Triamidoamine thorium-arsenic complexes with parent arsenide, arsinidiide and arsenido structural motifs

Advances in actinide chemistry have led to the isolation of a range of uranium–ligand multiple bonds, but analogous thorium complexes are rare. Here, the authors prepare thorium–arsenic complexes that are stabilized by bulky triamidoamine ligands and exhibit ThAsH2, ThAs(H)K, ThAs(H)Th and ThAsTh li...

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Autores principales: Elizabeth P. Wildman, Gábor Balázs, Ashley J. Wooles, Manfred Scheer, Stephen T. Liddle
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2017
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Acceso en línea:https://doaj.org/article/f709b23a7f1e474d822dea1f9b44a9dc
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spelling oai:doaj.org-article:f709b23a7f1e474d822dea1f9b44a9dc2021-12-02T14:40:23ZTriamidoamine thorium-arsenic complexes with parent arsenide, arsinidiide and arsenido structural motifs10.1038/ncomms147692041-1723https://doaj.org/article/f709b23a7f1e474d822dea1f9b44a9dc2017-03-01T00:00:00Zhttps://doi.org/10.1038/ncomms14769https://doaj.org/toc/2041-1723Advances in actinide chemistry have led to the isolation of a range of uranium–ligand multiple bonds, but analogous thorium complexes are rare. Here, the authors prepare thorium–arsenic complexes that are stabilized by bulky triamidoamine ligands and exhibit ThAsH2, ThAs(H)K, ThAs(H)Th and ThAsTh linkages.Elizabeth P. WildmanGábor BalázsAshley J. WoolesManfred ScheerStephen T. LiddleNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-9 (2017)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Elizabeth P. Wildman
Gábor Balázs
Ashley J. Wooles
Manfred Scheer
Stephen T. Liddle
Triamidoamine thorium-arsenic complexes with parent arsenide, arsinidiide and arsenido structural motifs
description Advances in actinide chemistry have led to the isolation of a range of uranium–ligand multiple bonds, but analogous thorium complexes are rare. Here, the authors prepare thorium–arsenic complexes that are stabilized by bulky triamidoamine ligands and exhibit ThAsH2, ThAs(H)K, ThAs(H)Th and ThAsTh linkages.
format article
author Elizabeth P. Wildman
Gábor Balázs
Ashley J. Wooles
Manfred Scheer
Stephen T. Liddle
author_facet Elizabeth P. Wildman
Gábor Balázs
Ashley J. Wooles
Manfred Scheer
Stephen T. Liddle
author_sort Elizabeth P. Wildman
title Triamidoamine thorium-arsenic complexes with parent arsenide, arsinidiide and arsenido structural motifs
title_short Triamidoamine thorium-arsenic complexes with parent arsenide, arsinidiide and arsenido structural motifs
title_full Triamidoamine thorium-arsenic complexes with parent arsenide, arsinidiide and arsenido structural motifs
title_fullStr Triamidoamine thorium-arsenic complexes with parent arsenide, arsinidiide and arsenido structural motifs
title_full_unstemmed Triamidoamine thorium-arsenic complexes with parent arsenide, arsinidiide and arsenido structural motifs
title_sort triamidoamine thorium-arsenic complexes with parent arsenide, arsinidiide and arsenido structural motifs
publisher Nature Portfolio
publishDate 2017
url https://doaj.org/article/f709b23a7f1e474d822dea1f9b44a9dc
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AT ashleyjwooles triamidoaminethoriumarseniccomplexeswithparentarsenidearsinidiideandarsenidostructuralmotifs
AT manfredscheer triamidoaminethoriumarseniccomplexeswithparentarsenidearsinidiideandarsenidostructuralmotifs
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