Hyperconjugative aromaticity and protodeauration reactivity of polyaurated indoliums

Hyperconjugative aromaticity and protodeauration reactivity of polyaurated indoliums

Hyperconjugative aromaticity combines the concepts of hyperconjugation and aromaticity and explains cyclopentadiene stability. Here, the authors demonstrate extended hyperconjugative aromaticity in a metallated indole ring, which shows extended electron conjugation due to the dual hyperconjugation.

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Autores principales: Kui Xiao, Yu Zhao, Jun Zhu, Liang Zhao
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2019
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Science
Q
Acceso en línea:https://doaj.org/article/f565e56009c0456c94b1b24dda727591
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spelling oai:doaj.org-article:f565e56009c0456c94b1b24dda7275912021-12-02T15:35:29ZHyperconjugative aromaticity and protodeauration reactivity of polyaurated indoliums10.1038/s41467-019-13663-82041-1723https://doaj.org/article/f565e56009c0456c94b1b24dda7275912019-12-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-13663-8https://doaj.org/toc/2041-1723Hyperconjugative aromaticity combines the concepts of hyperconjugation and aromaticity and explains cyclopentadiene stability. Here, the authors demonstrate extended hyperconjugative aromaticity in a metallated indole ring, which shows extended electron conjugation due to the dual hyperconjugation.Kui XiaoYu ZhaoJun ZhuLiang ZhaoNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-10 (2019)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Kui Xiao
Yu Zhao
Jun Zhu
Liang Zhao
Hyperconjugative aromaticity and protodeauration reactivity of polyaurated indoliums
description Hyperconjugative aromaticity combines the concepts of hyperconjugation and aromaticity and explains cyclopentadiene stability. Here, the authors demonstrate extended hyperconjugative aromaticity in a metallated indole ring, which shows extended electron conjugation due to the dual hyperconjugation.
format article
author Kui Xiao
Yu Zhao
Jun Zhu
Liang Zhao
author_facet Kui Xiao
Yu Zhao
Jun Zhu
Liang Zhao
author_sort Kui Xiao
title Hyperconjugative aromaticity and protodeauration reactivity of polyaurated indoliums
title_short Hyperconjugative aromaticity and protodeauration reactivity of polyaurated indoliums
title_full Hyperconjugative aromaticity and protodeauration reactivity of polyaurated indoliums
title_fullStr Hyperconjugative aromaticity and protodeauration reactivity of polyaurated indoliums
title_full_unstemmed Hyperconjugative aromaticity and protodeauration reactivity of polyaurated indoliums
title_sort hyperconjugative aromaticity and protodeauration reactivity of polyaurated indoliums
publisher Nature Portfolio
publishDate 2019
url https://doaj.org/article/f565e56009c0456c94b1b24dda727591
work_keys_str_mv AT kuixiao hyperconjugativearomaticityandprotodeaurationreactivityofpolyauratedindoliums
AT yuzhao hyperconjugativearomaticityandprotodeaurationreactivityofpolyauratedindoliums
AT junzhu hyperconjugativearomaticityandprotodeaurationreactivityofpolyauratedindoliums
AT liangzhao hyperconjugativearomaticityandprotodeaurationreactivityofpolyauratedindoliums
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