Geometric isotope effect of deuteration in a hydrogen-bonded host–guest crystal

Deuterating a hydrogen bond can change the bond’s geometry, a phenomenon known as the geometric isotope effect (GIE). Here, the authors find that a hydrogen-bonded host–guest crystal, imidazolium hydrogen terephthalate, exhibits significant GIE on its hydrogen bonds, changing its crystal phases and...

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Autores principales:	Chao Shi, Xi Zhang, Chun-Hua Yu, Ye-Feng Yao, Wen Zhang
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2018
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/f622c25b6f0740778669052d277b6c0c
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id	oai:doaj.org-article:f622c25b6f0740778669052d277b6c0c
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spelling	oai:doaj.org-article:f622c25b6f0740778669052d277b6c0c2021-12-02T16:49:31ZGeometric isotope effect of deuteration in a hydrogen-bonded host–guest crystal10.1038/s41467-018-02931-82041-1723https://doaj.org/article/f622c25b6f0740778669052d277b6c0c2018-02-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-02931-8https://doaj.org/toc/2041-1723Deuterating a hydrogen bond can change the bond’s geometry, a phenomenon known as the geometric isotope effect (GIE). Here, the authors find that a hydrogen-bonded host–guest crystal, imidazolium hydrogen terephthalate, exhibits significant GIE on its hydrogen bonds, changing its crystal phases and bulk dielectric properties.Chao ShiXi ZhangChun-Hua YuYe-Feng YaoWen ZhangNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-9 (2018)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Chao Shi Xi Zhang Chun-Hua Yu Ye-Feng Yao Wen Zhang Geometric isotope effect of deuteration in a hydrogen-bonded host–guest crystal
description	Deuterating a hydrogen bond can change the bond’s geometry, a phenomenon known as the geometric isotope effect (GIE). Here, the authors find that a hydrogen-bonded host–guest crystal, imidazolium hydrogen terephthalate, exhibits significant GIE on its hydrogen bonds, changing its crystal phases and bulk dielectric properties.
format	article
author	Chao Shi Xi Zhang Chun-Hua Yu Ye-Feng Yao Wen Zhang
author_facet	Chao Shi Xi Zhang Chun-Hua Yu Ye-Feng Yao Wen Zhang
author_sort	Chao Shi
title	Geometric isotope effect of deuteration in a hydrogen-bonded host–guest crystal
title_short	Geometric isotope effect of deuteration in a hydrogen-bonded host–guest crystal
title_full	Geometric isotope effect of deuteration in a hydrogen-bonded host–guest crystal
title_fullStr	Geometric isotope effect of deuteration in a hydrogen-bonded host–guest crystal
title_full_unstemmed	Geometric isotope effect of deuteration in a hydrogen-bonded host–guest crystal
title_sort	geometric isotope effect of deuteration in a hydrogen-bonded host–guest crystal
publisher	Nature Portfolio
publishDate	2018
url	https://doaj.org/article/f622c25b6f0740778669052d277b6c0c
work_keys_str_mv	AT chaoshi geometricisotopeeffectofdeuterationinahydrogenbondedhostguestcrystal AT xizhang geometricisotopeeffectofdeuterationinahydrogenbondedhostguestcrystal AT chunhuayu geometricisotopeeffectofdeuterationinahydrogenbondedhostguestcrystal AT yefengyao geometricisotopeeffectofdeuterationinahydrogenbondedhostguestcrystal AT wenzhang geometricisotopeeffectofdeuterationinahydrogenbondedhostguestcrystal
_version_	1718383312904388608

Geometric isotope effect of deuteration in a hydrogen-bonded host–guest crystal

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