Role of electrolytes on electrochemical performance of hydrothermally grown Li2MnSiO4 cathode material for Li-ion battery application in the energy nexus frame work
The present work reports the Li2MnSiO4, the next generation of perspective cathode material for lithium-ion batteries application synthesized via a hydrothermal route under optimal conditions and its electrochemical performance in different aqueous electrolytes, such as KOH, NaOH and LiOH is investi...
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2021
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oai:doaj.org-article:f82af8255e2c4660aa2b41209d0282822021-12-02T05:04:53ZRole of electrolytes on electrochemical performance of hydrothermally grown Li2MnSiO4 cathode material for Li-ion battery application in the energy nexus frame work2772-427110.1016/j.nexus.2021.100013https://doaj.org/article/f82af8255e2c4660aa2b41209d0282822021-12-01T00:00:00Zhttp://www.sciencedirect.com/science/article/pii/S2772427121000139https://doaj.org/toc/2772-4271The present work reports the Li2MnSiO4, the next generation of perspective cathode material for lithium-ion batteries application synthesized via a hydrothermal route under optimal conditions and its electrochemical performance in different aqueous electrolytes, such as KOH, NaOH and LiOH is investigated. X-ray diffraction revealed orthorhombic structure with the Pmn21 space group. Scanning Electron Microscope analysis shows the flower-like morphology which results in better electrochemical performance. Fourier Transform Infrared analysis has been done to identify the chemical bonds present in the material. The electrochemical characterization of the as-prepared cathode material in different aqueous electrolytes was done using CHI760E Electrochemical station with Ag/AgCl as a reference electrode. Cyclic Voltammetry is used to calculate the diffusion coefficient for each electrolyte and also cyclic voltammetry graphs have been generated for each electrolyte which shows different power ratings at different scan rates. Galvanostatic charge-discharge is used to determine the specific capacity of the material in each electrolyte. The results analysis shows that electrochemical performance is greatly affected by the nature of the electrolyte and the maximum specific capacity is found to be KOH (2M) in comparison to the other two electrolytes. Therefore, the selection of electrolytes plays a crucial function in the electrochemical performance of cathode material for lithium-ion battery applications.Isha GoyalPrakash Chand SunainaHardeep AnandElsevierarticleLi2MnSiO4HydrothermalElectrochemical propertiesAqueous electrolytesLithium-ion batteriesRenewable energy sourcesTJ807-830Agriculture (General)S1-972ENEnergy Nexus, Vol 2, Iss , Pp 100013- (2021) |
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Li2MnSiO4 Hydrothermal Electrochemical properties Aqueous electrolytes Lithium-ion batteries Renewable energy sources TJ807-830 Agriculture (General) S1-972 |
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Li2MnSiO4 Hydrothermal Electrochemical properties Aqueous electrolytes Lithium-ion batteries Renewable energy sources TJ807-830 Agriculture (General) S1-972 Isha Goyal Prakash Chand Sunaina Hardeep Anand Role of electrolytes on electrochemical performance of hydrothermally grown Li2MnSiO4 cathode material for Li-ion battery application in the energy nexus frame work |
description |
The present work reports the Li2MnSiO4, the next generation of perspective cathode material for lithium-ion batteries application synthesized via a hydrothermal route under optimal conditions and its electrochemical performance in different aqueous electrolytes, such as KOH, NaOH and LiOH is investigated. X-ray diffraction revealed orthorhombic structure with the Pmn21 space group. Scanning Electron Microscope analysis shows the flower-like morphology which results in better electrochemical performance. Fourier Transform Infrared analysis has been done to identify the chemical bonds present in the material. The electrochemical characterization of the as-prepared cathode material in different aqueous electrolytes was done using CHI760E Electrochemical station with Ag/AgCl as a reference electrode. Cyclic Voltammetry is used to calculate the diffusion coefficient for each electrolyte and also cyclic voltammetry graphs have been generated for each electrolyte which shows different power ratings at different scan rates. Galvanostatic charge-discharge is used to determine the specific capacity of the material in each electrolyte. The results analysis shows that electrochemical performance is greatly affected by the nature of the electrolyte and the maximum specific capacity is found to be KOH (2M) in comparison to the other two electrolytes. Therefore, the selection of electrolytes plays a crucial function in the electrochemical performance of cathode material for lithium-ion battery applications. |
format |
article |
author |
Isha Goyal Prakash Chand Sunaina Hardeep Anand |
author_facet |
Isha Goyal Prakash Chand Sunaina Hardeep Anand |
author_sort |
Isha Goyal |
title |
Role of electrolytes on electrochemical performance of hydrothermally grown Li2MnSiO4 cathode material for Li-ion battery application in the energy nexus frame work |
title_short |
Role of electrolytes on electrochemical performance of hydrothermally grown Li2MnSiO4 cathode material for Li-ion battery application in the energy nexus frame work |
title_full |
Role of electrolytes on electrochemical performance of hydrothermally grown Li2MnSiO4 cathode material for Li-ion battery application in the energy nexus frame work |
title_fullStr |
Role of electrolytes on electrochemical performance of hydrothermally grown Li2MnSiO4 cathode material for Li-ion battery application in the energy nexus frame work |
title_full_unstemmed |
Role of electrolytes on electrochemical performance of hydrothermally grown Li2MnSiO4 cathode material for Li-ion battery application in the energy nexus frame work |
title_sort |
role of electrolytes on electrochemical performance of hydrothermally grown li2mnsio4 cathode material for li-ion battery application in the energy nexus frame work |
publisher |
Elsevier |
publishDate |
2021 |
url |
https://doaj.org/article/f82af8255e2c4660aa2b41209d028282 |
work_keys_str_mv |
AT ishagoyal roleofelectrolytesonelectrochemicalperformanceofhydrothermallygrownli2mnsio4cathodematerialforliionbatteryapplicationintheenergynexusframework AT prakashchand roleofelectrolytesonelectrochemicalperformanceofhydrothermallygrownli2mnsio4cathodematerialforliionbatteryapplicationintheenergynexusframework AT sunaina roleofelectrolytesonelectrochemicalperformanceofhydrothermallygrownli2mnsio4cathodematerialforliionbatteryapplicationintheenergynexusframework AT hardeepanand roleofelectrolytesonelectrochemicalperformanceofhydrothermallygrownli2mnsio4cathodematerialforliionbatteryapplicationintheenergynexusframework |
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1718400628988837888 |