Bio-Zirconium Metal–Organic Framework Regenerable Bio-Beads for the Effective Removal of Organophosphates from Polluted Water

Organophosphate-based pesticides, such as diazinon, are among the most toxic organic contaminants to human and environment. Effective removal of diazinon from contaminated water sources is critical. Zirconium Metal−organic frameworks (Zr-MOFs) are promising candidates for the removal of organic cont...

Descripción completa

Guardado en:
Detalles Bibliográficos
Autores principales: Kamal E. Diab, Eslam Salama, Hassan Shokry Hassan, Ahmed Abd El-moneim, Marwa F. Elkady
Formato: article
Lenguaje:EN
Publicado: MDPI AG 2021
Materias:
Acceso en línea:https://doaj.org/article/f384ce8ccf194d119b62206ebc81ff59
Etiquetas: Agregar Etiqueta
Sin Etiquetas, Sea el primero en etiquetar este registro!
id oai:doaj.org-article:f384ce8ccf194d119b62206ebc81ff59
record_format dspace
spelling oai:doaj.org-article:f384ce8ccf194d119b62206ebc81ff592021-11-25T18:47:47ZBio-Zirconium Metal–Organic Framework Regenerable Bio-Beads for the Effective Removal of Organophosphates from Polluted Water10.3390/polym132238692073-4360https://doaj.org/article/f384ce8ccf194d119b62206ebc81ff592021-11-01T00:00:00Zhttps://www.mdpi.com/2073-4360/13/22/3869https://doaj.org/toc/2073-4360Organophosphate-based pesticides, such as diazinon, are among the most toxic organic contaminants to human and environment. Effective removal of diazinon from contaminated water sources is critical. Zirconium Metal−organic frameworks (Zr-MOFs) are promising candidates for the removal of organic contaminants from wastewater. Herein, we report the adequacy of a bio based Zr-MOF named MIP-202 for the removal of diazinon from water. On the other hand, the use of these materials in powder form is not workable, the development of scalable and economical processes and integrative of these materials onto beads is paramount for industrial processes. Hence, it was reported a scalable, bio aqueous solution-based preparation strategy for Bio Zr-MOF beads production. The composite material exposed identical reactivity under the same ambient parameters compared to powdered material in an aqueous solution. These results signify a critical procedure to an integrated strategy for organophosphates removal using bio-based MOFs, which demonstrates high potential for manufacturing applications such as continued removal of organophosphates from wastewater supplies.Kamal E. DiabEslam SalamaHassan Shokry HassanAhmed Abd El-moneimMarwa F. ElkadyMDPI AGarticlezirconium metal−organic frameworksMIP-202diazinonpesticidesBio Zr-MOF beadsorganophosphates wastewaterOrganic chemistryQD241-441ENPolymers, Vol 13, Iss 3869, p 3869 (2021)
institution DOAJ
collection DOAJ
language EN
topic zirconium metal−organic frameworks
MIP-202
diazinon
pesticides
Bio Zr-MOF beads
organophosphates wastewater
Organic chemistry
QD241-441
spellingShingle zirconium metal−organic frameworks
MIP-202
diazinon
pesticides
Bio Zr-MOF beads
organophosphates wastewater
Organic chemistry
QD241-441
Kamal E. Diab
Eslam Salama
Hassan Shokry Hassan
Ahmed Abd El-moneim
Marwa F. Elkady
Bio-Zirconium Metal–Organic Framework Regenerable Bio-Beads for the Effective Removal of Organophosphates from Polluted Water
description Organophosphate-based pesticides, such as diazinon, are among the most toxic organic contaminants to human and environment. Effective removal of diazinon from contaminated water sources is critical. Zirconium Metal−organic frameworks (Zr-MOFs) are promising candidates for the removal of organic contaminants from wastewater. Herein, we report the adequacy of a bio based Zr-MOF named MIP-202 for the removal of diazinon from water. On the other hand, the use of these materials in powder form is not workable, the development of scalable and economical processes and integrative of these materials onto beads is paramount for industrial processes. Hence, it was reported a scalable, bio aqueous solution-based preparation strategy for Bio Zr-MOF beads production. The composite material exposed identical reactivity under the same ambient parameters compared to powdered material in an aqueous solution. These results signify a critical procedure to an integrated strategy for organophosphates removal using bio-based MOFs, which demonstrates high potential for manufacturing applications such as continued removal of organophosphates from wastewater supplies.
format article
author Kamal E. Diab
Eslam Salama
Hassan Shokry Hassan
Ahmed Abd El-moneim
Marwa F. Elkady
author_facet Kamal E. Diab
Eslam Salama
Hassan Shokry Hassan
Ahmed Abd El-moneim
Marwa F. Elkady
author_sort Kamal E. Diab
title Bio-Zirconium Metal–Organic Framework Regenerable Bio-Beads for the Effective Removal of Organophosphates from Polluted Water
title_short Bio-Zirconium Metal–Organic Framework Regenerable Bio-Beads for the Effective Removal of Organophosphates from Polluted Water
title_full Bio-Zirconium Metal–Organic Framework Regenerable Bio-Beads for the Effective Removal of Organophosphates from Polluted Water
title_fullStr Bio-Zirconium Metal–Organic Framework Regenerable Bio-Beads for the Effective Removal of Organophosphates from Polluted Water
title_full_unstemmed Bio-Zirconium Metal–Organic Framework Regenerable Bio-Beads for the Effective Removal of Organophosphates from Polluted Water
title_sort bio-zirconium metal–organic framework regenerable bio-beads for the effective removal of organophosphates from polluted water
publisher MDPI AG
publishDate 2021
url https://doaj.org/article/f384ce8ccf194d119b62206ebc81ff59
work_keys_str_mv AT kamalediab biozirconiummetalorganicframeworkregenerablebiobeadsfortheeffectiveremovaloforganophosphatesfrompollutedwater
AT eslamsalama biozirconiummetalorganicframeworkregenerablebiobeadsfortheeffectiveremovaloforganophosphatesfrompollutedwater
AT hassanshokryhassan biozirconiummetalorganicframeworkregenerablebiobeadsfortheeffectiveremovaloforganophosphatesfrompollutedwater
AT ahmedabdelmoneim biozirconiummetalorganicframeworkregenerablebiobeadsfortheeffectiveremovaloforganophosphatesfrompollutedwater
AT marwafelkady biozirconiummetalorganicframeworkregenerablebiobeadsfortheeffectiveremovaloforganophosphatesfrompollutedwater
_version_ 1718410749208952832