Sequence-regulated copolymerization based on periodic covalent positioning of monomers along one-dimensional nanochannels

Achieving sequence control in polymers is limited by the relative monomer reactivity and thus often statistically random copolymers are obtained. Here the authors show sequence control in radical polymerizations by immobilising the monomer on a porous coordination polymer and subsequent polymerizati...

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Autores principales:	Shuto Mochizuki, Naoki Ogiwara, Masayoshi Takayanagi, Masataka Nagaoka, Susumu Kitagawa, Takashi Uemura
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2018
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/f85941af7cf64d5d8069e014b447ea07
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spelling	oai:doaj.org-article:f85941af7cf64d5d8069e014b447ea072021-12-02T15:34:15ZSequence-regulated copolymerization based on periodic covalent positioning of monomers along one-dimensional nanochannels10.1038/s41467-017-02736-12041-1723https://doaj.org/article/f85941af7cf64d5d8069e014b447ea072018-01-01T00:00:00Zhttps://doi.org/10.1038/s41467-017-02736-1https://doaj.org/toc/2041-1723Achieving sequence control in polymers is limited by the relative monomer reactivity and thus often statistically random copolymers are obtained. Here the authors show sequence control in radical polymerizations by immobilising the monomer on a porous coordination polymer and subsequent polymerization with a second free monomer.Shuto MochizukiNaoki OgiwaraMasayoshi TakayanagiMasataka NagaokaSusumu KitagawaTakashi UemuraNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-6 (2018)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Shuto Mochizuki Naoki Ogiwara Masayoshi Takayanagi Masataka Nagaoka Susumu Kitagawa Takashi Uemura Sequence-regulated copolymerization based on periodic covalent positioning of monomers along one-dimensional nanochannels
description	Achieving sequence control in polymers is limited by the relative monomer reactivity and thus often statistically random copolymers are obtained. Here the authors show sequence control in radical polymerizations by immobilising the monomer on a porous coordination polymer and subsequent polymerization with a second free monomer.
format	article
author	Shuto Mochizuki Naoki Ogiwara Masayoshi Takayanagi Masataka Nagaoka Susumu Kitagawa Takashi Uemura
author_facet	Shuto Mochizuki Naoki Ogiwara Masayoshi Takayanagi Masataka Nagaoka Susumu Kitagawa Takashi Uemura
author_sort	Shuto Mochizuki
title	Sequence-regulated copolymerization based on periodic covalent positioning of monomers along one-dimensional nanochannels
title_short	Sequence-regulated copolymerization based on periodic covalent positioning of monomers along one-dimensional nanochannels
title_full	Sequence-regulated copolymerization based on periodic covalent positioning of monomers along one-dimensional nanochannels
title_fullStr	Sequence-regulated copolymerization based on periodic covalent positioning of monomers along one-dimensional nanochannels
title_full_unstemmed	Sequence-regulated copolymerization based on periodic covalent positioning of monomers along one-dimensional nanochannels
title_sort	sequence-regulated copolymerization based on periodic covalent positioning of monomers along one-dimensional nanochannels
publisher	Nature Portfolio
publishDate	2018
url	https://doaj.org/article/f85941af7cf64d5d8069e014b447ea07
work_keys_str_mv	AT shutomochizuki sequenceregulatedcopolymerizationbasedonperiodiccovalentpositioningofmonomersalongonedimensionalnanochannels AT naokiogiwara sequenceregulatedcopolymerizationbasedonperiodiccovalentpositioningofmonomersalongonedimensionalnanochannels AT masayoshitakayanagi sequenceregulatedcopolymerizationbasedonperiodiccovalentpositioningofmonomersalongonedimensionalnanochannels AT masatakanagaoka sequenceregulatedcopolymerizationbasedonperiodiccovalentpositioningofmonomersalongonedimensionalnanochannels AT susumukitagawa sequenceregulatedcopolymerizationbasedonperiodiccovalentpositioningofmonomersalongonedimensionalnanochannels AT takashiuemura sequenceregulatedcopolymerizationbasedonperiodiccovalentpositioningofmonomersalongonedimensionalnanochannels
_version_	1718386939097251840

Sequence-regulated copolymerization based on periodic covalent positioning of monomers along one-dimensional nanochannels

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