In-situ structure and catalytic mechanism of NiFe and CoFe layered double hydroxides during oxygen evolution

NiFe and CoFe layered double hydroxides are among the most active electrocatalysts for the alkaline oxygen evolution reaction. Here, by combining operando experiments and rigorous DFT calculations, the authors unravel their active phase, the reaction center and the catalytic mechanism.

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Autores principales: Fabio Dionigi, Zhenhua Zeng, Ilya Sinev, Thomas Merzdorf, Siddharth Deshpande, Miguel Bernal Lopez, Sebastian Kunze, Ioannis Zegkinoglou, Hannes Sarodnik, Dingxin Fan, Arno Bergmann, Jakub Drnec, Jorge Ferreira de Araujo, Manuel Gliech, Detre Teschner, Jing Zhu, Wei-Xue Li, Jeffrey Greeley, Beatriz Roldan Cuenya, Peter Strasser
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Publicado: Nature Portfolio 2020
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Acceso en línea:https://doaj.org/article/f76f63f939ac4a989833be814bba62da
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spelling oai:doaj.org-article:f76f63f939ac4a989833be814bba62da2021-12-02T16:51:34ZIn-situ structure and catalytic mechanism of NiFe and CoFe layered double hydroxides during oxygen evolution10.1038/s41467-020-16237-12041-1723https://doaj.org/article/f76f63f939ac4a989833be814bba62da2020-05-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-16237-1https://doaj.org/toc/2041-1723NiFe and CoFe layered double hydroxides are among the most active electrocatalysts for the alkaline oxygen evolution reaction. Here, by combining operando experiments and rigorous DFT calculations, the authors unravel their active phase, the reaction center and the catalytic mechanism.Fabio DionigiZhenhua ZengIlya SinevThomas MerzdorfSiddharth DeshpandeMiguel Bernal LopezSebastian KunzeIoannis ZegkinoglouHannes SarodnikDingxin FanArno BergmannJakub DrnecJorge Ferreira de AraujoManuel GliechDetre TeschnerJing ZhuWei-Xue LiJeffrey GreeleyBeatriz Roldan CuenyaPeter StrasserNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-10 (2020)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Fabio Dionigi
Zhenhua Zeng
Ilya Sinev
Thomas Merzdorf
Siddharth Deshpande
Miguel Bernal Lopez
Sebastian Kunze
Ioannis Zegkinoglou
Hannes Sarodnik
Dingxin Fan
Arno Bergmann
Jakub Drnec
Jorge Ferreira de Araujo
Manuel Gliech
Detre Teschner
Jing Zhu
Wei-Xue Li
Jeffrey Greeley
Beatriz Roldan Cuenya
Peter Strasser
In-situ structure and catalytic mechanism of NiFe and CoFe layered double hydroxides during oxygen evolution
description NiFe and CoFe layered double hydroxides are among the most active electrocatalysts for the alkaline oxygen evolution reaction. Here, by combining operando experiments and rigorous DFT calculations, the authors unravel their active phase, the reaction center and the catalytic mechanism.
format article
author Fabio Dionigi
Zhenhua Zeng
Ilya Sinev
Thomas Merzdorf
Siddharth Deshpande
Miguel Bernal Lopez
Sebastian Kunze
Ioannis Zegkinoglou
Hannes Sarodnik
Dingxin Fan
Arno Bergmann
Jakub Drnec
Jorge Ferreira de Araujo
Manuel Gliech
Detre Teschner
Jing Zhu
Wei-Xue Li
Jeffrey Greeley
Beatriz Roldan Cuenya
Peter Strasser
author_facet Fabio Dionigi
Zhenhua Zeng
Ilya Sinev
Thomas Merzdorf
Siddharth Deshpande
Miguel Bernal Lopez
Sebastian Kunze
Ioannis Zegkinoglou
Hannes Sarodnik
Dingxin Fan
Arno Bergmann
Jakub Drnec
Jorge Ferreira de Araujo
Manuel Gliech
Detre Teschner
Jing Zhu
Wei-Xue Li
Jeffrey Greeley
Beatriz Roldan Cuenya
Peter Strasser
author_sort Fabio Dionigi
title In-situ structure and catalytic mechanism of NiFe and CoFe layered double hydroxides during oxygen evolution
title_short In-situ structure and catalytic mechanism of NiFe and CoFe layered double hydroxides during oxygen evolution
title_full In-situ structure and catalytic mechanism of NiFe and CoFe layered double hydroxides during oxygen evolution
title_fullStr In-situ structure and catalytic mechanism of NiFe and CoFe layered double hydroxides during oxygen evolution
title_full_unstemmed In-situ structure and catalytic mechanism of NiFe and CoFe layered double hydroxides during oxygen evolution
title_sort in-situ structure and catalytic mechanism of nife and cofe layered double hydroxides during oxygen evolution
publisher Nature Portfolio
publishDate 2020
url https://doaj.org/article/f76f63f939ac4a989833be814bba62da
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