Reaction scope and mechanistic insights of nickel-catalyzed migratory Suzuki–Miyaura cross-coupling

Migratory cross-coupling reactions are powerful tools to form bonds at predictable positions. Here the authors report a nickel-catalyzed migratory Suzuki–Miyaura cross-coupling of unactivated alkyl electrophiles with aryl and vinyl boron reagents and provide experimental and computational mechanisti...

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Autores principales: Yuqiang Li, Yixin Luo, Long Peng, Yangyang Li, Binzhi Zhao, Wang Wang, Hailiang Pang, Yi Deng, Ruopeng Bai, Yu Lan, Guoyin Yin
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Lenguaje:EN
Publicado: Nature Portfolio 2020
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Acceso en línea:https://doaj.org/article/f3e8e511c9a240f1a482cae274b6c38e
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spelling oai:doaj.org-article:f3e8e511c9a240f1a482cae274b6c38e2021-12-02T17:31:08ZReaction scope and mechanistic insights of nickel-catalyzed migratory Suzuki–Miyaura cross-coupling10.1038/s41467-019-14016-12041-1723https://doaj.org/article/f3e8e511c9a240f1a482cae274b6c38e2020-01-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-14016-1https://doaj.org/toc/2041-1723Migratory cross-coupling reactions are powerful tools to form bonds at predictable positions. Here the authors report a nickel-catalyzed migratory Suzuki–Miyaura cross-coupling of unactivated alkyl electrophiles with aryl and vinyl boron reagents and provide experimental and computational mechanistic evidence.Yuqiang LiYixin LuoLong PengYangyang LiBinzhi ZhaoWang WangHailiang PangYi DengRuopeng BaiYu LanGuoyin YinNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-13 (2020)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Yuqiang Li
Yixin Luo
Long Peng
Yangyang Li
Binzhi Zhao
Wang Wang
Hailiang Pang
Yi Deng
Ruopeng Bai
Yu Lan
Guoyin Yin
Reaction scope and mechanistic insights of nickel-catalyzed migratory Suzuki–Miyaura cross-coupling
description Migratory cross-coupling reactions are powerful tools to form bonds at predictable positions. Here the authors report a nickel-catalyzed migratory Suzuki–Miyaura cross-coupling of unactivated alkyl electrophiles with aryl and vinyl boron reagents and provide experimental and computational mechanistic evidence.
format article
author Yuqiang Li
Yixin Luo
Long Peng
Yangyang Li
Binzhi Zhao
Wang Wang
Hailiang Pang
Yi Deng
Ruopeng Bai
Yu Lan
Guoyin Yin
author_facet Yuqiang Li
Yixin Luo
Long Peng
Yangyang Li
Binzhi Zhao
Wang Wang
Hailiang Pang
Yi Deng
Ruopeng Bai
Yu Lan
Guoyin Yin
author_sort Yuqiang Li
title Reaction scope and mechanistic insights of nickel-catalyzed migratory Suzuki–Miyaura cross-coupling
title_short Reaction scope and mechanistic insights of nickel-catalyzed migratory Suzuki–Miyaura cross-coupling
title_full Reaction scope and mechanistic insights of nickel-catalyzed migratory Suzuki–Miyaura cross-coupling
title_fullStr Reaction scope and mechanistic insights of nickel-catalyzed migratory Suzuki–Miyaura cross-coupling
title_full_unstemmed Reaction scope and mechanistic insights of nickel-catalyzed migratory Suzuki–Miyaura cross-coupling
title_sort reaction scope and mechanistic insights of nickel-catalyzed migratory suzuki–miyaura cross-coupling
publisher Nature Portfolio
publishDate 2020
url https://doaj.org/article/f3e8e511c9a240f1a482cae274b6c38e
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