The elusive abnormal CO2 insertion enabled by metal-ligand cooperative photochemical selectivity inversion

The development of molecular catalysts for the reverse water–gas shift reaction is impeded by the general selectivity of CO2 insertion into M–H bonds to formates. Here, the authors report that the selectivity of CO2 insertion into a Ni–H bond can be inverted from normal to abnormal insertion upon sw...

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Autores principales:	Felix Schneck, Jennifer Ahrens, Markus Finger, A. Claudia Stückl, Christian Würtele, Dirk Schwarzer, Sven Schneider
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2018
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/f47c5351055d432aad9ad9b90406bafb
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spelling	oai:doaj.org-article:f47c5351055d432aad9ad9b90406bafb2021-12-02T17:33:01ZThe elusive abnormal CO2 insertion enabled by metal-ligand cooperative photochemical selectivity inversion10.1038/s41467-018-03239-32041-1723https://doaj.org/article/f47c5351055d432aad9ad9b90406bafb2018-03-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-03239-3https://doaj.org/toc/2041-1723The development of molecular catalysts for the reverse water–gas shift reaction is impeded by the general selectivity of CO2 insertion into M–H bonds to formates. Here, the authors report that the selectivity of CO2 insertion into a Ni–H bond can be inverted from normal to abnormal insertion upon switching from thermal to photochemical conditions.Felix SchneckJennifer AhrensMarkus FingerA. Claudia StücklChristian WürteleDirk SchwarzerSven SchneiderNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-8 (2018)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Felix Schneck Jennifer Ahrens Markus Finger A. Claudia Stückl Christian Würtele Dirk Schwarzer Sven Schneider The elusive abnormal CO2 insertion enabled by metal-ligand cooperative photochemical selectivity inversion
description	The development of molecular catalysts for the reverse water–gas shift reaction is impeded by the general selectivity of CO2 insertion into M–H bonds to formates. Here, the authors report that the selectivity of CO2 insertion into a Ni–H bond can be inverted from normal to abnormal insertion upon switching from thermal to photochemical conditions.
format	article
author	Felix Schneck Jennifer Ahrens Markus Finger A. Claudia Stückl Christian Würtele Dirk Schwarzer Sven Schneider
author_facet	Felix Schneck Jennifer Ahrens Markus Finger A. Claudia Stückl Christian Würtele Dirk Schwarzer Sven Schneider
author_sort	Felix Schneck
title	The elusive abnormal CO2 insertion enabled by metal-ligand cooperative photochemical selectivity inversion
title_short	The elusive abnormal CO2 insertion enabled by metal-ligand cooperative photochemical selectivity inversion
title_full	The elusive abnormal CO2 insertion enabled by metal-ligand cooperative photochemical selectivity inversion
title_fullStr	The elusive abnormal CO2 insertion enabled by metal-ligand cooperative photochemical selectivity inversion
title_full_unstemmed	The elusive abnormal CO2 insertion enabled by metal-ligand cooperative photochemical selectivity inversion
title_sort	elusive abnormal co2 insertion enabled by metal-ligand cooperative photochemical selectivity inversion
publisher	Nature Portfolio
publishDate	2018
url	https://doaj.org/article/f47c5351055d432aad9ad9b90406bafb
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The elusive abnormal CO2 insertion enabled by metal-ligand cooperative photochemical selectivity inversion

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