Helicate-to-tetrahedron transformation of chiral lanthanide supramolecular complexes induced by ionic radii effect and linker length

Lanthanide-based supramolecular complexes have labile and hard-topredict chemical structures. Here the authors show controlled formation of either helicates or tetrahedron shaped cages based on the interplay between the metal ionic radius and the ligand composition.

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Bibliographic Details
Main Authors: King-Him Yim, Chi-Tung Yeung, Michael R. Probert, Wesley Ting Kwok Chan, Lewis E. Mackenzie, Robert Pal, Wing-Tak Wong, Ga-Lai Law
Format: article
Language:EN
Published: Nature Portfolio 2021
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Online Access:https://doaj.org/article/f4a16f5c89da4cb9a0cf296bb3d351c6
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