Continuous negative-to-positive tuning of thermal expansion achieved by controlled gas sorption in porous coordination frameworks

Achieving control over the thermomechanical properties of functional materials is desirable, yet remains highly challenging. Here, the authors demonstrate continuous negative-to-positive tuning of thermal expansion in two Prussian blue analogues, by varying the concentration of adsorbed CO2.

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Autores principales: Josie E. Auckett, Arnold A. Barkhordarian, Stephen H. Ogilvie, Samuel G. Duyker, Hubert Chevreau, Vanessa K. Peterson, Cameron J. Kepert
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2018
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Acceso en línea:https://doaj.org/article/f76b06f294574459aa5fe53ad4d4dc8b
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spelling oai:doaj.org-article:f76b06f294574459aa5fe53ad4d4dc8b2021-12-02T17:31:58ZContinuous negative-to-positive tuning of thermal expansion achieved by controlled gas sorption in porous coordination frameworks10.1038/s41467-018-06850-62041-1723https://doaj.org/article/f76b06f294574459aa5fe53ad4d4dc8b2018-11-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-06850-6https://doaj.org/toc/2041-1723Achieving control over the thermomechanical properties of functional materials is desirable, yet remains highly challenging. Here, the authors demonstrate continuous negative-to-positive tuning of thermal expansion in two Prussian blue analogues, by varying the concentration of adsorbed CO2.Josie E. AuckettArnold A. BarkhordarianStephen H. OgilvieSamuel G. DuykerHubert ChevreauVanessa K. PetersonCameron J. KepertNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-5 (2018)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Josie E. Auckett
Arnold A. Barkhordarian
Stephen H. Ogilvie
Samuel G. Duyker
Hubert Chevreau
Vanessa K. Peterson
Cameron J. Kepert
Continuous negative-to-positive tuning of thermal expansion achieved by controlled gas sorption in porous coordination frameworks
description Achieving control over the thermomechanical properties of functional materials is desirable, yet remains highly challenging. Here, the authors demonstrate continuous negative-to-positive tuning of thermal expansion in two Prussian blue analogues, by varying the concentration of adsorbed CO2.
format article
author Josie E. Auckett
Arnold A. Barkhordarian
Stephen H. Ogilvie
Samuel G. Duyker
Hubert Chevreau
Vanessa K. Peterson
Cameron J. Kepert
author_facet Josie E. Auckett
Arnold A. Barkhordarian
Stephen H. Ogilvie
Samuel G. Duyker
Hubert Chevreau
Vanessa K. Peterson
Cameron J. Kepert
author_sort Josie E. Auckett
title Continuous negative-to-positive tuning of thermal expansion achieved by controlled gas sorption in porous coordination frameworks
title_short Continuous negative-to-positive tuning of thermal expansion achieved by controlled gas sorption in porous coordination frameworks
title_full Continuous negative-to-positive tuning of thermal expansion achieved by controlled gas sorption in porous coordination frameworks
title_fullStr Continuous negative-to-positive tuning of thermal expansion achieved by controlled gas sorption in porous coordination frameworks
title_full_unstemmed Continuous negative-to-positive tuning of thermal expansion achieved by controlled gas sorption in porous coordination frameworks
title_sort continuous negative-to-positive tuning of thermal expansion achieved by controlled gas sorption in porous coordination frameworks
publisher Nature Portfolio
publishDate 2018
url https://doaj.org/article/f76b06f294574459aa5fe53ad4d4dc8b
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