Acyl radical to rhodacycle addition and cyclization relay to access butterfly flavylium fluorophores
Structural diversity of organic fluorophores is of importance for several applications (fluorescent markers, photosensitizers, etc.). Here the authors report a method to merge radical chemistry with C–H activation to construct a brand-new class of flavylium fluorophores starting from (hetero)aryl ke...
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Nature Portfolio
2019
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oai:doaj.org-article:f39bf2979ad94b39a47b0a6c1e0b04242021-12-02T16:58:05ZAcyl radical to rhodacycle addition and cyclization relay to access butterfly flavylium fluorophores10.1038/s41467-019-13611-62041-1723https://doaj.org/article/f39bf2979ad94b39a47b0a6c1e0b04242019-12-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-13611-6https://doaj.org/toc/2041-1723Structural diversity of organic fluorophores is of importance for several applications (fluorescent markers, photosensitizers, etc.). Here the authors report a method to merge radical chemistry with C–H activation to construct a brand-new class of flavylium fluorophores starting from (hetero)aryl ketones and alkynes.Jiangliang YinYuming ZhangJian LiLei ZhuYu LanJingsong YouNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-8 (2019) |
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Science Q Jiangliang Yin Yuming Zhang Jian Li Lei Zhu Yu Lan Jingsong You Acyl radical to rhodacycle addition and cyclization relay to access butterfly flavylium fluorophores |
description |
Structural diversity of organic fluorophores is of importance for several applications (fluorescent markers, photosensitizers, etc.). Here the authors report a method to merge radical chemistry with C–H activation to construct a brand-new class of flavylium fluorophores starting from (hetero)aryl ketones and alkynes. |
format |
article |
author |
Jiangliang Yin Yuming Zhang Jian Li Lei Zhu Yu Lan Jingsong You |
author_facet |
Jiangliang Yin Yuming Zhang Jian Li Lei Zhu Yu Lan Jingsong You |
author_sort |
Jiangliang Yin |
title |
Acyl radical to rhodacycle addition and cyclization relay to access butterfly flavylium fluorophores |
title_short |
Acyl radical to rhodacycle addition and cyclization relay to access butterfly flavylium fluorophores |
title_full |
Acyl radical to rhodacycle addition and cyclization relay to access butterfly flavylium fluorophores |
title_fullStr |
Acyl radical to rhodacycle addition and cyclization relay to access butterfly flavylium fluorophores |
title_full_unstemmed |
Acyl radical to rhodacycle addition and cyclization relay to access butterfly flavylium fluorophores |
title_sort |
acyl radical to rhodacycle addition and cyclization relay to access butterfly flavylium fluorophores |
publisher |
Nature Portfolio |
publishDate |
2019 |
url |
https://doaj.org/article/f39bf2979ad94b39a47b0a6c1e0b0424 |
work_keys_str_mv |
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_version_ |
1718382422746202112 |