Triamidoamine thorium-arsenic complexes with parent arsenide, arsinidiide and arsenido structural motifs

Advances in actinide chemistry have led to the isolation of a range of uranium–ligand multiple bonds, but analogous thorium complexes are rare. Here, the authors prepare thorium–arsenic complexes that are stabilized by bulky triamidoamine ligands and exhibit ThAsH2, ThAs(H)K, ThAs(H)Th and ThAsTh li...

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Main Authors:	Elizabeth P. Wildman, Gábor Balázs, Ashley J. Wooles, Manfred Scheer, Stephen T. Liddle
Format:	article
Language:	EN
Published:	Nature Portfolio 2017
Subjects:	Science Q
Online Access:	https://doaj.org/article/f709b23a7f1e474d822dea1f9b44a9dc
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spelling	oai:doaj.org-article:f709b23a7f1e474d822dea1f9b44a9dc2021-12-02T14:40:23ZTriamidoamine thorium-arsenic complexes with parent arsenide, arsinidiide and arsenido structural motifs10.1038/ncomms147692041-1723https://doaj.org/article/f709b23a7f1e474d822dea1f9b44a9dc2017-03-01T00:00:00Zhttps://doi.org/10.1038/ncomms14769https://doaj.org/toc/2041-1723Advances in actinide chemistry have led to the isolation of a range of uranium–ligand multiple bonds, but analogous thorium complexes are rare. Here, the authors prepare thorium–arsenic complexes that are stabilized by bulky triamidoamine ligands and exhibit ThAsH2, ThAs(H)K, ThAs(H)Th and ThAsTh linkages.Elizabeth P. WildmanGábor BalázsAshley J. WoolesManfred ScheerStephen T. LiddleNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-9 (2017)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Elizabeth P. Wildman Gábor Balázs Ashley J. Wooles Manfred Scheer Stephen T. Liddle Triamidoamine thorium-arsenic complexes with parent arsenide, arsinidiide and arsenido structural motifs
description	Advances in actinide chemistry have led to the isolation of a range of uranium–ligand multiple bonds, but analogous thorium complexes are rare. Here, the authors prepare thorium–arsenic complexes that are stabilized by bulky triamidoamine ligands and exhibit ThAsH2, ThAs(H)K, ThAs(H)Th and ThAsTh linkages.
format	article
author	Elizabeth P. Wildman Gábor Balázs Ashley J. Wooles Manfred Scheer Stephen T. Liddle
author_facet	Elizabeth P. Wildman Gábor Balázs Ashley J. Wooles Manfred Scheer Stephen T. Liddle
author_sort	Elizabeth P. Wildman
title	Triamidoamine thorium-arsenic complexes with parent arsenide, arsinidiide and arsenido structural motifs
title_short	Triamidoamine thorium-arsenic complexes with parent arsenide, arsinidiide and arsenido structural motifs
title_full	Triamidoamine thorium-arsenic complexes with parent arsenide, arsinidiide and arsenido structural motifs
title_fullStr	Triamidoamine thorium-arsenic complexes with parent arsenide, arsinidiide and arsenido structural motifs
title_full_unstemmed	Triamidoamine thorium-arsenic complexes with parent arsenide, arsinidiide and arsenido structural motifs
title_sort	triamidoamine thorium-arsenic complexes with parent arsenide, arsinidiide and arsenido structural motifs
publisher	Nature Portfolio
publishDate	2017
url	https://doaj.org/article/f709b23a7f1e474d822dea1f9b44a9dc
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Triamidoamine thorium-arsenic complexes with parent arsenide, arsinidiide and arsenido structural motifs

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