Breaking a dative bond with mechanical forces

Controlled breaking of a chemical bond by mechanical forces can provide key insight into reaction mechanisms. Here the authors, using atomic force microscopy and computations, measure the forces involved in breaking a single dative bond between a CO molecule and a ferrous phthalocyanine complex.

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Autores principales: Pengcheng Chen, Dingxin Fan, Yunlong Zhang, Annabella Selloni, Emily A. Carter, Craig B. Arnold, David C. Dankworth, Steven P. Rucker, James R. Chelikowsky, Nan Yao
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2021
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Acceso en línea:https://doaj.org/article/f71109c16f8e4370a7100d9ab5b3b7b1
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spelling oai:doaj.org-article:f71109c16f8e4370a7100d9ab5b3b7b12021-12-02T18:14:09ZBreaking a dative bond with mechanical forces10.1038/s41467-021-25932-62041-1723https://doaj.org/article/f71109c16f8e4370a7100d9ab5b3b7b12021-09-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-25932-6https://doaj.org/toc/2041-1723Controlled breaking of a chemical bond by mechanical forces can provide key insight into reaction mechanisms. Here the authors, using atomic force microscopy and computations, measure the forces involved in breaking a single dative bond between a CO molecule and a ferrous phthalocyanine complex.Pengcheng ChenDingxin FanYunlong ZhangAnnabella SelloniEmily A. CarterCraig B. ArnoldDavid C. DankworthSteven P. RuckerJames R. ChelikowskyNan YaoNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-7 (2021)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Pengcheng Chen
Dingxin Fan
Yunlong Zhang
Annabella Selloni
Emily A. Carter
Craig B. Arnold
David C. Dankworth
Steven P. Rucker
James R. Chelikowsky
Nan Yao
Breaking a dative bond with mechanical forces
description Controlled breaking of a chemical bond by mechanical forces can provide key insight into reaction mechanisms. Here the authors, using atomic force microscopy and computations, measure the forces involved in breaking a single dative bond between a CO molecule and a ferrous phthalocyanine complex.
format article
author Pengcheng Chen
Dingxin Fan
Yunlong Zhang
Annabella Selloni
Emily A. Carter
Craig B. Arnold
David C. Dankworth
Steven P. Rucker
James R. Chelikowsky
Nan Yao
author_facet Pengcheng Chen
Dingxin Fan
Yunlong Zhang
Annabella Selloni
Emily A. Carter
Craig B. Arnold
David C. Dankworth
Steven P. Rucker
James R. Chelikowsky
Nan Yao
author_sort Pengcheng Chen
title Breaking a dative bond with mechanical forces
title_short Breaking a dative bond with mechanical forces
title_full Breaking a dative bond with mechanical forces
title_fullStr Breaking a dative bond with mechanical forces
title_full_unstemmed Breaking a dative bond with mechanical forces
title_sort breaking a dative bond with mechanical forces
publisher Nature Portfolio
publishDate 2021
url https://doaj.org/article/f71109c16f8e4370a7100d9ab5b3b7b1
work_keys_str_mv AT pengchengchen breakingadativebondwithmechanicalforces
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AT yunlongzhang breakingadativebondwithmechanicalforces
AT annabellaselloni breakingadativebondwithmechanicalforces
AT emilyacarter breakingadativebondwithmechanicalforces
AT craigbarnold breakingadativebondwithmechanicalforces
AT davidcdankworth breakingadativebondwithmechanicalforces
AT stevenprucker breakingadativebondwithmechanicalforces
AT jamesrchelikowsky breakingadativebondwithmechanicalforces
AT nanyao breakingadativebondwithmechanicalforces
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