Hidden structural and chemical order controls lithium transport in cation-disordered oxides for rechargeable batteries

The average crystal structure largely governs the Li diffusion kinetics in well-ordered cathode materials. Here the authors show this rule does not hold true for cation-disordered analogues. Cation short-range order is not only ubiquitous but also controls the Li transport behavior.

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Autores principales: Huiwen Ji, Alexander Urban, Daniil A. Kitchaev, Deok-Hwang Kwon, Nongnuch Artrith, Colin Ophus, Wenxuan Huang, Zijian Cai, Tan Shi, Jae Chul Kim, Haegyeom Kim, Gerbrand Ceder
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Lenguaje:EN
Publicado: Nature Portfolio 2019
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Acceso en línea:https://doaj.org/article/f73de8766e0944acbf5e035577535a51
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spelling oai:doaj.org-article:f73de8766e0944acbf5e035577535a512021-12-02T16:57:55ZHidden structural and chemical order controls lithium transport in cation-disordered oxides for rechargeable batteries10.1038/s41467-019-08490-w2041-1723https://doaj.org/article/f73de8766e0944acbf5e035577535a512019-02-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-08490-whttps://doaj.org/toc/2041-1723The average crystal structure largely governs the Li diffusion kinetics in well-ordered cathode materials. Here the authors show this rule does not hold true for cation-disordered analogues. Cation short-range order is not only ubiquitous but also controls the Li transport behavior.Huiwen JiAlexander UrbanDaniil A. KitchaevDeok-Hwang KwonNongnuch ArtrithColin OphusWenxuan HuangZijian CaiTan ShiJae Chul KimHaegyeom KimGerbrand CederNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-9 (2019)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Huiwen Ji
Alexander Urban
Daniil A. Kitchaev
Deok-Hwang Kwon
Nongnuch Artrith
Colin Ophus
Wenxuan Huang
Zijian Cai
Tan Shi
Jae Chul Kim
Haegyeom Kim
Gerbrand Ceder
Hidden structural and chemical order controls lithium transport in cation-disordered oxides for rechargeable batteries
description The average crystal structure largely governs the Li diffusion kinetics in well-ordered cathode materials. Here the authors show this rule does not hold true for cation-disordered analogues. Cation short-range order is not only ubiquitous but also controls the Li transport behavior.
format article
author Huiwen Ji
Alexander Urban
Daniil A. Kitchaev
Deok-Hwang Kwon
Nongnuch Artrith
Colin Ophus
Wenxuan Huang
Zijian Cai
Tan Shi
Jae Chul Kim
Haegyeom Kim
Gerbrand Ceder
author_facet Huiwen Ji
Alexander Urban
Daniil A. Kitchaev
Deok-Hwang Kwon
Nongnuch Artrith
Colin Ophus
Wenxuan Huang
Zijian Cai
Tan Shi
Jae Chul Kim
Haegyeom Kim
Gerbrand Ceder
author_sort Huiwen Ji
title Hidden structural and chemical order controls lithium transport in cation-disordered oxides for rechargeable batteries
title_short Hidden structural and chemical order controls lithium transport in cation-disordered oxides for rechargeable batteries
title_full Hidden structural and chemical order controls lithium transport in cation-disordered oxides for rechargeable batteries
title_fullStr Hidden structural and chemical order controls lithium transport in cation-disordered oxides for rechargeable batteries
title_full_unstemmed Hidden structural and chemical order controls lithium transport in cation-disordered oxides for rechargeable batteries
title_sort hidden structural and chemical order controls lithium transport in cation-disordered oxides for rechargeable batteries
publisher Nature Portfolio
publishDate 2019
url https://doaj.org/article/f73de8766e0944acbf5e035577535a51
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