Fe3O4@chitosan-tannic acid bionanocomposite as a novel nanocatalyst for the synthesis of pyranopyrazoles

Abstract Recently magnetic nanocatalyst has attracted considerable attention because of its unique properties, including high performance, easy separation from the reaction mixture, and recyclability. In this study, a novel magnetic bionanocomposite was synthesized with chitosan and tannic acid as a...

Descripción completa

Guardado en:

Detalles Bibliográficos
Autores principales:	Maryam Kamalzare, Mohammad Reza Ahghari, Mohammad Bayat, Ali Maleki
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Medicine R Science Q
Acceso en línea:	https://doaj.org/article/f5f15af7ecd04bf0950985587840ebc9
Etiquetas:	Agregar Etiqueta Sin Etiquetas, Sea el primero en etiquetar este registro!

id	oai:doaj.org-article:f5f15af7ecd04bf0950985587840ebc9
record_format	dspace
spelling	oai:doaj.org-article:f5f15af7ecd04bf0950985587840ebc92021-12-02T19:16:11ZFe3O4@chitosan-tannic acid bionanocomposite as a novel nanocatalyst for the synthesis of pyranopyrazoles10.1038/s41598-021-99121-22045-2322https://doaj.org/article/f5f15af7ecd04bf0950985587840ebc92021-10-01T00:00:00Zhttps://doi.org/10.1038/s41598-021-99121-2https://doaj.org/toc/2045-2322Abstract Recently magnetic nanocatalyst has attracted considerable attention because of its unique properties, including high performance, easy separation from the reaction mixture, and recyclability. In this study, a novel magnetic bionanocomposite was synthesized with chitosan and tannic acid as a natural material. The synthesized bionanocatalyst was characterized by essential analysis. Fe3O4@chitosan-tannic acid as a heterogeneous nanocatalyst was successfully applied to synthesize pyranopyrazole and its derivatives by a one-pot four-component reaction of malononitrile, ethyl acetoacetate, hydrazine hydrate, and various aromatic aldehyde. At the end of the reaction, the nanocatalyst was separated from the reaction mixture and was reused several times with no significant decrease in its catalytic performance. Simple purification of products, the ability for recovering and reusing the nanocatalyst, eco-friendliness, high yields of pure products, mild reaction conditions, short reaction time, non-toxicity, economically affordable are some of the advantages of using the fabricated nanocatalyst in the synthesis of pyranopyrazole.Maryam KamalzareMohammad Reza AhghariMohammad BayatAli MalekiNature PortfolioarticleMedicineRScienceQENScientific Reports, Vol 11, Iss 1, Pp 1-10 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Medicine R Science Q
spellingShingle	Medicine R Science Q Maryam Kamalzare Mohammad Reza Ahghari Mohammad Bayat Ali Maleki Fe3O4@chitosan-tannic acid bionanocomposite as a novel nanocatalyst for the synthesis of pyranopyrazoles
description	Abstract Recently magnetic nanocatalyst has attracted considerable attention because of its unique properties, including high performance, easy separation from the reaction mixture, and recyclability. In this study, a novel magnetic bionanocomposite was synthesized with chitosan and tannic acid as a natural material. The synthesized bionanocatalyst was characterized by essential analysis. Fe3O4@chitosan-tannic acid as a heterogeneous nanocatalyst was successfully applied to synthesize pyranopyrazole and its derivatives by a one-pot four-component reaction of malononitrile, ethyl acetoacetate, hydrazine hydrate, and various aromatic aldehyde. At the end of the reaction, the nanocatalyst was separated from the reaction mixture and was reused several times with no significant decrease in its catalytic performance. Simple purification of products, the ability for recovering and reusing the nanocatalyst, eco-friendliness, high yields of pure products, mild reaction conditions, short reaction time, non-toxicity, economically affordable are some of the advantages of using the fabricated nanocatalyst in the synthesis of pyranopyrazole.
format	article
author	Maryam Kamalzare Mohammad Reza Ahghari Mohammad Bayat Ali Maleki
author_facet	Maryam Kamalzare Mohammad Reza Ahghari Mohammad Bayat Ali Maleki
author_sort	Maryam Kamalzare
title	Fe3O4@chitosan-tannic acid bionanocomposite as a novel nanocatalyst for the synthesis of pyranopyrazoles
title_short	Fe3O4@chitosan-tannic acid bionanocomposite as a novel nanocatalyst for the synthesis of pyranopyrazoles
title_full	Fe3O4@chitosan-tannic acid bionanocomposite as a novel nanocatalyst for the synthesis of pyranopyrazoles
title_fullStr	Fe3O4@chitosan-tannic acid bionanocomposite as a novel nanocatalyst for the synthesis of pyranopyrazoles
title_full_unstemmed	Fe3O4@chitosan-tannic acid bionanocomposite as a novel nanocatalyst for the synthesis of pyranopyrazoles
title_sort	fe3o4@chitosan-tannic acid bionanocomposite as a novel nanocatalyst for the synthesis of pyranopyrazoles
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/f5f15af7ecd04bf0950985587840ebc9
work_keys_str_mv	AT maryamkamalzare fe3o4chitosantannicacidbionanocompositeasanovelnanocatalystforthesynthesisofpyranopyrazoles AT mohammadrezaahghari fe3o4chitosantannicacidbionanocompositeasanovelnanocatalystforthesynthesisofpyranopyrazoles AT mohammadbayat fe3o4chitosantannicacidbionanocompositeasanovelnanocatalystforthesynthesisofpyranopyrazoles AT alimaleki fe3o4chitosantannicacidbionanocompositeasanovelnanocatalystforthesynthesisofpyranopyrazoles
_version_	1718377007234940928

Fe3O4@chitosan-tannic acid bionanocomposite as a novel nanocatalyst for the synthesis of pyranopyrazoles

Ejemplares similares