Facile synthesis of PEDOT-rGO/HKUST-1 for high performance symmetrical supercapacitor device

Abstract A novel poly(3,4-ethylenedioxythiophene)-reduced graphene oxide/copper-based metal–organic framework (PrGO/HKUST-1) has been successfully fabricated by incorporating electrochemically synthesized poly(3,4-ethylenedioxythiophene)-reduced graphene oxide (PrGO) and hydrothermally synthesized c...

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Autores principales: Dharshini Mohanadas, Muhammad Amirul Aizat Mohd Abdah, Nur Hawa Nabilah Azman, Thahira B. S. A. Ravoof, Yusran Sulaiman
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Publicado: Nature Portfolio 2021
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spelling oai:doaj.org-article:f3aeb89bbf38445a8fbdb4c666ef1e4a2021-12-02T15:56:41ZFacile synthesis of PEDOT-rGO/HKUST-1 for high performance symmetrical supercapacitor device10.1038/s41598-021-91100-x2045-2322https://doaj.org/article/f3aeb89bbf38445a8fbdb4c666ef1e4a2021-06-01T00:00:00Zhttps://doi.org/10.1038/s41598-021-91100-xhttps://doaj.org/toc/2045-2322Abstract A novel poly(3,4-ethylenedioxythiophene)-reduced graphene oxide/copper-based metal–organic framework (PrGO/HKUST-1) has been successfully fabricated by incorporating electrochemically synthesized poly(3,4-ethylenedioxythiophene)-reduced graphene oxide (PrGO) and hydrothermally synthesized copper-based metal–organic framework (HKUST-1). The field emission scanning microscopy (FESEM) and elemental mapping analysis revealed an even distribution of poly(3,4-ethylenedioxythiophene) (PEDOT), reduced graphene oxide (rGO) and HKUST-1. The crystalline structure and vibration modes of PrGO/HKUST-1 were validated utilizing X-ray diffraction (XRD) as well as Raman spectroscopy, respectively. A remarkable specific capacitance (360.5 F/g) was obtained for PrGO/HKUST-1 compared to HKUST-1 (103.1 F/g), PrGO (98.5 F/g) and PEDOT (50.8 F/g) using KCl/PVA as a gel electrolyte. Moreover, PrGO/HKUST-1 composite with the longest charge/discharge time displayed excellent specific energy (21.0 Wh/kg), specific power (479.7 W/kg) and an outstanding cycle life (95.5%) over 4000 cycles. Thus, the PrGO/HKUST-1 can be recognized as a promising energy storage material.Dharshini MohanadasMuhammad Amirul Aizat Mohd AbdahNur Hawa Nabilah AzmanThahira B. S. A. RavoofYusran SulaimanNature PortfolioarticleMedicineRScienceQENScientific Reports, Vol 11, Iss 1, Pp 1-13 (2021)
institution DOAJ
collection DOAJ
language EN
topic Medicine
R
Science
Q
spellingShingle Medicine
R
Science
Q
Dharshini Mohanadas
Muhammad Amirul Aizat Mohd Abdah
Nur Hawa Nabilah Azman
Thahira B. S. A. Ravoof
Yusran Sulaiman
Facile synthesis of PEDOT-rGO/HKUST-1 for high performance symmetrical supercapacitor device
description Abstract A novel poly(3,4-ethylenedioxythiophene)-reduced graphene oxide/copper-based metal–organic framework (PrGO/HKUST-1) has been successfully fabricated by incorporating electrochemically synthesized poly(3,4-ethylenedioxythiophene)-reduced graphene oxide (PrGO) and hydrothermally synthesized copper-based metal–organic framework (HKUST-1). The field emission scanning microscopy (FESEM) and elemental mapping analysis revealed an even distribution of poly(3,4-ethylenedioxythiophene) (PEDOT), reduced graphene oxide (rGO) and HKUST-1. The crystalline structure and vibration modes of PrGO/HKUST-1 were validated utilizing X-ray diffraction (XRD) as well as Raman spectroscopy, respectively. A remarkable specific capacitance (360.5 F/g) was obtained for PrGO/HKUST-1 compared to HKUST-1 (103.1 F/g), PrGO (98.5 F/g) and PEDOT (50.8 F/g) using KCl/PVA as a gel electrolyte. Moreover, PrGO/HKUST-1 composite with the longest charge/discharge time displayed excellent specific energy (21.0 Wh/kg), specific power (479.7 W/kg) and an outstanding cycle life (95.5%) over 4000 cycles. Thus, the PrGO/HKUST-1 can be recognized as a promising energy storage material.
format article
author Dharshini Mohanadas
Muhammad Amirul Aizat Mohd Abdah
Nur Hawa Nabilah Azman
Thahira B. S. A. Ravoof
Yusran Sulaiman
author_facet Dharshini Mohanadas
Muhammad Amirul Aizat Mohd Abdah
Nur Hawa Nabilah Azman
Thahira B. S. A. Ravoof
Yusran Sulaiman
author_sort Dharshini Mohanadas
title Facile synthesis of PEDOT-rGO/HKUST-1 for high performance symmetrical supercapacitor device
title_short Facile synthesis of PEDOT-rGO/HKUST-1 for high performance symmetrical supercapacitor device
title_full Facile synthesis of PEDOT-rGO/HKUST-1 for high performance symmetrical supercapacitor device
title_fullStr Facile synthesis of PEDOT-rGO/HKUST-1 for high performance symmetrical supercapacitor device
title_full_unstemmed Facile synthesis of PEDOT-rGO/HKUST-1 for high performance symmetrical supercapacitor device
title_sort facile synthesis of pedot-rgo/hkust-1 for high performance symmetrical supercapacitor device
publisher Nature Portfolio
publishDate 2021
url https://doaj.org/article/f3aeb89bbf38445a8fbdb4c666ef1e4a
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