The inverse-trans-influence in tetravalent lanthanide and actinide bis(carbene) complexes

The inverse-trans-influence has been shown to operate in high oxidation state actinide complexes. Here, the authors report tetravalent cerium, uranium and thorium bis(carbene) complexes with trans C=M=C cores where experimental and theoretical data also suggest the presence of an inverse-trans-effec...

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Autores principales:	Matthew Gregson, Erli Lu, David P. Mills, Floriana Tuna, Eric J. L. McInnes, Christoph Hennig, Andreas C. Scheinost, Jonathan McMaster, William Lewis, Alexander J. Blake, Andrew Kerridge, Stephen T. Liddle
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2017
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/f493a1a8b1374d42be83fd7c35270993
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spelling	oai:doaj.org-article:f493a1a8b1374d42be83fd7c352709932021-12-02T17:06:02ZThe inverse-trans-influence in tetravalent lanthanide and actinide bis(carbene) complexes10.1038/ncomms141372041-1723https://doaj.org/article/f493a1a8b1374d42be83fd7c352709932017-02-01T00:00:00Zhttps://doi.org/10.1038/ncomms14137https://doaj.org/toc/2041-1723The inverse-trans-influence has been shown to operate in high oxidation state actinide complexes. Here, the authors report tetravalent cerium, uranium and thorium bis(carbene) complexes with trans C=M=C cores where experimental and theoretical data also suggest the presence of an inverse-trans-effect.Matthew GregsonErli LuDavid P. MillsFloriana TunaEric J. L. McInnesChristoph HennigAndreas C. ScheinostJonathan McMasterWilliam LewisAlexander J. BlakeAndrew KerridgeStephen T. LiddleNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-11 (2017)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Matthew Gregson Erli Lu David P. Mills Floriana Tuna Eric J. L. McInnes Christoph Hennig Andreas C. Scheinost Jonathan McMaster William Lewis Alexander J. Blake Andrew Kerridge Stephen T. Liddle The inverse-trans-influence in tetravalent lanthanide and actinide bis(carbene) complexes
description	The inverse-trans-influence has been shown to operate in high oxidation state actinide complexes. Here, the authors report tetravalent cerium, uranium and thorium bis(carbene) complexes with trans C=M=C cores where experimental and theoretical data also suggest the presence of an inverse-trans-effect.
format	article
author	Matthew Gregson Erli Lu David P. Mills Floriana Tuna Eric J. L. McInnes Christoph Hennig Andreas C. Scheinost Jonathan McMaster William Lewis Alexander J. Blake Andrew Kerridge Stephen T. Liddle
author_facet	Matthew Gregson Erli Lu David P. Mills Floriana Tuna Eric J. L. McInnes Christoph Hennig Andreas C. Scheinost Jonathan McMaster William Lewis Alexander J. Blake Andrew Kerridge Stephen T. Liddle
author_sort	Matthew Gregson
title	The inverse-trans-influence in tetravalent lanthanide and actinide bis(carbene) complexes
title_short	The inverse-trans-influence in tetravalent lanthanide and actinide bis(carbene) complexes
title_full	The inverse-trans-influence in tetravalent lanthanide and actinide bis(carbene) complexes
title_fullStr	The inverse-trans-influence in tetravalent lanthanide and actinide bis(carbene) complexes
title_full_unstemmed	The inverse-trans-influence in tetravalent lanthanide and actinide bis(carbene) complexes
title_sort	inverse-trans-influence in tetravalent lanthanide and actinide bis(carbene) complexes
publisher	Nature Portfolio
publishDate	2017
url	https://doaj.org/article/f493a1a8b1374d42be83fd7c35270993
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The inverse-trans-influence in tetravalent lanthanide and actinide bis(carbene) complexes

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