Syntheses and crystal structures of two copper(I)–halide π,σ-coordination compounds based on 2-[(prop-2-en-1-yl)sulfanyl]pyridine

The title compounds, di-μ-chlorido-bis({2-[(η-2,3)-(prop-2-en-1-yl)sulfanyl]pyridine-κN}copper(I)), [Cu2Cl2(C8H9NS)2], and di-μ-bromido-bis({2-[(η-2,3)-(prop-2-en-1-yl)sulfanyl]pyridine-κN}copper(I)), [Cu2Br2(C8H9NS)2], were obtained by alternating-current electrochemical synthesis starting from an...

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Autores principales:	Yurii Slyvka, Nazariy T. Pokhodylo, Evgeny Goreshnik, Olexii Pavlyuk, Marian Mys'kiv
Formato:	article
Lenguaje:	EN
Publicado:	International Union of Crystallography 2021
Materias:	copper(i) η2-interaction pyridine-2-thiol allyl derivative crystal structure Chemistry QD1-999
Acceso en línea:	https://doaj.org/article/f64313f65fe54a058474045563ade960
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spelling	oai:doaj.org-article:f64313f65fe54a058474045563ade9602021-11-12T11:16:09ZSyntheses and crystal structures of two copper(I)–halide π,σ-coordination compounds based on 2-[(prop-2-en-1-yl)sulfanyl]pyridine2056-989010.1107/S2056989021011002https://doaj.org/article/f64313f65fe54a058474045563ade9602021-11-01T00:00:00Zhttp://scripts.iucr.org/cgi-bin/paper?S2056989021011002https://doaj.org/toc/2056-9890The title compounds, di-μ-chlorido-bis({2-[(η-2,3)-(prop-2-en-1-yl)sulfanyl]pyridine-κN}copper(I)), [Cu2Cl2(C8H9NS)2], and di-μ-bromido-bis({2-[(η-2,3)-(prop-2-en-1-yl)sulfanyl]pyridine-κN}copper(I)), [Cu2Br2(C8H9NS)2], were obtained by alternating-current electrochemical synthesis starting from an ethanolic solution of 2-[(prop-2-en-1-yl)sulfanyl]pyridine (Psup) and the copper(II) halide. The isostructural crystals are built up from centrosymmetric [Cu2Hal2(Psup)2] dimers, which are formed due to the π,σ-chelating behavior of the organic ligand. In the crystals, the dimers are linked by C—H...Hal hydrogen bonds as well as by aromatic π–π stacking interactions into a three-dimensional network.Yurii SlyvkaNazariy T. PokhodyloEvgeny GoreshnikOlexii PavlyukMarian Mys'kivInternational Union of Crystallographyarticlecopper(i)η2-interactionpyridine-2-thiolallyl derivativecrystal structureChemistryQD1-999ENActa Crystallographica Section E: Crystallographic Communications, Vol 77, Iss 11, Pp 1180-1184 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	copper(i) η2-interaction pyridine-2-thiol allyl derivative crystal structure Chemistry QD1-999
spellingShingle	copper(i) η2-interaction pyridine-2-thiol allyl derivative crystal structure Chemistry QD1-999 Yurii Slyvka Nazariy T. Pokhodylo Evgeny Goreshnik Olexii Pavlyuk Marian Mys'kiv Syntheses and crystal structures of two copper(I)–halide π,σ-coordination compounds based on 2-[(prop-2-en-1-yl)sulfanyl]pyridine
description	The title compounds, di-μ-chlorido-bis({2-[(η-2,3)-(prop-2-en-1-yl)sulfanyl]pyridine-κN}copper(I)), [Cu2Cl2(C8H9NS)2], and di-μ-bromido-bis({2-[(η-2,3)-(prop-2-en-1-yl)sulfanyl]pyridine-κN}copper(I)), [Cu2Br2(C8H9NS)2], were obtained by alternating-current electrochemical synthesis starting from an ethanolic solution of 2-[(prop-2-en-1-yl)sulfanyl]pyridine (Psup) and the copper(II) halide. The isostructural crystals are built up from centrosymmetric [Cu2Hal2(Psup)2] dimers, which are formed due to the π,σ-chelating behavior of the organic ligand. In the crystals, the dimers are linked by C—H...Hal hydrogen bonds as well as by aromatic π–π stacking interactions into a three-dimensional network.
format	article
author	Yurii Slyvka Nazariy T. Pokhodylo Evgeny Goreshnik Olexii Pavlyuk Marian Mys'kiv
author_facet	Yurii Slyvka Nazariy T. Pokhodylo Evgeny Goreshnik Olexii Pavlyuk Marian Mys'kiv
author_sort	Yurii Slyvka
title	Syntheses and crystal structures of two copper(I)–halide π,σ-coordination compounds based on 2-[(prop-2-en-1-yl)sulfanyl]pyridine
title_short	Syntheses and crystal structures of two copper(I)–halide π,σ-coordination compounds based on 2-[(prop-2-en-1-yl)sulfanyl]pyridine
title_full	Syntheses and crystal structures of two copper(I)–halide π,σ-coordination compounds based on 2-[(prop-2-en-1-yl)sulfanyl]pyridine
title_fullStr	Syntheses and crystal structures of two copper(I)–halide π,σ-coordination compounds based on 2-[(prop-2-en-1-yl)sulfanyl]pyridine
title_full_unstemmed	Syntheses and crystal structures of two copper(I)–halide π,σ-coordination compounds based on 2-[(prop-2-en-1-yl)sulfanyl]pyridine
title_sort	syntheses and crystal structures of two copper(i)–halide π,σ-coordination compounds based on 2-[(prop-2-en-1-yl)sulfanyl]pyridine
publisher	International Union of Crystallography
publishDate	2021
url	https://doaj.org/article/f64313f65fe54a058474045563ade960
work_keys_str_mv	AT yuriislyvka synthesesandcrystalstructuresoftwocopperihalidepscoordinationcompoundsbasedon2prop2en1ylsulfanylpyridine AT nazariytpokhodylo synthesesandcrystalstructuresoftwocopperihalidepscoordinationcompoundsbasedon2prop2en1ylsulfanylpyridine AT evgenygoreshnik synthesesandcrystalstructuresoftwocopperihalidepscoordinationcompoundsbasedon2prop2en1ylsulfanylpyridine AT olexiipavlyuk synthesesandcrystalstructuresoftwocopperihalidepscoordinationcompoundsbasedon2prop2en1ylsulfanylpyridine AT marianmyskiv synthesesandcrystalstructuresoftwocopperihalidepscoordinationcompoundsbasedon2prop2en1ylsulfanylpyridine
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Syntheses and crystal structures of two copper(I)–halide π,σ-coordination compounds based on 2-[(prop-2-en-1-yl)sulfanyl]pyridine

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