Three-dimensional aromaticity in an antiaromatic cyclophane

Little is known about interactions between two antiaromatic molecules. Here, the authors synthesised a cyclophane, in which two antiaromatic porphyrin moieties adopt a stacked face-to-face geometry with a distance shorter than the sum of the van der Waals radii of the atoms involved.

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Autores principales:	Ryo Nozawa, Jinseok Kim, Juwon Oh, Anna Lamping, Yemei Wang, Soji Shimizu, Ichiro Hisaki, Tim Kowalczyk, Heike Fliegl, Dongho Kim, Hiroshi Shinokubo
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2019
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/f3e4bc971fd84128bedcf004838b4673
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spelling	oai:doaj.org-article:f3e4bc971fd84128bedcf004838b46732021-12-02T17:01:32ZThree-dimensional aromaticity in an antiaromatic cyclophane10.1038/s41467-019-11467-42041-1723https://doaj.org/article/f3e4bc971fd84128bedcf004838b46732019-08-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-11467-4https://doaj.org/toc/2041-1723Little is known about interactions between two antiaromatic molecules. Here, the authors synthesised a cyclophane, in which two antiaromatic porphyrin moieties adopt a stacked face-to-face geometry with a distance shorter than the sum of the van der Waals radii of the atoms involved.Ryo NozawaJinseok KimJuwon OhAnna LampingYemei WangSoji ShimizuIchiro HisakiTim KowalczykHeike FlieglDongho KimHiroshi ShinokuboNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-7 (2019)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Ryo Nozawa Jinseok Kim Juwon Oh Anna Lamping Yemei Wang Soji Shimizu Ichiro Hisaki Tim Kowalczyk Heike Fliegl Dongho Kim Hiroshi Shinokubo Three-dimensional aromaticity in an antiaromatic cyclophane
description	Little is known about interactions between two antiaromatic molecules. Here, the authors synthesised a cyclophane, in which two antiaromatic porphyrin moieties adopt a stacked face-to-face geometry with a distance shorter than the sum of the van der Waals radii of the atoms involved.
format	article
author	Ryo Nozawa Jinseok Kim Juwon Oh Anna Lamping Yemei Wang Soji Shimizu Ichiro Hisaki Tim Kowalczyk Heike Fliegl Dongho Kim Hiroshi Shinokubo
author_facet	Ryo Nozawa Jinseok Kim Juwon Oh Anna Lamping Yemei Wang Soji Shimizu Ichiro Hisaki Tim Kowalczyk Heike Fliegl Dongho Kim Hiroshi Shinokubo
author_sort	Ryo Nozawa
title	Three-dimensional aromaticity in an antiaromatic cyclophane
title_short	Three-dimensional aromaticity in an antiaromatic cyclophane
title_full	Three-dimensional aromaticity in an antiaromatic cyclophane
title_fullStr	Three-dimensional aromaticity in an antiaromatic cyclophane
title_full_unstemmed	Three-dimensional aromaticity in an antiaromatic cyclophane
title_sort	three-dimensional aromaticity in an antiaromatic cyclophane
publisher	Nature Portfolio
publishDate	2019
url	https://doaj.org/article/f3e4bc971fd84128bedcf004838b4673
work_keys_str_mv	AT ryonozawa threedimensionalaromaticityinanantiaromaticcyclophane AT jinseokkim threedimensionalaromaticityinanantiaromaticcyclophane AT juwonoh threedimensionalaromaticityinanantiaromaticcyclophane AT annalamping threedimensionalaromaticityinanantiaromaticcyclophane AT yemeiwang threedimensionalaromaticityinanantiaromaticcyclophane AT sojishimizu threedimensionalaromaticityinanantiaromaticcyclophane AT ichirohisaki threedimensionalaromaticityinanantiaromaticcyclophane AT timkowalczyk threedimensionalaromaticityinanantiaromaticcyclophane AT heikefliegl threedimensionalaromaticityinanantiaromaticcyclophane AT donghokim threedimensionalaromaticityinanantiaromaticcyclophane AT hiroshishinokubo threedimensionalaromaticityinanantiaromaticcyclophane
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Three-dimensional aromaticity in an antiaromatic cyclophane

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