H-bonded reusable template assisted para-selective ketonisation using soft electrophilic vinyl ethers

Electrophilic acylation of arenes is largely limited to electron rich systems, non-polar medium and often displays moderate selectivity. Here, the authors show a directed para-selective ketonisation of arenes, overriding electronic bias and structural congestion, and apply it to the synthesis of bio...

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Auteurs principaux: Arun Maji, Amit Dahiya, Gang Lu, Trisha Bhattacharya, Massimo Brochetta, Giuseppe Zanoni, Peng Liu, Debabrata Maiti
Format: article
Langue:EN
Publié: Nature Portfolio 2018
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Accès en ligne:https://doaj.org/article/f8e52a1b27b94288a6c5af4e4c47e1b5
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