Metal–peptide rings form highly entangled topologically inequivalent frameworks with the same ring- and crossing-numbers

For interlocking ring structures, knot theory predicts that the number of topologically different links increases with ring and crossing number. Here, the authors use a peptide folding-and-assembly strategy to selectively realize two highly entangled catenanes with 4 rings and 12 crossings, represen...

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Autores principales:	Tomohisa Sawada, Ami Saito, Kenki Tamiya, Koya Shimokawa, Yutaro Hisada, Makoto Fujita
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2019
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/f85555a38c764ff59bba5713c9780de9
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spelling	oai:doaj.org-article:f85555a38c764ff59bba5713c9780de92021-12-02T15:36:23ZMetal–peptide rings form highly entangled topologically inequivalent frameworks with the same ring- and crossing-numbers10.1038/s41467-019-08879-72041-1723https://doaj.org/article/f85555a38c764ff59bba5713c9780de92019-02-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-08879-7https://doaj.org/toc/2041-1723For interlocking ring structures, knot theory predicts that the number of topologically different links increases with ring and crossing number. Here, the authors use a peptide folding-and-assembly strategy to selectively realize two highly entangled catenanes with 4 rings and 12 crossings, representing two of the 100 predicted topologies with this complexity.Tomohisa SawadaAmi SaitoKenki TamiyaKoya ShimokawaYutaro HisadaMakoto FujitaNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-7 (2019)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Tomohisa Sawada Ami Saito Kenki Tamiya Koya Shimokawa Yutaro Hisada Makoto Fujita Metal–peptide rings form highly entangled topologically inequivalent frameworks with the same ring- and crossing-numbers
description	For interlocking ring structures, knot theory predicts that the number of topologically different links increases with ring and crossing number. Here, the authors use a peptide folding-and-assembly strategy to selectively realize two highly entangled catenanes with 4 rings and 12 crossings, representing two of the 100 predicted topologies with this complexity.
format	article
author	Tomohisa Sawada Ami Saito Kenki Tamiya Koya Shimokawa Yutaro Hisada Makoto Fujita
author_facet	Tomohisa Sawada Ami Saito Kenki Tamiya Koya Shimokawa Yutaro Hisada Makoto Fujita
author_sort	Tomohisa Sawada
title	Metal–peptide rings form highly entangled topologically inequivalent frameworks with the same ring- and crossing-numbers
title_short	Metal–peptide rings form highly entangled topologically inequivalent frameworks with the same ring- and crossing-numbers
title_full	Metal–peptide rings form highly entangled topologically inequivalent frameworks with the same ring- and crossing-numbers
title_fullStr	Metal–peptide rings form highly entangled topologically inequivalent frameworks with the same ring- and crossing-numbers
title_full_unstemmed	Metal–peptide rings form highly entangled topologically inequivalent frameworks with the same ring- and crossing-numbers
title_sort	metal–peptide rings form highly entangled topologically inequivalent frameworks with the same ring- and crossing-numbers
publisher	Nature Portfolio
publishDate	2019
url	https://doaj.org/article/f85555a38c764ff59bba5713c9780de9
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Metal–peptide rings form highly entangled topologically inequivalent frameworks with the same ring- and crossing-numbers

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