Triamidoamine thorium-arsenic complexes with parent arsenide, arsinidiide and arsenido structural motifs

Advances in actinide chemistry have led to the isolation of a range of uranium–ligand multiple bonds, but analogous thorium complexes are rare. Here, the authors prepare thorium–arsenic complexes that are stabilized by bulky triamidoamine ligands and exhibit ThAsH2, ThAs(H)K, ThAs(H)Th and ThAsTh li...

Descripción completa

Guardado en:
Detalles Bibliográficos
Autores principales: Elizabeth P. Wildman, Gábor Balázs, Ashley J. Wooles, Manfred Scheer, Stephen T. Liddle
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2017
Materias:
Q
Acceso en línea:https://doaj.org/article/f709b23a7f1e474d822dea1f9b44a9dc
Etiquetas: Agregar Etiqueta
Sin Etiquetas, Sea el primero en etiquetar este registro!
Descripción
Sumario:Advances in actinide chemistry have led to the isolation of a range of uranium–ligand multiple bonds, but analogous thorium complexes are rare. Here, the authors prepare thorium–arsenic complexes that are stabilized by bulky triamidoamine ligands and exhibit ThAsH2, ThAs(H)K, ThAs(H)Th and ThAsTh linkages.