Facile synthesis of PEDOT-rGO/HKUST-1 for high performance symmetrical supercapacitor device
Abstract A novel poly(3,4-ethylenedioxythiophene)-reduced graphene oxide/copper-based metal–organic framework (PrGO/HKUST-1) has been successfully fabricated by incorporating electrochemically synthesized poly(3,4-ethylenedioxythiophene)-reduced graphene oxide (PrGO) and hydrothermally synthesized c...
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2021
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oai:doaj.org-article:f3aeb89bbf38445a8fbdb4c666ef1e4a2021-12-02T15:56:41ZFacile synthesis of PEDOT-rGO/HKUST-1 for high performance symmetrical supercapacitor device10.1038/s41598-021-91100-x2045-2322https://doaj.org/article/f3aeb89bbf38445a8fbdb4c666ef1e4a2021-06-01T00:00:00Zhttps://doi.org/10.1038/s41598-021-91100-xhttps://doaj.org/toc/2045-2322Abstract A novel poly(3,4-ethylenedioxythiophene)-reduced graphene oxide/copper-based metal–organic framework (PrGO/HKUST-1) has been successfully fabricated by incorporating electrochemically synthesized poly(3,4-ethylenedioxythiophene)-reduced graphene oxide (PrGO) and hydrothermally synthesized copper-based metal–organic framework (HKUST-1). The field emission scanning microscopy (FESEM) and elemental mapping analysis revealed an even distribution of poly(3,4-ethylenedioxythiophene) (PEDOT), reduced graphene oxide (rGO) and HKUST-1. The crystalline structure and vibration modes of PrGO/HKUST-1 were validated utilizing X-ray diffraction (XRD) as well as Raman spectroscopy, respectively. A remarkable specific capacitance (360.5 F/g) was obtained for PrGO/HKUST-1 compared to HKUST-1 (103.1 F/g), PrGO (98.5 F/g) and PEDOT (50.8 F/g) using KCl/PVA as a gel electrolyte. Moreover, PrGO/HKUST-1 composite with the longest charge/discharge time displayed excellent specific energy (21.0 Wh/kg), specific power (479.7 W/kg) and an outstanding cycle life (95.5%) over 4000 cycles. Thus, the PrGO/HKUST-1 can be recognized as a promising energy storage material.Dharshini MohanadasMuhammad Amirul Aizat Mohd AbdahNur Hawa Nabilah AzmanThahira B. S. A. RavoofYusran SulaimanNature PortfolioarticleMedicineRScienceQENScientific Reports, Vol 11, Iss 1, Pp 1-13 (2021) |
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Medicine R Science Q Dharshini Mohanadas Muhammad Amirul Aizat Mohd Abdah Nur Hawa Nabilah Azman Thahira B. S. A. Ravoof Yusran Sulaiman Facile synthesis of PEDOT-rGO/HKUST-1 for high performance symmetrical supercapacitor device |
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Abstract A novel poly(3,4-ethylenedioxythiophene)-reduced graphene oxide/copper-based metal–organic framework (PrGO/HKUST-1) has been successfully fabricated by incorporating electrochemically synthesized poly(3,4-ethylenedioxythiophene)-reduced graphene oxide (PrGO) and hydrothermally synthesized copper-based metal–organic framework (HKUST-1). The field emission scanning microscopy (FESEM) and elemental mapping analysis revealed an even distribution of poly(3,4-ethylenedioxythiophene) (PEDOT), reduced graphene oxide (rGO) and HKUST-1. The crystalline structure and vibration modes of PrGO/HKUST-1 were validated utilizing X-ray diffraction (XRD) as well as Raman spectroscopy, respectively. A remarkable specific capacitance (360.5 F/g) was obtained for PrGO/HKUST-1 compared to HKUST-1 (103.1 F/g), PrGO (98.5 F/g) and PEDOT (50.8 F/g) using KCl/PVA as a gel electrolyte. Moreover, PrGO/HKUST-1 composite with the longest charge/discharge time displayed excellent specific energy (21.0 Wh/kg), specific power (479.7 W/kg) and an outstanding cycle life (95.5%) over 4000 cycles. Thus, the PrGO/HKUST-1 can be recognized as a promising energy storage material. |
format |
article |
author |
Dharshini Mohanadas Muhammad Amirul Aizat Mohd Abdah Nur Hawa Nabilah Azman Thahira B. S. A. Ravoof Yusran Sulaiman |
author_facet |
Dharshini Mohanadas Muhammad Amirul Aizat Mohd Abdah Nur Hawa Nabilah Azman Thahira B. S. A. Ravoof Yusran Sulaiman |
author_sort |
Dharshini Mohanadas |
title |
Facile synthesis of PEDOT-rGO/HKUST-1 for high performance symmetrical supercapacitor device |
title_short |
Facile synthesis of PEDOT-rGO/HKUST-1 for high performance symmetrical supercapacitor device |
title_full |
Facile synthesis of PEDOT-rGO/HKUST-1 for high performance symmetrical supercapacitor device |
title_fullStr |
Facile synthesis of PEDOT-rGO/HKUST-1 for high performance symmetrical supercapacitor device |
title_full_unstemmed |
Facile synthesis of PEDOT-rGO/HKUST-1 for high performance symmetrical supercapacitor device |
title_sort |
facile synthesis of pedot-rgo/hkust-1 for high performance symmetrical supercapacitor device |
publisher |
Nature Portfolio |
publishDate |
2021 |
url |
https://doaj.org/article/f3aeb89bbf38445a8fbdb4c666ef1e4a |
work_keys_str_mv |
AT dharshinimohanadas facilesynthesisofpedotrgohkust1forhighperformancesymmetricalsupercapacitordevice AT muhammadamirulaizatmohdabdah facilesynthesisofpedotrgohkust1forhighperformancesymmetricalsupercapacitordevice AT nurhawanabilahazman facilesynthesisofpedotrgohkust1forhighperformancesymmetricalsupercapacitordevice AT thahirabsaravoof facilesynthesisofpedotrgohkust1forhighperformancesymmetricalsupercapacitordevice AT yusransulaiman facilesynthesisofpedotrgohkust1forhighperformancesymmetricalsupercapacitordevice |
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1718385427609550848 |