Aryl radical-mediated N-heterocyclic carbene catalysis

Use of aryl halides as coupling precursors typically occurs through transition metal catalysis and/or photoredox chemistry, which requires some combination of light, metals, and oxidants or reductants. Here, the authors show a method to generate aryl radicals from halides using only an NHC organocat...

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Autores principales:	Yuki Matsuki, Nagisa Ohnishi, Yuki Kakeno, Shunsuke Takemoto, Takuya Ishii, Kazunori Nagao, Hirohisa Ohmiya
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/f36b6c5bc0004213ae418b24ec57fb2a
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spelling	oai:doaj.org-article:f36b6c5bc0004213ae418b24ec57fb2a2021-12-02T16:05:50ZAryl radical-mediated N-heterocyclic carbene catalysis10.1038/s41467-021-24144-22041-1723https://doaj.org/article/f36b6c5bc0004213ae418b24ec57fb2a2021-06-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-24144-2https://doaj.org/toc/2041-1723Use of aryl halides as coupling precursors typically occurs through transition metal catalysis and/or photoredox chemistry, which requires some combination of light, metals, and oxidants or reductants. Here, the authors show a method to generate aryl radicals from halides using only an NHC organocatalyst.Yuki MatsukiNagisa OhnishiYuki KakenoShunsuke TakemotoTakuya IshiiKazunori NagaoHirohisa OhmiyaNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-8 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Yuki Matsuki Nagisa Ohnishi Yuki Kakeno Shunsuke Takemoto Takuya Ishii Kazunori Nagao Hirohisa Ohmiya Aryl radical-mediated N-heterocyclic carbene catalysis
description	Use of aryl halides as coupling precursors typically occurs through transition metal catalysis and/or photoredox chemistry, which requires some combination of light, metals, and oxidants or reductants. Here, the authors show a method to generate aryl radicals from halides using only an NHC organocatalyst.
format	article
author	Yuki Matsuki Nagisa Ohnishi Yuki Kakeno Shunsuke Takemoto Takuya Ishii Kazunori Nagao Hirohisa Ohmiya
author_facet	Yuki Matsuki Nagisa Ohnishi Yuki Kakeno Shunsuke Takemoto Takuya Ishii Kazunori Nagao Hirohisa Ohmiya
author_sort	Yuki Matsuki
title	Aryl radical-mediated N-heterocyclic carbene catalysis
title_short	Aryl radical-mediated N-heterocyclic carbene catalysis
title_full	Aryl radical-mediated N-heterocyclic carbene catalysis
title_fullStr	Aryl radical-mediated N-heterocyclic carbene catalysis
title_full_unstemmed	Aryl radical-mediated N-heterocyclic carbene catalysis
title_sort	aryl radical-mediated n-heterocyclic carbene catalysis
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/f36b6c5bc0004213ae418b24ec57fb2a
work_keys_str_mv	AT yukimatsuki arylradicalmediatednheterocycliccarbenecatalysis AT nagisaohnishi arylradicalmediatednheterocycliccarbenecatalysis AT yukikakeno arylradicalmediatednheterocycliccarbenecatalysis AT shunsuketakemoto arylradicalmediatednheterocycliccarbenecatalysis AT takuyaishii arylradicalmediatednheterocycliccarbenecatalysis AT kazunorinagao arylradicalmediatednheterocycliccarbenecatalysis AT hirohisaohmiya arylradicalmediatednheterocycliccarbenecatalysis
_version_	1718385184485670912

Aryl radical-mediated N-heterocyclic carbene catalysis

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