Carbene-catalysed reductive coupling of nitrobenzyl bromides and activated ketones or imines via single-electron-transfer process
Benzyl bromides can be activated for radical reactions by photocatalytic single electron transfer. Here the authors show thatN-heterocyclic carbenes are also capable of activating this pathway for nitrobenzyl bromides, and that the radical intermediates can add to the carbonyl group of ketones.
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| Autores principales: | , , , , , , , |
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| Formato: | article |
| Lenguaje: | EN |
| Publicado: |
Nature Portfolio
2016
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| Materias: | |
| Acceso en línea: | https://doaj.org/article/f5b0f77486ea464ea415a0200b949e73 |
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| Sumario: | Benzyl bromides can be activated for radical reactions by photocatalytic single electron transfer. Here the authors show thatN-heterocyclic carbenes are also capable of activating this pathway for nitrobenzyl bromides, and that the radical intermediates can add to the carbonyl group of ketones. |
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