Triamidoamine thorium-arsenic complexes with parent arsenide, arsinidiide and arsenido structural motifs
Advances in actinide chemistry have led to the isolation of a range of uranium–ligand multiple bonds, but analogous thorium complexes are rare. Here, the authors prepare thorium–arsenic complexes that are stabilized by bulky triamidoamine ligands and exhibit ThAsH2, ThAs(H)K, ThAs(H)Th and ThAsTh li...
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Nature Portfolio
2017
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oai:doaj.org-article:f709b23a7f1e474d822dea1f9b44a9dc2021-12-02T14:40:23ZTriamidoamine thorium-arsenic complexes with parent arsenide, arsinidiide and arsenido structural motifs10.1038/ncomms147692041-1723https://doaj.org/article/f709b23a7f1e474d822dea1f9b44a9dc2017-03-01T00:00:00Zhttps://doi.org/10.1038/ncomms14769https://doaj.org/toc/2041-1723Advances in actinide chemistry have led to the isolation of a range of uranium–ligand multiple bonds, but analogous thorium complexes are rare. Here, the authors prepare thorium–arsenic complexes that are stabilized by bulky triamidoamine ligands and exhibit ThAsH2, ThAs(H)K, ThAs(H)Th and ThAsTh linkages.Elizabeth P. WildmanGábor BalázsAshley J. WoolesManfred ScheerStephen T. LiddleNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-9 (2017) |
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Science Q Elizabeth P. Wildman Gábor Balázs Ashley J. Wooles Manfred Scheer Stephen T. Liddle Triamidoamine thorium-arsenic complexes with parent arsenide, arsinidiide and arsenido structural motifs |
description |
Advances in actinide chemistry have led to the isolation of a range of uranium–ligand multiple bonds, but analogous thorium complexes are rare. Here, the authors prepare thorium–arsenic complexes that are stabilized by bulky triamidoamine ligands and exhibit ThAsH2, ThAs(H)K, ThAs(H)Th and ThAsTh linkages. |
format |
article |
author |
Elizabeth P. Wildman Gábor Balázs Ashley J. Wooles Manfred Scheer Stephen T. Liddle |
author_facet |
Elizabeth P. Wildman Gábor Balázs Ashley J. Wooles Manfred Scheer Stephen T. Liddle |
author_sort |
Elizabeth P. Wildman |
title |
Triamidoamine thorium-arsenic complexes with parent arsenide, arsinidiide and arsenido structural motifs |
title_short |
Triamidoamine thorium-arsenic complexes with parent arsenide, arsinidiide and arsenido structural motifs |
title_full |
Triamidoamine thorium-arsenic complexes with parent arsenide, arsinidiide and arsenido structural motifs |
title_fullStr |
Triamidoamine thorium-arsenic complexes with parent arsenide, arsinidiide and arsenido structural motifs |
title_full_unstemmed |
Triamidoamine thorium-arsenic complexes with parent arsenide, arsinidiide and arsenido structural motifs |
title_sort |
triamidoamine thorium-arsenic complexes with parent arsenide, arsinidiide and arsenido structural motifs |
publisher |
Nature Portfolio |
publishDate |
2017 |
url |
https://doaj.org/article/f709b23a7f1e474d822dea1f9b44a9dc |
work_keys_str_mv |
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1718390333733076992 |