Geochemical Distribution of Copper and Zinc in the Aquatic Sediment of Nyolo Spring Water at Karangploso Malang East Java

Aquatic sediment has a role for heavy metals sink. Understanding the geochemical fractions of heavy metals in the aquatic sediment can predict the mobility and reactivity of heavy metals fractions that can induce environmental problems. The aim of this study was to determine the distribution of geoc...

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Autores principales: Anis Khoirun Nisa, Barlah Rumhayati, Andi Kurniawan
Formato: article
Lenguaje:EN
Publicado: University of Brawijaya 2019
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Acceso en línea:http://dx.doi.org/10.21776/ub.jpacr.2019.008.01.443
https://doaj.org/article/f82c5af5dd554ce59bf12c1c1408f45c
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spelling oai:doaj.org-article:f82c5af5dd554ce59bf12c1c1408f45c2021-12-02T13:13:59ZGeochemical Distribution of Copper and Zinc in the Aquatic Sediment of Nyolo Spring Water at Karangploso Malang East Javahttp://dx.doi.org/10.21776/ub.jpacr.2019.008.01.4432302-46902302-4690https://doaj.org/article/f82c5af5dd554ce59bf12c1c1408f45c2019-01-01T00:00:00Zhttps://jpacr.ub.ac.id/index.php/jpacr/article/view/443/pdfhttps://doaj.org/toc/2302-4690https://doaj.org/toc/2302-4690Aquatic sediment has a role for heavy metals sink. Understanding the geochemical fractions of heavy metals in the aquatic sediment can predict the mobility and reactivity of heavy metals fractions that can induce environmental problems. The aim of this study was to determine the distribution of geochemical fractions of copper and zinc in aquatic sediment of Nyolo spring. Sediments samples were taken from five locations along the spring. Geochemical fractions of copper and zinc were extracted using BCR (Community Bureau of Reference) sequential extraction method. The concentration of these metals in each extract was analyzed using AAS. The result showed that overall the sediment consisted of zinc at a higher concentration than copper. Amongst the geochemical fractions, copper and zinc were found dominantly at an oxidizable fraction. As the first fraction, Zn was more bioavailable than copper for biological uptake. Furthermore, based on the Risk Assessment Code (RAC) value, the aquatic sediment of Nyolo Spring was low risk to the Zn and Cu contaminations at most sites, except for Zn in Site III showed a medium risk. This metals fraction will potentially available for organism uptake with the changing of pH sediment or overlying water.Anis Khoirun NisaBarlah RumhayatiAndi KurniawanUniversity of Brawijayaarticlecopperzincnyolo springbcr sequential extraction methodChemistryQD1-999ENJournal of Pure and Applied Chemistry Research, Vol 8, Iss 1, Pp 62-72 (2019)
institution DOAJ
collection DOAJ
language EN
topic copper
zinc
nyolo spring
bcr sequential extraction method
Chemistry
QD1-999
spellingShingle copper
zinc
nyolo spring
bcr sequential extraction method
Chemistry
QD1-999
Anis Khoirun Nisa
Barlah Rumhayati
Andi Kurniawan
Geochemical Distribution of Copper and Zinc in the Aquatic Sediment of Nyolo Spring Water at Karangploso Malang East Java
description Aquatic sediment has a role for heavy metals sink. Understanding the geochemical fractions of heavy metals in the aquatic sediment can predict the mobility and reactivity of heavy metals fractions that can induce environmental problems. The aim of this study was to determine the distribution of geochemical fractions of copper and zinc in aquatic sediment of Nyolo spring. Sediments samples were taken from five locations along the spring. Geochemical fractions of copper and zinc were extracted using BCR (Community Bureau of Reference) sequential extraction method. The concentration of these metals in each extract was analyzed using AAS. The result showed that overall the sediment consisted of zinc at a higher concentration than copper. Amongst the geochemical fractions, copper and zinc were found dominantly at an oxidizable fraction. As the first fraction, Zn was more bioavailable than copper for biological uptake. Furthermore, based on the Risk Assessment Code (RAC) value, the aquatic sediment of Nyolo Spring was low risk to the Zn and Cu contaminations at most sites, except for Zn in Site III showed a medium risk. This metals fraction will potentially available for organism uptake with the changing of pH sediment or overlying water.
format article
author Anis Khoirun Nisa
Barlah Rumhayati
Andi Kurniawan
author_facet Anis Khoirun Nisa
Barlah Rumhayati
Andi Kurniawan
author_sort Anis Khoirun Nisa
title Geochemical Distribution of Copper and Zinc in the Aquatic Sediment of Nyolo Spring Water at Karangploso Malang East Java
title_short Geochemical Distribution of Copper and Zinc in the Aquatic Sediment of Nyolo Spring Water at Karangploso Malang East Java
title_full Geochemical Distribution of Copper and Zinc in the Aquatic Sediment of Nyolo Spring Water at Karangploso Malang East Java
title_fullStr Geochemical Distribution of Copper and Zinc in the Aquatic Sediment of Nyolo Spring Water at Karangploso Malang East Java
title_full_unstemmed Geochemical Distribution of Copper and Zinc in the Aquatic Sediment of Nyolo Spring Water at Karangploso Malang East Java
title_sort geochemical distribution of copper and zinc in the aquatic sediment of nyolo spring water at karangploso malang east java
publisher University of Brawijaya
publishDate 2019
url http://dx.doi.org/10.21776/ub.jpacr.2019.008.01.443
https://doaj.org/article/f82c5af5dd554ce59bf12c1c1408f45c
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