H-bonded reusable template assisted para-selective ketonisation using soft electrophilic vinyl ethers

Electrophilic acylation of arenes is largely limited to electron rich systems, non-polar medium and often displays moderate selectivity. Here, the authors show a directed para-selective ketonisation of arenes, overriding electronic bias and structural congestion, and apply it to the synthesis of bio...

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Main Authors:	Arun Maji, Amit Dahiya, Gang Lu, Trisha Bhattacharya, Massimo Brochetta, Giuseppe Zanoni, Peng Liu, Debabrata Maiti
Format:	article
Language:	EN
Published:	Nature Portfolio 2018
Subjects:	Science Q
Online Access:	https://doaj.org/article/f8e52a1b27b94288a6c5af4e4c47e1b5
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id	oai:doaj.org-article:f8e52a1b27b94288a6c5af4e4c47e1b5
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spelling	oai:doaj.org-article:f8e52a1b27b94288a6c5af4e4c47e1b52021-12-02T15:33:45ZH-bonded reusable template assisted para-selective ketonisation using soft electrophilic vinyl ethers10.1038/s41467-018-06018-22041-1723https://doaj.org/article/f8e52a1b27b94288a6c5af4e4c47e1b52018-09-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-06018-2https://doaj.org/toc/2041-1723Electrophilic acylation of arenes is largely limited to electron rich systems, non-polar medium and often displays moderate selectivity. Here, the authors show a directed para-selective ketonisation of arenes, overriding electronic bias and structural congestion, and apply it to the synthesis of bioactive compounds.Arun MajiAmit DahiyaGang LuTrisha BhattacharyaMassimo BrochettaGiuseppe ZanoniPeng LiuDebabrata MaitiNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-10 (2018)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Arun Maji Amit Dahiya Gang Lu Trisha Bhattacharya Massimo Brochetta Giuseppe Zanoni Peng Liu Debabrata Maiti H-bonded reusable template assisted para-selective ketonisation using soft electrophilic vinyl ethers
description	Electrophilic acylation of arenes is largely limited to electron rich systems, non-polar medium and often displays moderate selectivity. Here, the authors show a directed para-selective ketonisation of arenes, overriding electronic bias and structural congestion, and apply it to the synthesis of bioactive compounds.
format	article
author	Arun Maji Amit Dahiya Gang Lu Trisha Bhattacharya Massimo Brochetta Giuseppe Zanoni Peng Liu Debabrata Maiti
author_facet	Arun Maji Amit Dahiya Gang Lu Trisha Bhattacharya Massimo Brochetta Giuseppe Zanoni Peng Liu Debabrata Maiti
author_sort	Arun Maji
title	H-bonded reusable template assisted para-selective ketonisation using soft electrophilic vinyl ethers
title_short	H-bonded reusable template assisted para-selective ketonisation using soft electrophilic vinyl ethers
title_full	H-bonded reusable template assisted para-selective ketonisation using soft electrophilic vinyl ethers
title_fullStr	H-bonded reusable template assisted para-selective ketonisation using soft electrophilic vinyl ethers
title_full_unstemmed	H-bonded reusable template assisted para-selective ketonisation using soft electrophilic vinyl ethers
title_sort	h-bonded reusable template assisted para-selective ketonisation using soft electrophilic vinyl ethers
publisher	Nature Portfolio
publishDate	2018
url	https://doaj.org/article/f8e52a1b27b94288a6c5af4e4c47e1b5
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H-bonded reusable template assisted para-selective ketonisation using soft electrophilic vinyl ethers

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