Impedance spectroscopy study of the AC conductivity of sodium superoxide nanoparticles doped vanadate based glasses

In the present work, we successfully prepared sodium superoxide (NaO2) doped vanadium phosphate borate glasses using normal melt quenching technique of composition 60V2O5–5P2O5–(35-x) B2O3–xNaO2, x  = 0, 10, 15 and 20 mol %. The foremost objective of this work is to explore the transport properties...

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Autores principales: R.V. Barde, K.R. Nemade, S.A. Waghuley
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Lenguaje:EN
Publicado: KeAi Communications Co., Ltd. 2021
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Acceso en línea:https://doaj.org/article/f87cd903fb8745cc8eac0f6b4ea77e71
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spelling oai:doaj.org-article:f87cd903fb8745cc8eac0f6b4ea77e712021-11-30T04:17:01ZImpedance spectroscopy study of the AC conductivity of sodium superoxide nanoparticles doped vanadate based glasses2589-299110.1016/j.mset.2021.06.004https://doaj.org/article/f87cd903fb8745cc8eac0f6b4ea77e712021-01-01T00:00:00Zhttp://www.sciencedirect.com/science/article/pii/S2589299121000197https://doaj.org/toc/2589-2991In the present work, we successfully prepared sodium superoxide (NaO2) doped vanadium phosphate borate glasses using normal melt quenching technique of composition 60V2O5–5P2O5–(35-x) B2O3–xNaO2, x  = 0, 10, 15 and 20 mol %. The foremost objective of this work is to explore the transport properties of sodium superoxide doped vanadium phosphate borate glasses. The impedance spectroscopy was employed to investigate transport properties of all glass systems under study. The AC conductivity for all glass systems were investigated in temperature range 308–473 K. The Jonscher's power law found to be fit with conductivity data, which decrease with temperature and satisfies the criteria of the correlated hopping model. The activation energy (Ea) estimated from the Arrhenius plot and it is observed to be 0.12 eV.R.V. BardeK.R. NemadeS.A. WaghuleyKeAi Communications Co., Ltd.articleSodium superoxideNyquist plotsElectrical conductivityImpedance spectroscopyHopping distanceMaterials of engineering and construction. Mechanics of materialsTA401-492Energy conservationTJ163.26-163.5ENMaterials Science for Energy Technologies, Vol 4, Iss , Pp 202-207 (2021)
institution DOAJ
collection DOAJ
language EN
topic Sodium superoxide
Nyquist plots
Electrical conductivity
Impedance spectroscopy
Hopping distance
Materials of engineering and construction. Mechanics of materials
TA401-492
Energy conservation
TJ163.26-163.5
spellingShingle Sodium superoxide
Nyquist plots
Electrical conductivity
Impedance spectroscopy
Hopping distance
Materials of engineering and construction. Mechanics of materials
TA401-492
Energy conservation
TJ163.26-163.5
R.V. Barde
K.R. Nemade
S.A. Waghuley
Impedance spectroscopy study of the AC conductivity of sodium superoxide nanoparticles doped vanadate based glasses
description In the present work, we successfully prepared sodium superoxide (NaO2) doped vanadium phosphate borate glasses using normal melt quenching technique of composition 60V2O5–5P2O5–(35-x) B2O3–xNaO2, x  = 0, 10, 15 and 20 mol %. The foremost objective of this work is to explore the transport properties of sodium superoxide doped vanadium phosphate borate glasses. The impedance spectroscopy was employed to investigate transport properties of all glass systems under study. The AC conductivity for all glass systems were investigated in temperature range 308–473 K. The Jonscher's power law found to be fit with conductivity data, which decrease with temperature and satisfies the criteria of the correlated hopping model. The activation energy (Ea) estimated from the Arrhenius plot and it is observed to be 0.12 eV.
format article
author R.V. Barde
K.R. Nemade
S.A. Waghuley
author_facet R.V. Barde
K.R. Nemade
S.A. Waghuley
author_sort R.V. Barde
title Impedance spectroscopy study of the AC conductivity of sodium superoxide nanoparticles doped vanadate based glasses
title_short Impedance spectroscopy study of the AC conductivity of sodium superoxide nanoparticles doped vanadate based glasses
title_full Impedance spectroscopy study of the AC conductivity of sodium superoxide nanoparticles doped vanadate based glasses
title_fullStr Impedance spectroscopy study of the AC conductivity of sodium superoxide nanoparticles doped vanadate based glasses
title_full_unstemmed Impedance spectroscopy study of the AC conductivity of sodium superoxide nanoparticles doped vanadate based glasses
title_sort impedance spectroscopy study of the ac conductivity of sodium superoxide nanoparticles doped vanadate based glasses
publisher KeAi Communications Co., Ltd.
publishDate 2021
url https://doaj.org/article/f87cd903fb8745cc8eac0f6b4ea77e71
work_keys_str_mv AT rvbarde impedancespectroscopystudyoftheacconductivityofsodiumsuperoxidenanoparticlesdopedvanadatebasedglasses
AT krnemade impedancespectroscopystudyoftheacconductivityofsodiumsuperoxidenanoparticlesdopedvanadatebasedglasses
AT sawaghuley impedancespectroscopystudyoftheacconductivityofsodiumsuperoxidenanoparticlesdopedvanadatebasedglasses
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