C(sp3)−C(sp3) bond formation via nickel-catalyzed deoxygenative homo-coupling of aldehydes/ketones mediated by hydrazine

C(sp3)−C(sp3) bond formation via nickel-catalyzed deoxygenative homo-coupling of aldehydes/ketones mediated by hydrazine

The direct deoxygenative coupling of aldehydes or ketones to construct C(sp3)−C(sp3) bond remains a scientific challenge. Here the authors use a nickel−catalyzed reductive homo-coupling of moisture- and air-stable hydrazones generated in-situ from naturally abundant aldehydes and ketones to construc...

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Autores principales: Dawei Cao, Chen-Chen Li, Huiying Zeng, Yong Peng, Chao-Jun Li
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2021
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Acceso en línea:https://doaj.org/article/f836b94ce8f54b75ae72685adf15cd2e
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spelling oai:doaj.org-article:f836b94ce8f54b75ae72685adf15cd2e2021-12-02T16:04:16ZC(sp3)−C(sp3) bond formation via nickel-catalyzed deoxygenative homo-coupling of aldehydes/ketones mediated by hydrazine10.1038/s41467-021-23971-72041-1723https://doaj.org/article/f836b94ce8f54b75ae72685adf15cd2e2021-06-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-23971-7https://doaj.org/toc/2041-1723The direct deoxygenative coupling of aldehydes or ketones to construct C(sp3)−C(sp3) bond remains a scientific challenge. Here the authors use a nickel−catalyzed reductive homo-coupling of moisture- and air-stable hydrazones generated in-situ from naturally abundant aldehydes and ketones to construct challenging C(sp3)−C(sp3) bonds.Dawei CaoChen-Chen LiHuiying ZengYong PengChao-Jun LiNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-8 (2021)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Dawei Cao
Chen-Chen Li
Huiying Zeng
Yong Peng
Chao-Jun Li
C(sp3)−C(sp3) bond formation via nickel-catalyzed deoxygenative homo-coupling of aldehydes/ketones mediated by hydrazine
description The direct deoxygenative coupling of aldehydes or ketones to construct C(sp3)−C(sp3) bond remains a scientific challenge. Here the authors use a nickel−catalyzed reductive homo-coupling of moisture- and air-stable hydrazones generated in-situ from naturally abundant aldehydes and ketones to construct challenging C(sp3)−C(sp3) bonds.
format article
author Dawei Cao
Chen-Chen Li
Huiying Zeng
Yong Peng
Chao-Jun Li
author_facet Dawei Cao
Chen-Chen Li
Huiying Zeng
Yong Peng
Chao-Jun Li
author_sort Dawei Cao
title C(sp3)−C(sp3) bond formation via nickel-catalyzed deoxygenative homo-coupling of aldehydes/ketones mediated by hydrazine
title_short C(sp3)−C(sp3) bond formation via nickel-catalyzed deoxygenative homo-coupling of aldehydes/ketones mediated by hydrazine
title_full C(sp3)−C(sp3) bond formation via nickel-catalyzed deoxygenative homo-coupling of aldehydes/ketones mediated by hydrazine
title_fullStr C(sp3)−C(sp3) bond formation via nickel-catalyzed deoxygenative homo-coupling of aldehydes/ketones mediated by hydrazine
title_full_unstemmed C(sp3)−C(sp3) bond formation via nickel-catalyzed deoxygenative homo-coupling of aldehydes/ketones mediated by hydrazine
title_sort c(sp3)−c(sp3) bond formation via nickel-catalyzed deoxygenative homo-coupling of aldehydes/ketones mediated by hydrazine
publisher Nature Portfolio
publishDate 2021
url https://doaj.org/article/f836b94ce8f54b75ae72685adf15cd2e
work_keys_str_mv AT daweicao csp3csp3bondformationvianickelcatalyzeddeoxygenativehomocouplingofaldehydesketonesmediatedbyhydrazine
AT chenchenli csp3csp3bondformationvianickelcatalyzeddeoxygenativehomocouplingofaldehydesketonesmediatedbyhydrazine
AT huiyingzeng csp3csp3bondformationvianickelcatalyzeddeoxygenativehomocouplingofaldehydesketonesmediatedbyhydrazine
AT yongpeng csp3csp3bondformationvianickelcatalyzeddeoxygenativehomocouplingofaldehydesketonesmediatedbyhydrazine
AT chaojunli csp3csp3bondformationvianickelcatalyzeddeoxygenativehomocouplingofaldehydesketonesmediatedbyhydrazine
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