Hidden structural and chemical order controls lithium transport in cation-disordered oxides for rechargeable batteries
The average crystal structure largely governs the Li diffusion kinetics in well-ordered cathode materials. Here the authors show this rule does not hold true for cation-disordered analogues. Cation short-range order is not only ubiquitous but also controls the Li transport behavior.
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Nature Portfolio
2019
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oai:doaj.org-article:f73de8766e0944acbf5e035577535a512021-12-02T16:57:55ZHidden structural and chemical order controls lithium transport in cation-disordered oxides for rechargeable batteries10.1038/s41467-019-08490-w2041-1723https://doaj.org/article/f73de8766e0944acbf5e035577535a512019-02-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-08490-whttps://doaj.org/toc/2041-1723The average crystal structure largely governs the Li diffusion kinetics in well-ordered cathode materials. Here the authors show this rule does not hold true for cation-disordered analogues. Cation short-range order is not only ubiquitous but also controls the Li transport behavior.Huiwen JiAlexander UrbanDaniil A. KitchaevDeok-Hwang KwonNongnuch ArtrithColin OphusWenxuan HuangZijian CaiTan ShiJae Chul KimHaegyeom KimGerbrand CederNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-9 (2019) |
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Science Q |
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Science Q Huiwen Ji Alexander Urban Daniil A. Kitchaev Deok-Hwang Kwon Nongnuch Artrith Colin Ophus Wenxuan Huang Zijian Cai Tan Shi Jae Chul Kim Haegyeom Kim Gerbrand Ceder Hidden structural and chemical order controls lithium transport in cation-disordered oxides for rechargeable batteries |
description |
The average crystal structure largely governs the Li diffusion kinetics in well-ordered cathode materials. Here the authors show this rule does not hold true for cation-disordered analogues. Cation short-range order is not only ubiquitous but also controls the Li transport behavior. |
format |
article |
author |
Huiwen Ji Alexander Urban Daniil A. Kitchaev Deok-Hwang Kwon Nongnuch Artrith Colin Ophus Wenxuan Huang Zijian Cai Tan Shi Jae Chul Kim Haegyeom Kim Gerbrand Ceder |
author_facet |
Huiwen Ji Alexander Urban Daniil A. Kitchaev Deok-Hwang Kwon Nongnuch Artrith Colin Ophus Wenxuan Huang Zijian Cai Tan Shi Jae Chul Kim Haegyeom Kim Gerbrand Ceder |
author_sort |
Huiwen Ji |
title |
Hidden structural and chemical order controls lithium transport in cation-disordered oxides for rechargeable batteries |
title_short |
Hidden structural and chemical order controls lithium transport in cation-disordered oxides for rechargeable batteries |
title_full |
Hidden structural and chemical order controls lithium transport in cation-disordered oxides for rechargeable batteries |
title_fullStr |
Hidden structural and chemical order controls lithium transport in cation-disordered oxides for rechargeable batteries |
title_full_unstemmed |
Hidden structural and chemical order controls lithium transport in cation-disordered oxides for rechargeable batteries |
title_sort |
hidden structural and chemical order controls lithium transport in cation-disordered oxides for rechargeable batteries |
publisher |
Nature Portfolio |
publishDate |
2019 |
url |
https://doaj.org/article/f73de8766e0944acbf5e035577535a51 |
work_keys_str_mv |
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1718382483251134464 |