ryul Park Ah Reum Lee Suk Hyun Byun Junho Song Jeong Soo Sohn Kyungjung Kwon
author_sort	Jimin Lee
title	The Effect of Excessive Sulfate in the Li-Ion Battery Leachate on the Properties of Resynthesized Li[Ni<sub>1/3</sub>Co<sub>1/3</sub>Mn<sub>1/3</sub>]O<sub>2</sub>
title_short	The Effect of Excessive Sulfate in the Li-Ion Battery Leachate on the Properties of Resynthesized Li[Ni<sub>1/3</sub>Co<sub>1/3</sub>Mn<sub>1/3</sub>]O<sub>2</sub>
title_full	The Effect of Excessive Sulfate in the Li-Ion Battery Leachate on the Properties of Resynthesized Li[Ni<sub>1/3</sub>Co<sub>1/3</sub>Mn<sub>1/3</sub>]O<sub>2</sub>
title_fullStr	The Effect of Excessive Sulfate in the Li-Ion Battery Leachate on the Properties of Resynthesized Li[Ni<sub>1/3</sub>Co<sub>1/3</sub>Mn<sub>1/3</sub>]O<sub>2</sub>
title_full_unstemmed	The Effect of Excessive Sulfate in the Li-Ion Battery Leachate on the Properties of Resynthesized Li[Ni<sub>1/3</sub>Co<sub>1/3</sub>Mn<sub>1/3</sub>]O<sub>2</sub>
title_sort	effect of excessive sulfate in the li-ion battery leachate on the properties of resynthesized li[ni<sub>1/3</sub>co<sub>1/3</sub>mn<sub>1/3</sub>]o<sub>2</sub>
publisher	MDPI AG
publishDate	2021
url	https://doaj.org/article/f34d760dfd154e119b0e64c2dc06bc3e
work_keys_str_mv	AT jiminlee theeffectofexcessivesulfateintheliionbatteryleachateonthepropertiesofresynthesizedlinisub13subcosub13submnsub13subosub2sub AT sanghyukpark theeffectofexcessivesulfateintheliionbatteryleachateonthepropertiesofresynthesizedlinisub13subcosub13submnsub13subosub2sub AT mincheolbeak theeffectofexcessivesulfateintheliionbatteryleachateonthepropertiesofresynthesizedlinisub13subcosub13submnsub13subosub2sub AT sangryulpark theeffectofexcessivesulfateintheliionbatteryleachateonthepropertiesofresynthesizedlinisub13subcosub13submnsub13subosub2sub AT ahreumlee theeffectofexcessivesulfateintheliionbatteryleachateonthepropertiesofresynthesizedlinisub13subcosub13submnsub13subosub2sub AT sukhyunbyun theeffectofexcessivesulfateintheliionbatteryleachateonthepropertiesofresynthesizedlinisub13subcosub13submnsub13subosub2sub AT junhosong theeffectofexcessivesulfateintheliionbatteryleachateonthepropertiesofresynthesizedlinisub13subcosub13submnsub13subosub2sub AT jeongsoosohn theeffectofexcessivesulfateintheliionbatteryleachateonthepropertiesofresynthesizedlinisub13subcosub13submnsub13subosub2sub AT kyungjungkwon theeffectofexcessivesulfateintheliionbatteryleachateonthepropertiesofresynthesizedlinisub13subcosub13submnsub13subosub2sub AT jiminlee effectofexcessivesulfateintheliionbatteryleachateonthepropertiesofresynthesizedlinisub13subcosub13submnsub13subosub2sub AT sanghyukpark effectofexcessivesulfateintheliionbatteryleachateonthepropertiesofresynthesizedlinisub13subcosub13submnsub13subosub2sub AT mincheolbeak effectofexcessivesulfateintheliionbatteryleachateonthepropertiesofresynthesizedlinisub13subcosub13submnsub13subosub2sub AT sangryulpark effectofexcessivesulfateintheliionbatteryleachateonthepropertiesofresynthesizedlinisub13subcosub13submnsub13subosub2sub AT ahreumlee effectofexcessivesulfateintheliionbatteryleachateonthepropertiesofresynthesizedlinisub13subcosub13submnsub13subosub2sub AT sukhyunbyun effectofexcessivesulfateintheliionbatteryleachateonthepropertiesofresynthesizedlinisub13subcosub13submnsub13subosub2sub AT junhosong effectofexcessivesulfateintheliionbatteryleachateonthepropertiesofresynthesizedlinisub13subcosub13submnsub13subosub2sub AT jeongsoosohn effectofexcessivesulfateintheliionbatteryleachateonthepropertiesofresynthesizedlinisub13subcosub13submnsub13subosub2sub AT kyungjungkwon effectofexcessivesulfateintheliionbatteryleachateonthepropertiesofresynthesizedlinisub13subcosub13submnsub13subosub2sub
_version_	1718431918796570624

The Effect of Excessive Sulfate in the Li-Ion Battery Leachate on the Properties of Resynthesized Li[Ni<sub>1/3</sub>Co<sub>1/3</sub>Mn<sub>1/3</sub>]O<sub>2</sub>

Ejemplares similares