Reaction scope and mechanistic insights of nickel-catalyzed migratory Suzuki–Miyaura cross-coupling
Migratory cross-coupling reactions are powerful tools to form bonds at predictable positions. Here the authors report a nickel-catalyzed migratory Suzuki–Miyaura cross-coupling of unactivated alkyl electrophiles with aryl and vinyl boron reagents and provide experimental and computational mechanisti...
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Nature Portfolio
2020
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oai:doaj.org-article:f3e8e511c9a240f1a482cae274b6c38e2021-12-02T17:31:08ZReaction scope and mechanistic insights of nickel-catalyzed migratory Suzuki–Miyaura cross-coupling10.1038/s41467-019-14016-12041-1723https://doaj.org/article/f3e8e511c9a240f1a482cae274b6c38e2020-01-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-14016-1https://doaj.org/toc/2041-1723Migratory cross-coupling reactions are powerful tools to form bonds at predictable positions. Here the authors report a nickel-catalyzed migratory Suzuki–Miyaura cross-coupling of unactivated alkyl electrophiles with aryl and vinyl boron reagents and provide experimental and computational mechanistic evidence.Yuqiang LiYixin LuoLong PengYangyang LiBinzhi ZhaoWang WangHailiang PangYi DengRuopeng BaiYu LanGuoyin YinNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-13 (2020) |
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EN |
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Science Q Yuqiang Li Yixin Luo Long Peng Yangyang Li Binzhi Zhao Wang Wang Hailiang Pang Yi Deng Ruopeng Bai Yu Lan Guoyin Yin Reaction scope and mechanistic insights of nickel-catalyzed migratory Suzuki–Miyaura cross-coupling |
description |
Migratory cross-coupling reactions are powerful tools to form bonds at predictable positions. Here the authors report a nickel-catalyzed migratory Suzuki–Miyaura cross-coupling of unactivated alkyl electrophiles with aryl and vinyl boron reagents and provide experimental and computational mechanistic evidence. |
format |
article |
author |
Yuqiang Li Yixin Luo Long Peng Yangyang Li Binzhi Zhao Wang Wang Hailiang Pang Yi Deng Ruopeng Bai Yu Lan Guoyin Yin |
author_facet |
Yuqiang Li Yixin Luo Long Peng Yangyang Li Binzhi Zhao Wang Wang Hailiang Pang Yi Deng Ruopeng Bai Yu Lan Guoyin Yin |
author_sort |
Yuqiang Li |
title |
Reaction scope and mechanistic insights of nickel-catalyzed migratory Suzuki–Miyaura cross-coupling |
title_short |
Reaction scope and mechanistic insights of nickel-catalyzed migratory Suzuki–Miyaura cross-coupling |
title_full |
Reaction scope and mechanistic insights of nickel-catalyzed migratory Suzuki–Miyaura cross-coupling |
title_fullStr |
Reaction scope and mechanistic insights of nickel-catalyzed migratory Suzuki–Miyaura cross-coupling |
title_full_unstemmed |
Reaction scope and mechanistic insights of nickel-catalyzed migratory Suzuki–Miyaura cross-coupling |
title_sort |
reaction scope and mechanistic insights of nickel-catalyzed migratory suzuki–miyaura cross-coupling |
publisher |
Nature Portfolio |
publishDate |
2020 |
url |
https://doaj.org/article/f3e8e511c9a240f1a482cae274b6c38e |
work_keys_str_mv |
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1718380709159108608 |