Tailored cobalt-salen complexes enable electrocatalytic intramolecular allylic C–H functionalizations

Tailored cobalt-salen complexes enable electrocatalytic intramolecular allylic C–H functionalizations

Oxidative allylic C–H functionalizations minimise the need for functional group activation and generate alkenyl-substituted products amenable to further chemical modifications. Here the authors report an oxidant-free, electrocatalytic approach to achieve intramolecular oxidative allylic C–H aminatio...

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Autores principales: Chen-Yan Cai, Zheng-Jian Wu, Ji-Ying Liu, Ming Chen, Jinshuai Song, Hai-Chao Xu
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2021
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Acceso en línea:https://doaj.org/article/f805f67bc6b2459a8fe06a15095cebe7
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spelling oai:doaj.org-article:f805f67bc6b2459a8fe06a15095cebe72021-12-02T17:23:50ZTailored cobalt-salen complexes enable electrocatalytic intramolecular allylic C–H functionalizations10.1038/s41467-021-24125-52041-1723https://doaj.org/article/f805f67bc6b2459a8fe06a15095cebe72021-06-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-24125-5https://doaj.org/toc/2041-1723Oxidative allylic C–H functionalizations minimise the need for functional group activation and generate alkenyl-substituted products amenable to further chemical modifications. Here the authors report an oxidant-free, electrocatalytic approach to achieve intramolecular oxidative allylic C–H amination and alkylation by employing tailored cobalt-salen complexes as catalysts.Chen-Yan CaiZheng-Jian WuJi-Ying LiuMing ChenJinshuai SongHai-Chao XuNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-9 (2021)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Chen-Yan Cai
Zheng-Jian Wu
Ji-Ying Liu
Ming Chen
Jinshuai Song
Hai-Chao Xu
Tailored cobalt-salen complexes enable electrocatalytic intramolecular allylic C–H functionalizations
description Oxidative allylic C–H functionalizations minimise the need for functional group activation and generate alkenyl-substituted products amenable to further chemical modifications. Here the authors report an oxidant-free, electrocatalytic approach to achieve intramolecular oxidative allylic C–H amination and alkylation by employing tailored cobalt-salen complexes as catalysts.
format article
author Chen-Yan Cai
Zheng-Jian Wu
Ji-Ying Liu
Ming Chen
Jinshuai Song
Hai-Chao Xu
author_facet Chen-Yan Cai
Zheng-Jian Wu
Ji-Ying Liu
Ming Chen
Jinshuai Song
Hai-Chao Xu
author_sort Chen-Yan Cai
title Tailored cobalt-salen complexes enable electrocatalytic intramolecular allylic C–H functionalizations
title_short Tailored cobalt-salen complexes enable electrocatalytic intramolecular allylic C–H functionalizations
title_full Tailored cobalt-salen complexes enable electrocatalytic intramolecular allylic C–H functionalizations
title_fullStr Tailored cobalt-salen complexes enable electrocatalytic intramolecular allylic C–H functionalizations
title_full_unstemmed Tailored cobalt-salen complexes enable electrocatalytic intramolecular allylic C–H functionalizations
title_sort tailored cobalt-salen complexes enable electrocatalytic intramolecular allylic c–h functionalizations
publisher Nature Portfolio
publishDate 2021
url https://doaj.org/article/f805f67bc6b2459a8fe06a15095cebe7
work_keys_str_mv AT chenyancai tailoredcobaltsalencomplexesenableelectrocatalyticintramolecularallylicchfunctionalizations
AT zhengjianwu tailoredcobaltsalencomplexesenableelectrocatalyticintramolecularallylicchfunctionalizations
AT jiyingliu tailoredcobaltsalencomplexesenableelectrocatalyticintramolecularallylicchfunctionalizations
AT mingchen tailoredcobaltsalencomplexesenableelectrocatalyticintramolecularallylicchfunctionalizations
AT jinshuaisong tailoredcobaltsalencomplexesenableelectrocatalyticintramolecularallylicchfunctionalizations
AT haichaoxu tailoredcobaltsalencomplexesenableelectrocatalyticintramolecularallylicchfunctionalizations
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