Acyl radical to rhodacycle addition and cyclization relay to access butterfly flavylium fluorophores

Structural diversity of organic fluorophores is of importance for several applications (fluorescent markers, photosensitizers, etc.). Here the authors report a method to merge radical chemistry with C–H activation to construct a brand-new class of flavylium fluorophores starting from (hetero)aryl ke...

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Autores principales: Jiangliang Yin, Yuming Zhang, Jian Li, Lei Zhu, Yu Lan, Jingsong You
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2019
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Acceso en línea:https://doaj.org/article/f39bf2979ad94b39a47b0a6c1e0b0424
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spelling oai:doaj.org-article:f39bf2979ad94b39a47b0a6c1e0b04242021-12-02T16:58:05ZAcyl radical to rhodacycle addition and cyclization relay to access butterfly flavylium fluorophores10.1038/s41467-019-13611-62041-1723https://doaj.org/article/f39bf2979ad94b39a47b0a6c1e0b04242019-12-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-13611-6https://doaj.org/toc/2041-1723Structural diversity of organic fluorophores is of importance for several applications (fluorescent markers, photosensitizers, etc.). Here the authors report a method to merge radical chemistry with C–H activation to construct a brand-new class of flavylium fluorophores starting from (hetero)aryl ketones and alkynes.Jiangliang YinYuming ZhangJian LiLei ZhuYu LanJingsong YouNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-8 (2019)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Jiangliang Yin
Yuming Zhang
Jian Li
Lei Zhu
Yu Lan
Jingsong You
Acyl radical to rhodacycle addition and cyclization relay to access butterfly flavylium fluorophores
description Structural diversity of organic fluorophores is of importance for several applications (fluorescent markers, photosensitizers, etc.). Here the authors report a method to merge radical chemistry with C–H activation to construct a brand-new class of flavylium fluorophores starting from (hetero)aryl ketones and alkynes.
format article
author Jiangliang Yin
Yuming Zhang
Jian Li
Lei Zhu
Yu Lan
Jingsong You
author_facet Jiangliang Yin
Yuming Zhang
Jian Li
Lei Zhu
Yu Lan
Jingsong You
author_sort Jiangliang Yin
title Acyl radical to rhodacycle addition and cyclization relay to access butterfly flavylium fluorophores
title_short Acyl radical to rhodacycle addition and cyclization relay to access butterfly flavylium fluorophores
title_full Acyl radical to rhodacycle addition and cyclization relay to access butterfly flavylium fluorophores
title_fullStr Acyl radical to rhodacycle addition and cyclization relay to access butterfly flavylium fluorophores
title_full_unstemmed Acyl radical to rhodacycle addition and cyclization relay to access butterfly flavylium fluorophores
title_sort acyl radical to rhodacycle addition and cyclization relay to access butterfly flavylium fluorophores
publisher Nature Portfolio
publishDate 2019
url https://doaj.org/article/f39bf2979ad94b39a47b0a6c1e0b0424
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