H-bonded reusable template assisted para-selective ketonisation using soft electrophilic vinyl ethers
Electrophilic acylation of arenes is largely limited to electron rich systems, non-polar medium and often displays moderate selectivity. Here, the authors show a directed para-selective ketonisation of arenes, overriding electronic bias and structural congestion, and apply it to the synthesis of bio...
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Nature Portfolio
2018
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oai:doaj.org-article:f8e52a1b27b94288a6c5af4e4c47e1b52021-12-02T15:33:45ZH-bonded reusable template assisted para-selective ketonisation using soft electrophilic vinyl ethers10.1038/s41467-018-06018-22041-1723https://doaj.org/article/f8e52a1b27b94288a6c5af4e4c47e1b52018-09-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-06018-2https://doaj.org/toc/2041-1723Electrophilic acylation of arenes is largely limited to electron rich systems, non-polar medium and often displays moderate selectivity. Here, the authors show a directed para-selective ketonisation of arenes, overriding electronic bias and structural congestion, and apply it to the synthesis of bioactive compounds.Arun MajiAmit DahiyaGang LuTrisha BhattacharyaMassimo BrochettaGiuseppe ZanoniPeng LiuDebabrata MaitiNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-10 (2018) |
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Science Q Arun Maji Amit Dahiya Gang Lu Trisha Bhattacharya Massimo Brochetta Giuseppe Zanoni Peng Liu Debabrata Maiti H-bonded reusable template assisted para-selective ketonisation using soft electrophilic vinyl ethers |
description |
Electrophilic acylation of arenes is largely limited to electron rich systems, non-polar medium and often displays moderate selectivity. Here, the authors show a directed para-selective ketonisation of arenes, overriding electronic bias and structural congestion, and apply it to the synthesis of bioactive compounds. |
format |
article |
author |
Arun Maji Amit Dahiya Gang Lu Trisha Bhattacharya Massimo Brochetta Giuseppe Zanoni Peng Liu Debabrata Maiti |
author_facet |
Arun Maji Amit Dahiya Gang Lu Trisha Bhattacharya Massimo Brochetta Giuseppe Zanoni Peng Liu Debabrata Maiti |
author_sort |
Arun Maji |
title |
H-bonded reusable template assisted para-selective ketonisation using soft electrophilic vinyl ethers |
title_short |
H-bonded reusable template assisted para-selective ketonisation using soft electrophilic vinyl ethers |
title_full |
H-bonded reusable template assisted para-selective ketonisation using soft electrophilic vinyl ethers |
title_fullStr |
H-bonded reusable template assisted para-selective ketonisation using soft electrophilic vinyl ethers |
title_full_unstemmed |
H-bonded reusable template assisted para-selective ketonisation using soft electrophilic vinyl ethers |
title_sort |
h-bonded reusable template assisted para-selective ketonisation using soft electrophilic vinyl ethers |
publisher |
Nature Portfolio |
publishDate |
2018 |
url |
https://doaj.org/article/f8e52a1b27b94288a6c5af4e4c47e1b5 |
work_keys_str_mv |
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_version_ |
1718387061106409472 |