Hydrodenitrogenation of pyridines and quinolines at a multinuclear titanium hydride framework

Hydrodenitrogenation is a fundamental process in the petroleum refinery context. Here, the authors report the mild ring-opening and denitrogenation of pyridines and quinolines with a titanium hydride cluster and the unusual formation of denitrogenated cyclic hydrocarbon products.

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Autores principales: Shaowei Hu, Gen Luo, Takanori Shima, Yi Luo, Zhaomin Hou
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2017
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Acceso en línea:https://doaj.org/article/f74e23e1f0ca422e997202c30843c14e
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Sumario:Hydrodenitrogenation is a fundamental process in the petroleum refinery context. Here, the authors report the mild ring-opening and denitrogenation of pyridines and quinolines with a titanium hydride cluster and the unusual formation of denitrogenated cyclic hydrocarbon products.