The elusive abnormal CO2 insertion enabled by metal-ligand cooperative photochemical selectivity inversion
The development of molecular catalysts for the reverse water–gas shift reaction is impeded by the general selectivity of CO2 insertion into M–H bonds to formates. Here, the authors report that the selectivity of CO2 insertion into a Ni–H bond can be inverted from normal to abnormal insertion upon sw...
Enregistré dans:
| Auteurs principaux: | , , , , , , |
|---|---|
| Format: | article |
| Langue: | EN |
| Publié: |
Nature Portfolio
2018
|
| Sujets: | |
| Accès en ligne: | https://doaj.org/article/f47c5351055d432aad9ad9b90406bafb |
| Tags: |
Ajouter un tag
Pas de tags, Soyez le premier à ajouter un tag!
|