Role of electrolytes on electrochemical performance of hydrothermally grown Li2MnSiO4 cathode material for Li-ion battery application in the energy nexus frame work

The present work reports the Li2MnSiO4, the next generation of perspective cathode material for lithium-ion batteries application synthesized via a hydrothermal route under optimal conditions and its electrochemical performance in different aqueous electrolytes, such as KOH, NaOH and LiOH is investi...

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Autores principales: Isha Goyal, Prakash Chand, Sunaina, Hardeep Anand
Formato: article
Lenguaje:EN
Publicado: Elsevier 2021
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Acceso en línea:https://doaj.org/article/f82af8255e2c4660aa2b41209d028282
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spelling oai:doaj.org-article:f82af8255e2c4660aa2b41209d0282822021-12-02T05:04:53ZRole of electrolytes on electrochemical performance of hydrothermally grown Li2MnSiO4 cathode material for Li-ion battery application in the energy nexus frame work2772-427110.1016/j.nexus.2021.100013https://doaj.org/article/f82af8255e2c4660aa2b41209d0282822021-12-01T00:00:00Zhttp://www.sciencedirect.com/science/article/pii/S2772427121000139https://doaj.org/toc/2772-4271The present work reports the Li2MnSiO4, the next generation of perspective cathode material for lithium-ion batteries application synthesized via a hydrothermal route under optimal conditions and its electrochemical performance in different aqueous electrolytes, such as KOH, NaOH and LiOH is investigated. X-ray diffraction revealed orthorhombic structure with the Pmn21 space group. Scanning Electron Microscope analysis shows the flower-like morphology which results in better electrochemical performance. Fourier Transform Infrared analysis has been done to identify the chemical bonds present in the material. The electrochemical characterization of the as-prepared cathode material in different aqueous electrolytes was done using CHI760E Electrochemical station with Ag/AgCl as a reference electrode. Cyclic Voltammetry is used to calculate the diffusion coefficient for each electrolyte and also cyclic voltammetry graphs have been generated for each electrolyte which shows different power ratings at different scan rates. Galvanostatic charge-discharge is used to determine the specific capacity of the material in each electrolyte. The results analysis shows that electrochemical performance is greatly affected by the nature of the electrolyte and the maximum specific capacity is found to be KOH (2M) in comparison to the other two electrolytes. Therefore, the selection of electrolytes plays a crucial function in the electrochemical performance of cathode material for lithium-ion battery applications.Isha GoyalPrakash Chand SunainaHardeep AnandElsevierarticleLi2MnSiO4HydrothermalElectrochemical propertiesAqueous electrolytesLithium-ion batteriesRenewable energy sourcesTJ807-830Agriculture (General)S1-972ENEnergy Nexus, Vol 2, Iss , Pp 100013- (2021)
institution DOAJ
collection DOAJ
language EN
topic Li2MnSiO4
Hydrothermal
Electrochemical properties
Aqueous electrolytes
Lithium-ion batteries
Renewable energy sources
TJ807-830
Agriculture (General)
S1-972
spellingShingle Li2MnSiO4
Hydrothermal
Electrochemical properties
Aqueous electrolytes
Lithium-ion batteries
Renewable energy sources
TJ807-830
Agriculture (General)
S1-972
Isha Goyal
Prakash Chand
Sunaina
Hardeep Anand
Role of electrolytes on electrochemical performance of hydrothermally grown Li2MnSiO4 cathode material for Li-ion battery application in the energy nexus frame work
description The present work reports the Li2MnSiO4, the next generation of perspective cathode material for lithium-ion batteries application synthesized via a hydrothermal route under optimal conditions and its electrochemical performance in different aqueous electrolytes, such as KOH, NaOH and LiOH is investigated. X-ray diffraction revealed orthorhombic structure with the Pmn21 space group. Scanning Electron Microscope analysis shows the flower-like morphology which results in better electrochemical performance. Fourier Transform Infrared analysis has been done to identify the chemical bonds present in the material. The electrochemical characterization of the as-prepared cathode material in different aqueous electrolytes was done using CHI760E Electrochemical station with Ag/AgCl as a reference electrode. Cyclic Voltammetry is used to calculate the diffusion coefficient for each electrolyte and also cyclic voltammetry graphs have been generated for each electrolyte which shows different power ratings at different scan rates. Galvanostatic charge-discharge is used to determine the specific capacity of the material in each electrolyte. The results analysis shows that electrochemical performance is greatly affected by the nature of the electrolyte and the maximum specific capacity is found to be KOH (2M) in comparison to the other two electrolytes. Therefore, the selection of electrolytes plays a crucial function in the electrochemical performance of cathode material for lithium-ion battery applications.
format article
author Isha Goyal
Prakash Chand
Sunaina
Hardeep Anand
author_facet Isha Goyal
Prakash Chand
Sunaina
Hardeep Anand
author_sort Isha Goyal
title Role of electrolytes on electrochemical performance of hydrothermally grown Li2MnSiO4 cathode material for Li-ion battery application in the energy nexus frame work
title_short Role of electrolytes on electrochemical performance of hydrothermally grown Li2MnSiO4 cathode material for Li-ion battery application in the energy nexus frame work
title_full Role of electrolytes on electrochemical performance of hydrothermally grown Li2MnSiO4 cathode material for Li-ion battery application in the energy nexus frame work
title_fullStr Role of electrolytes on electrochemical performance of hydrothermally grown Li2MnSiO4 cathode material for Li-ion battery application in the energy nexus frame work
title_full_unstemmed Role of electrolytes on electrochemical performance of hydrothermally grown Li2MnSiO4 cathode material for Li-ion battery application in the energy nexus frame work
title_sort role of electrolytes on electrochemical performance of hydrothermally grown li2mnsio4 cathode material for li-ion battery application in the energy nexus frame work
publisher Elsevier
publishDate 2021
url https://doaj.org/article/f82af8255e2c4660aa2b41209d028282
work_keys_str_mv AT ishagoyal roleofelectrolytesonelectrochemicalperformanceofhydrothermallygrownli2mnsio4cathodematerialforliionbatteryapplicationintheenergynexusframework
AT prakashchand roleofelectrolytesonelectrochemicalperformanceofhydrothermallygrownli2mnsio4cathodematerialforliionbatteryapplicationintheenergynexusframework
AT sunaina roleofelectrolytesonelectrochemicalperformanceofhydrothermallygrownli2mnsio4cathodematerialforliionbatteryapplicationintheenergynexusframework
AT hardeepanand roleofelectrolytesonelectrochemicalperformanceofhydrothermallygrownli2mnsio4cathodematerialforliionbatteryapplicationintheenergynexusframework
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