Addition of alkynes and osmium carbynes towards functionalized d π–p π conjugated systems

Metal-carbon and carbon-carbon triple bonds are highly unsaturated bonds and their reactions tend to afford cycloaddition intermediates or products. Here, the authors report a new robust reaction on metal-carbon and carbon-carbon triple bonds which affords region- and stereospecific acyclic addition...

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Autores principales:	Shiyan Chen, Longzhu Liu, Xiang Gao, Yuhui Hua, Lixia Peng, Ying Zhang, Liulin Yang, Yuanzhi Tan, Feng He, Haiping Xia
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2020
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/f7aaee7618f049cc8f4d1c6635a00347
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spelling	oai:doaj.org-article:f7aaee7618f049cc8f4d1c6635a003472021-12-02T15:16:06ZAddition of alkynes and osmium carbynes towards functionalized d π–p π conjugated systems10.1038/s41467-020-18498-22041-1723https://doaj.org/article/f7aaee7618f049cc8f4d1c6635a003472020-09-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-18498-2https://doaj.org/toc/2041-1723Metal-carbon and carbon-carbon triple bonds are highly unsaturated bonds and their reactions tend to afford cycloaddition intermediates or products. Here, the authors report a new robust reaction on metal-carbon and carbon-carbon triple bonds which affords region- and stereospecific acyclic addition products.Shiyan ChenLongzhu LiuXiang GaoYuhui HuaLixia PengYing ZhangLiulin YangYuanzhi TanFeng HeHaiping XiaNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-11 (2020)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Shiyan Chen Longzhu Liu Xiang Gao Yuhui Hua Lixia Peng Ying Zhang Liulin Yang Yuanzhi Tan Feng He Haiping Xia Addition of alkynes and osmium carbynes towards functionalized d π–p π conjugated systems
description	Metal-carbon and carbon-carbon triple bonds are highly unsaturated bonds and their reactions tend to afford cycloaddition intermediates or products. Here, the authors report a new robust reaction on metal-carbon and carbon-carbon triple bonds which affords region- and stereospecific acyclic addition products.
format	article
author	Shiyan Chen Longzhu Liu Xiang Gao Yuhui Hua Lixia Peng Ying Zhang Liulin Yang Yuanzhi Tan Feng He Haiping Xia
author_facet	Shiyan Chen Longzhu Liu Xiang Gao Yuhui Hua Lixia Peng Ying Zhang Liulin Yang Yuanzhi Tan Feng He Haiping Xia
author_sort	Shiyan Chen
title	Addition of alkynes and osmium carbynes towards functionalized d π–p π conjugated systems
title_short	Addition of alkynes and osmium carbynes towards functionalized d π–p π conjugated systems
title_full	Addition of alkynes and osmium carbynes towards functionalized d π–p π conjugated systems
title_fullStr	Addition of alkynes and osmium carbynes towards functionalized d π–p π conjugated systems
title_full_unstemmed	Addition of alkynes and osmium carbynes towards functionalized d π–p π conjugated systems
title_sort	addition of alkynes and osmium carbynes towards functionalized d π–p π conjugated systems
publisher	Nature Portfolio
publishDate	2020
url	https://doaj.org/article/f7aaee7618f049cc8f4d1c6635a00347
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Addition of alkynes and osmium carbynes towards functionalized d π–p π conjugated systems

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