Continuous negative-to-positive tuning of thermal expansion achieved by controlled gas sorption in porous coordination frameworks
Achieving control over the thermomechanical properties of functional materials is desirable, yet remains highly challenging. Here, the authors demonstrate continuous negative-to-positive tuning of thermal expansion in two Prussian blue analogues, by varying the concentration of adsorbed CO2.
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Nature Portfolio
2018
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oai:doaj.org-article:f76b06f294574459aa5fe53ad4d4dc8b2021-12-02T17:31:58ZContinuous negative-to-positive tuning of thermal expansion achieved by controlled gas sorption in porous coordination frameworks10.1038/s41467-018-06850-62041-1723https://doaj.org/article/f76b06f294574459aa5fe53ad4d4dc8b2018-11-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-06850-6https://doaj.org/toc/2041-1723Achieving control over the thermomechanical properties of functional materials is desirable, yet remains highly challenging. Here, the authors demonstrate continuous negative-to-positive tuning of thermal expansion in two Prussian blue analogues, by varying the concentration of adsorbed CO2.Josie E. AuckettArnold A. BarkhordarianStephen H. OgilvieSamuel G. DuykerHubert ChevreauVanessa K. PetersonCameron J. KepertNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-5 (2018) |
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Science Q |
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Science Q Josie E. Auckett Arnold A. Barkhordarian Stephen H. Ogilvie Samuel G. Duyker Hubert Chevreau Vanessa K. Peterson Cameron J. Kepert Continuous negative-to-positive tuning of thermal expansion achieved by controlled gas sorption in porous coordination frameworks |
description |
Achieving control over the thermomechanical properties of functional materials is desirable, yet remains highly challenging. Here, the authors demonstrate continuous negative-to-positive tuning of thermal expansion in two Prussian blue analogues, by varying the concentration of adsorbed CO2. |
format |
article |
author |
Josie E. Auckett Arnold A. Barkhordarian Stephen H. Ogilvie Samuel G. Duyker Hubert Chevreau Vanessa K. Peterson Cameron J. Kepert |
author_facet |
Josie E. Auckett Arnold A. Barkhordarian Stephen H. Ogilvie Samuel G. Duyker Hubert Chevreau Vanessa K. Peterson Cameron J. Kepert |
author_sort |
Josie E. Auckett |
title |
Continuous negative-to-positive tuning of thermal expansion achieved by controlled gas sorption in porous coordination frameworks |
title_short |
Continuous negative-to-positive tuning of thermal expansion achieved by controlled gas sorption in porous coordination frameworks |
title_full |
Continuous negative-to-positive tuning of thermal expansion achieved by controlled gas sorption in porous coordination frameworks |
title_fullStr |
Continuous negative-to-positive tuning of thermal expansion achieved by controlled gas sorption in porous coordination frameworks |
title_full_unstemmed |
Continuous negative-to-positive tuning of thermal expansion achieved by controlled gas sorption in porous coordination frameworks |
title_sort |
continuous negative-to-positive tuning of thermal expansion achieved by controlled gas sorption in porous coordination frameworks |
publisher |
Nature Portfolio |
publishDate |
2018 |
url |
https://doaj.org/article/f76b06f294574459aa5fe53ad4d4dc8b |
work_keys_str_mv |
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