Breaking a dative bond with mechanical forces
Controlled breaking of a chemical bond by mechanical forces can provide key insight into reaction mechanisms. Here the authors, using atomic force microscopy and computations, measure the forces involved in breaking a single dative bond between a CO molecule and a ferrous phthalocyanine complex.
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Nature Portfolio
2021
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oai:doaj.org-article:f71109c16f8e4370a7100d9ab5b3b7b12021-12-02T18:14:09ZBreaking a dative bond with mechanical forces10.1038/s41467-021-25932-62041-1723https://doaj.org/article/f71109c16f8e4370a7100d9ab5b3b7b12021-09-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-25932-6https://doaj.org/toc/2041-1723Controlled breaking of a chemical bond by mechanical forces can provide key insight into reaction mechanisms. Here the authors, using atomic force microscopy and computations, measure the forces involved in breaking a single dative bond between a CO molecule and a ferrous phthalocyanine complex.Pengcheng ChenDingxin FanYunlong ZhangAnnabella SelloniEmily A. CarterCraig B. ArnoldDavid C. DankworthSteven P. RuckerJames R. ChelikowskyNan YaoNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-7 (2021) |
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DOAJ |
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EN |
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Science Q |
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Science Q Pengcheng Chen Dingxin Fan Yunlong Zhang Annabella Selloni Emily A. Carter Craig B. Arnold David C. Dankworth Steven P. Rucker James R. Chelikowsky Nan Yao Breaking a dative bond with mechanical forces |
description |
Controlled breaking of a chemical bond by mechanical forces can provide key insight into reaction mechanisms. Here the authors, using atomic force microscopy and computations, measure the forces involved in breaking a single dative bond between a CO molecule and a ferrous phthalocyanine complex. |
format |
article |
author |
Pengcheng Chen Dingxin Fan Yunlong Zhang Annabella Selloni Emily A. Carter Craig B. Arnold David C. Dankworth Steven P. Rucker James R. Chelikowsky Nan Yao |
author_facet |
Pengcheng Chen Dingxin Fan Yunlong Zhang Annabella Selloni Emily A. Carter Craig B. Arnold David C. Dankworth Steven P. Rucker James R. Chelikowsky Nan Yao |
author_sort |
Pengcheng Chen |
title |
Breaking a dative bond with mechanical forces |
title_short |
Breaking a dative bond with mechanical forces |
title_full |
Breaking a dative bond with mechanical forces |
title_fullStr |
Breaking a dative bond with mechanical forces |
title_full_unstemmed |
Breaking a dative bond with mechanical forces |
title_sort |
breaking a dative bond with mechanical forces |
publisher |
Nature Portfolio |
publishDate |
2021 |
url |
https://doaj.org/article/f71109c16f8e4370a7100d9ab5b3b7b1 |
work_keys_str_mv |
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_version_ |
1718378488698765312 |