Design of metastable oxychalcogenide phases by topochemical (de)intercalation of sulfur in La2O2S2

Great progress has been made in topochemistry of mobile oxygen anions, but metastable compounds have not yet been achieved by deintercalation of sulfur anions. Here, the authors prepare metastable oxychalcogenide phases by taking advantage of redox-reactive sulfur dimers embedded in a layered oxysul...

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Autores principales: Shunsuke Sasaki, Maria Teresa Caldes, Catherine Guillot-Deudon, Isabelle Braems, Gwladys Steciuk, Lukáš Palatinus, Eric Gautron, Gilles Frapper, Etienne Janod, Benoît Corraze, Stéphane Jobic, Laurent Cario
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Publicado: Nature Portfolio 2021
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Acceso en línea:https://doaj.org/article/f5f9230e3bc84a528235809c1086a3cb
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spelling oai:doaj.org-article:f5f9230e3bc84a528235809c1086a3cb2021-12-02T16:04:25ZDesign of metastable oxychalcogenide phases by topochemical (de)intercalation of sulfur in La2O2S210.1038/s41467-021-23677-w2041-1723https://doaj.org/article/f5f9230e3bc84a528235809c1086a3cb2021-06-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-23677-whttps://doaj.org/toc/2041-1723Great progress has been made in topochemistry of mobile oxygen anions, but metastable compounds have not yet been achieved by deintercalation of sulfur anions. Here, the authors prepare metastable oxychalcogenide phases by taking advantage of redox-reactive sulfur dimers embedded in a layered oxysulfide.Shunsuke SasakiMaria Teresa CaldesCatherine Guillot-DeudonIsabelle BraemsGwladys SteciukLukáš PalatinusEric GautronGilles FrapperEtienne JanodBenoît CorrazeStéphane JobicLaurent CarioNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-8 (2021)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Shunsuke Sasaki
Maria Teresa Caldes
Catherine Guillot-Deudon
Isabelle Braems
Gwladys Steciuk
Lukáš Palatinus
Eric Gautron
Gilles Frapper
Etienne Janod
Benoît Corraze
Stéphane Jobic
Laurent Cario
Design of metastable oxychalcogenide phases by topochemical (de)intercalation of sulfur in La2O2S2
description Great progress has been made in topochemistry of mobile oxygen anions, but metastable compounds have not yet been achieved by deintercalation of sulfur anions. Here, the authors prepare metastable oxychalcogenide phases by taking advantage of redox-reactive sulfur dimers embedded in a layered oxysulfide.
format article
author Shunsuke Sasaki
Maria Teresa Caldes
Catherine Guillot-Deudon
Isabelle Braems
Gwladys Steciuk
Lukáš Palatinus
Eric Gautron
Gilles Frapper
Etienne Janod
Benoît Corraze
Stéphane Jobic
Laurent Cario
author_facet Shunsuke Sasaki
Maria Teresa Caldes
Catherine Guillot-Deudon
Isabelle Braems
Gwladys Steciuk
Lukáš Palatinus
Eric Gautron
Gilles Frapper
Etienne Janod
Benoît Corraze
Stéphane Jobic
Laurent Cario
author_sort Shunsuke Sasaki
title Design of metastable oxychalcogenide phases by topochemical (de)intercalation of sulfur in La2O2S2
title_short Design of metastable oxychalcogenide phases by topochemical (de)intercalation of sulfur in La2O2S2
title_full Design of metastable oxychalcogenide phases by topochemical (de)intercalation of sulfur in La2O2S2
title_fullStr Design of metastable oxychalcogenide phases by topochemical (de)intercalation of sulfur in La2O2S2
title_full_unstemmed Design of metastable oxychalcogenide phases by topochemical (de)intercalation of sulfur in La2O2S2
title_sort design of metastable oxychalcogenide phases by topochemical (de)intercalation of sulfur in la2o2s2
publisher Nature Portfolio
publishDate 2021
url https://doaj.org/article/f5f9230e3bc84a528235809c1086a3cb
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