Carbene-catalysed reductive coupling of nitrobenzyl bromides and activated ketones or imines via single-electron-transfer process

Benzyl bromides can be activated for radical reactions by photocatalytic single electron transfer. Here the authors show thatN-heterocyclic carbenes are also capable of activating this pathway for nitrobenzyl bromides, and that the radical intermediates can add to the carbonyl group of ketones.

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Autores principales:	Bao-Sheng Li, Yuhuang Wang, Rupert S. J. Proctor, Yuexia Zhang, Richard D. Webster, Song Yang, Baoan Song, Yonggui Robin Chi
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2016
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/f5b0f77486ea464ea415a0200b949e73
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spelling	oai:doaj.org-article:f5b0f77486ea464ea415a0200b949e732021-12-02T14:38:33ZCarbene-catalysed reductive coupling of nitrobenzyl bromides and activated ketones or imines via single-electron-transfer process10.1038/ncomms129332041-1723https://doaj.org/article/f5b0f77486ea464ea415a0200b949e732016-09-01T00:00:00Zhttps://doi.org/10.1038/ncomms12933https://doaj.org/toc/2041-1723Benzyl bromides can be activated for radical reactions by photocatalytic single electron transfer. Here the authors show thatN-heterocyclic carbenes are also capable of activating this pathway for nitrobenzyl bromides, and that the radical intermediates can add to the carbonyl group of ketones.Bao-Sheng LiYuhuang WangRupert S. J. ProctorYuexia ZhangRichard D. WebsterSong YangBaoan SongYonggui Robin ChiNature PortfolioarticleScienceQENNature Communications, Vol 7, Iss 1, Pp 1-8 (2016)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Bao-Sheng Li Yuhuang Wang Rupert S. J. Proctor Yuexia Zhang Richard D. Webster Song Yang Baoan Song Yonggui Robin Chi Carbene-catalysed reductive coupling of nitrobenzyl bromides and activated ketones or imines via single-electron-transfer process
description	Benzyl bromides can be activated for radical reactions by photocatalytic single electron transfer. Here the authors show thatN-heterocyclic carbenes are also capable of activating this pathway for nitrobenzyl bromides, and that the radical intermediates can add to the carbonyl group of ketones.
format	article
author	Bao-Sheng Li Yuhuang Wang Rupert S. J. Proctor Yuexia Zhang Richard D. Webster Song Yang Baoan Song Yonggui Robin Chi
author_facet	Bao-Sheng Li Yuhuang Wang Rupert S. J. Proctor Yuexia Zhang Richard D. Webster Song Yang Baoan Song Yonggui Robin Chi
author_sort	Bao-Sheng Li
title	Carbene-catalysed reductive coupling of nitrobenzyl bromides and activated ketones or imines via single-electron-transfer process
title_short	Carbene-catalysed reductive coupling of nitrobenzyl bromides and activated ketones or imines via single-electron-transfer process
title_full	Carbene-catalysed reductive coupling of nitrobenzyl bromides and activated ketones or imines via single-electron-transfer process
title_fullStr	Carbene-catalysed reductive coupling of nitrobenzyl bromides and activated ketones or imines via single-electron-transfer process
title_full_unstemmed	Carbene-catalysed reductive coupling of nitrobenzyl bromides and activated ketones or imines via single-electron-transfer process
title_sort	carbene-catalysed reductive coupling of nitrobenzyl bromides and activated ketones or imines via single-electron-transfer process
publisher	Nature Portfolio
publishDate	2016
url	https://doaj.org/article/f5b0f77486ea464ea415a0200b949e73
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Carbene-catalysed reductive coupling of nitrobenzyl bromides and activated ketones or imines via single-electron-transfer process

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