Hyperconjugative aromaticity and protodeauration reactivity of polyaurated indoliums
Hyperconjugative aromaticity combines the concepts of hyperconjugation and aromaticity and explains cyclopentadiene stability. Here, the authors demonstrate extended hyperconjugative aromaticity in a metallated indole ring, which shows extended electron conjugation due to the dual hyperconjugation.
Guardado en:
Autores principales: | Kui Xiao, Yu Zhao, Jun Zhu, Liang Zhao |
---|---|
Formato: | article |
Lenguaje: | EN |
Publicado: |
Nature Portfolio
2019
|
Materias: | |
Acceso en línea: | https://doaj.org/article/f565e56009c0456c94b1b24dda727591 |
Etiquetas: |
Agregar Etiqueta
Sin Etiquetas, Sea el primero en etiquetar este registro!
|
Ejemplares similares
-
Synthesis of tetra- and octa-aurated heteroaryl complexes towards probing aromatic indoliums
por: Jun Yuan, et al.
Publicado: (2016) -
Non-aromatic annulene-based aggregation-induced emission system via aromaticity reversal process
por: Zheng Zhao, et al.
Publicado: (2019) -
Site-selective electrooxidation of methylarenes to aromatic acetals
por: Peng Xiong, et al.
Publicado: (2020) -
Boron-mediated directed aromatic C–H hydroxylation
por: Jiahang Lv, et al.
Publicado: (2020) -
A tris-spiro metalla-aromatic system featuring Craig-Möbius aromaticity
por: Zhe Huang, et al.
Publicado: (2021)