Acyl radical to rhodacycle addition and cyclization relay to access butterfly flavylium fluorophores

Structural diversity of organic fluorophores is of importance for several applications (fluorescent markers, photosensitizers, etc.). Here the authors report a method to merge radical chemistry with C–H activation to construct a brand-new class of flavylium fluorophores starting from (hetero)aryl ke...

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Main Authors:	Jiangliang Yin, Yuming Zhang, Jian Li, Lei Zhu, Yu Lan, Jingsong You
Format:	article
Language:	EN
Published:	Nature Portfolio 2019
Subjects:	Science Q
Online Access:	https://doaj.org/article/f39bf2979ad94b39a47b0a6c1e0b0424
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spelling	oai:doaj.org-article:f39bf2979ad94b39a47b0a6c1e0b04242021-12-02T16:58:05ZAcyl radical to rhodacycle addition and cyclization relay to access butterfly flavylium fluorophores10.1038/s41467-019-13611-62041-1723https://doaj.org/article/f39bf2979ad94b39a47b0a6c1e0b04242019-12-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-13611-6https://doaj.org/toc/2041-1723Structural diversity of organic fluorophores is of importance for several applications (fluorescent markers, photosensitizers, etc.). Here the authors report a method to merge radical chemistry with C–H activation to construct a brand-new class of flavylium fluorophores starting from (hetero)aryl ketones and alkynes.Jiangliang YinYuming ZhangJian LiLei ZhuYu LanJingsong YouNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-8 (2019)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Jiangliang Yin Yuming Zhang Jian Li Lei Zhu Yu Lan Jingsong You Acyl radical to rhodacycle addition and cyclization relay to access butterfly flavylium fluorophores
description	Structural diversity of organic fluorophores is of importance for several applications (fluorescent markers, photosensitizers, etc.). Here the authors report a method to merge radical chemistry with C–H activation to construct a brand-new class of flavylium fluorophores starting from (hetero)aryl ketones and alkynes.
format	article
author	Jiangliang Yin Yuming Zhang Jian Li Lei Zhu Yu Lan Jingsong You
author_facet	Jiangliang Yin Yuming Zhang Jian Li Lei Zhu Yu Lan Jingsong You
author_sort	Jiangliang Yin
title	Acyl radical to rhodacycle addition and cyclization relay to access butterfly flavylium fluorophores
title_short	Acyl radical to rhodacycle addition and cyclization relay to access butterfly flavylium fluorophores
title_full	Acyl radical to rhodacycle addition and cyclization relay to access butterfly flavylium fluorophores
title_fullStr	Acyl radical to rhodacycle addition and cyclization relay to access butterfly flavylium fluorophores
title_full_unstemmed	Acyl radical to rhodacycle addition and cyclization relay to access butterfly flavylium fluorophores
title_sort	acyl radical to rhodacycle addition and cyclization relay to access butterfly flavylium fluorophores
publisher	Nature Portfolio
publishDate	2019
url	https://doaj.org/article/f39bf2979ad94b39a47b0a6c1e0b0424
work_keys_str_mv	AT jiangliangyin acylradicaltorhodacycleadditionandcyclizationrelaytoaccessbutterflyflavyliumfluorophores AT yumingzhang acylradicaltorhodacycleadditionandcyclizationrelaytoaccessbutterflyflavyliumfluorophores AT jianli acylradicaltorhodacycleadditionandcyclizationrelaytoaccessbutterflyflavyliumfluorophores AT leizhu acylradicaltorhodacycleadditionandcyclizationrelaytoaccessbutterflyflavyliumfluorophores AT yulan acylradicaltorhodacycleadditionandcyclizationrelaytoaccessbutterflyflavyliumfluorophores AT jingsongyou acylradicaltorhodacycleadditionandcyclizationrelaytoaccessbutterflyflavyliumfluorophores
_version_	1718382422746202112

Acyl radical to rhodacycle addition and cyclization relay to access butterfly flavylium fluorophores

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