Helicate-to-tetrahedron transformation of chiral lanthanide supramolecular complexes induced by ionic radii effect and linker length

Lanthanide-based supramolecular complexes have labile and hard-topredict chemical structures. Here the authors show controlled formation of either helicates or tetrahedron shaped cages based on the interplay between the metal ionic radius and the ligand composition.

Guardado en:

Detalles Bibliográficos
Autores principales:	King-Him Yim, Chi-Tung Yeung, Michael R. Probert, Wesley Ting Kwok Chan, Lewis E. Mackenzie, Robert Pal, Wing-Tak Wong, Ga-Lai Law
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Chemistry QD1-999
Acceso en línea:	https://doaj.org/article/f4a16f5c89da4cb9a0cf296bb3d351c6
Etiquetas:	Agregar Etiqueta Sin Etiquetas, Sea el primero en etiquetar este registro!

id	oai:doaj.org-article:f4a16f5c89da4cb9a0cf296bb3d351c6
record_format	dspace
spelling	oai:doaj.org-article:f4a16f5c89da4cb9a0cf296bb3d351c62021-12-02T18:49:16ZHelicate-to-tetrahedron transformation of chiral lanthanide supramolecular complexes induced by ionic radii effect and linker length10.1038/s42004-021-00553-82399-3669https://doaj.org/article/f4a16f5c89da4cb9a0cf296bb3d351c62021-08-01T00:00:00Zhttps://doi.org/10.1038/s42004-021-00553-8https://doaj.org/toc/2399-3669Lanthanide-based supramolecular complexes have labile and hard-topredict chemical structures. Here the authors show controlled formation of either helicates or tetrahedron shaped cages based on the interplay between the metal ionic radius and the ligand composition.King-Him YimChi-Tung YeungMichael R. ProbertWesley Ting Kwok ChanLewis E. MackenzieRobert PalWing-Tak WongGa-Lai LawNature PortfolioarticleChemistryQD1-999ENCommunications Chemistry, Vol 4, Iss 1, Pp 1-10 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Chemistry QD1-999
spellingShingle	Chemistry QD1-999 King-Him Yim Chi-Tung Yeung Michael R. Probert Wesley Ting Kwok Chan Lewis E. Mackenzie Robert Pal Wing-Tak Wong Ga-Lai Law Helicate-to-tetrahedron transformation of chiral lanthanide supramolecular complexes induced by ionic radii effect and linker length
description	Lanthanide-based supramolecular complexes have labile and hard-topredict chemical structures. Here the authors show controlled formation of either helicates or tetrahedron shaped cages based on the interplay between the metal ionic radius and the ligand composition.
format	article
author	King-Him Yim Chi-Tung Yeung Michael R. Probert Wesley Ting Kwok Chan Lewis E. Mackenzie Robert Pal Wing-Tak Wong Ga-Lai Law
author_facet	King-Him Yim Chi-Tung Yeung Michael R. Probert Wesley Ting Kwok Chan Lewis E. Mackenzie Robert Pal Wing-Tak Wong Ga-Lai Law
author_sort	King-Him Yim
title	Helicate-to-tetrahedron transformation of chiral lanthanide supramolecular complexes induced by ionic radii effect and linker length
title_short	Helicate-to-tetrahedron transformation of chiral lanthanide supramolecular complexes induced by ionic radii effect and linker length
title_full	Helicate-to-tetrahedron transformation of chiral lanthanide supramolecular complexes induced by ionic radii effect and linker length
title_fullStr	Helicate-to-tetrahedron transformation of chiral lanthanide supramolecular complexes induced by ionic radii effect and linker length
title_full_unstemmed	Helicate-to-tetrahedron transformation of chiral lanthanide supramolecular complexes induced by ionic radii effect and linker length
title_sort	helicate-to-tetrahedron transformation of chiral lanthanide supramolecular complexes induced by ionic radii effect and linker length
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/f4a16f5c89da4cb9a0cf296bb3d351c6
work_keys_str_mv	AT kinghimyim helicatetotetrahedrontransformationofchirallanthanidesupramolecularcomplexesinducedbyionicradiieffectandlinkerlength AT chitungyeung helicatetotetrahedrontransformationofchirallanthanidesupramolecularcomplexesinducedbyionicradiieffectandlinkerlength AT michaelrprobert helicatetotetrahedrontransformationofchirallanthanidesupramolecularcomplexesinducedbyionicradiieffectandlinkerlength AT wesleytingkwokchan helicatetotetrahedrontransformationofchirallanthanidesupramolecularcomplexesinducedbyionicradiieffectandlinkerlength AT lewisemackenzie helicatetotetrahedrontransformationofchirallanthanidesupramolecularcomplexesinducedbyionicradiieffectandlinkerlength AT robertpal helicatetotetrahedrontransformationofchirallanthanidesupramolecularcomplexesinducedbyionicradiieffectandlinkerlength AT wingtakwong helicatetotetrahedrontransformationofchirallanthanidesupramolecularcomplexesinducedbyionicradiieffectandlinkerlength AT galailaw helicatetotetrahedrontransformationofchirallanthanidesupramolecularcomplexesinducedbyionicradiieffectandlinkerlength
_version_	1718377599753781248

Helicate-to-tetrahedron transformation of chiral lanthanide supramolecular complexes induced by ionic radii effect and linker length

Ejemplares similares