Structural study of mono- and binuclear 2,6-Diacetylpyridine bis(nicotinoylhydrazone) coordination compounds
2,6-Diacetylpyridine bis(nicotinoylhydrazone) (H2L) represents a Schiff base condensation product of 2,6-diacetylpyridine and nicotinic acid hydrazide and may represent a versatile ligand for a variety of research objectives because it has multiple coordination sites. In this review, the design of s...
Guardado en:
| Autor principal: | |
|---|---|
| Formato: | article |
| Lenguaje: | EN |
| Publicado: |
D.Ghitu Institute of Electronic Engineering and Nanotechnologies
2018
|
| Materias: | |
| Acceso en línea: | https://doaj.org/article/f357231d48ad4efb8ce67b2aae4b304f |
| Etiquetas: |
Agregar Etiqueta
Sin Etiquetas, Sea el primero en etiquetar este registro!
|
| Sumario: | 2,6-Diacetylpyridine bis(nicotinoylhydrazone) (H2L) represents a Schiff base condensation product of 2,6-diacetylpyridine and nicotinic acid hydrazide and may represent a versatile ligand for a variety of research objectives because it has multiple coordination sites. In this review, the design of seven coordination compounds of the title ligand H2L with some transition metals-V(II, IV), Fe(III), and Co(II)-is reported. The V(IV), Fe(III), and Co(II) metals give rise to the mononuclear compounds where the metal cations form pentagonal bipyramids, while V(II) forms a binuclear compound with the metal in a tetragonal pyramid environment. The characteristic IR oscillations of H2L in all complexes and promising adsorption properties are analyzed. |
|---|